Patents Assigned to Cray Valley USA, LLC
  • Publication number: 20140120280
    Abstract: An additive composition for imparting caustic removability to a hot melt adhesive includes an ester functionalized polymer having a polymeric backbone and, pendent thereon, one or more dicarboxylic acid moieties in at least partial ester form. The polymeric backbone has a weight average molecular weight less than 50,000. The ester functionalized polymer may be, for example, an at least partial ester of a maleated hydrocarbon. The additive may further include a low molecular weight ?,? ethylenically unsaturated anhydride-containing or acid-containing polymer. A caustic removable hot melt adhesive composition comprises a hot melt adhesive additive and a conventional hot melt adhesive resin. A caustic removable adhesive label comprises a substrate and a caustic removable hot melt adhesive composition which includes an additive composition. The caustic removable hot melt adhesives can be used on labels for articles, such as glass bottles.
    Type: Application
    Filed: April 11, 2012
    Publication date: May 1, 2014
    Applicant: Cray Valley USA, LLC
    Inventors: William R. Dougherty, Nestor P. Hansen
  • Publication number: 20140121316
    Abstract: A rubber composition includes high molecular weight diene elastomer, 5 to 120 phr of silica, 0 to 100 phr of a carbon black, and a silane modified oligomer including diene monomers and optionally vinyl aromatic monomers in polymerized form, wherein the silane modified oligomer has a molecular weight of 1000 to 5000 g/mol. A method of making the rubber composition includes compound mixing the components of the rubber composition in situ.
    Type: Application
    Filed: March 12, 2013
    Publication date: May 1, 2014
    Applicant: Cray Valley USA, LLC
    Inventors: Jean-Marc Monsallier, Steven K. Henning
  • Publication number: 20130224404
    Abstract: An insulated glass sealant includes an elastomeric matrix that is the reaction product of an acetoacetylated polymer and a cross-linking reagent having amino functionality, preferably a polyetheramine, polyamine, or polyamide. A method of sealing an insulated glass unit includes applying the insulated glass sealant to one or more glass sheets, disposing a spacer between the glass sheets, and contacting the glass sheets with the spacer to define an annular space between the glass sheets to produce the insulated glass unit. The sealants maintain the excellent attributes of traditional polyurethane sealants, such as low water swell, low moisture vapor transmission, good adhesion to the window frame, low migration of the insulating gas, and good workability, but without the use of polyisocyanates in the curing process. Methods for making the sealant and sealing insulated glass panels, such as glass windows, with these sealants, and the resulting articles, are also provided.
    Type: Application
    Filed: February 28, 2012
    Publication date: August 29, 2013
    Applicant: CRAY VALLEY USA, LLC
    Inventors: Herbert Shin-I Chao, Nan Tian
  • Patent number: 8461277
    Abstract: An additive composition for imparting caustic removability to a hot melt adhesive comprises a low molecular weight ?,? ethylenically unsaturated anhydride-containing or acid-containing polymer. The polymer is selected from the group consisting of a low molecular weight carboxylic anhydride homo-polymer or the at least partial ester thereof, a low molecular weight carboxylic anhydride copolymer or the at least partial ester thereof, a low molecular weight carboxylic anhydride polyolefin, a low molecular weight carboxylic anhydride vinyl aromatic copolymer, and a low molecular weight carboxylic anhydride grafted copolymer, or the combination or mixtures thereof. A caustic removable hot melt adhesive composition comprises a hot melt adhesive additive and a conventional hot melt adhesive resin. A caustic removable adhesive label comprises a substrate and a caustic removable hot melt adhesive composition which includes an additive composition.
    Type: Grant
    Filed: April 5, 2010
    Date of Patent: June 11, 2013
    Assignee: Cray Valley USA, LLC
    Inventors: William R. Dougherty, Alan J. Pape, Nestor P. Hansen, W. Paul Boggs, Charles C. Mateer
  • Publication number: 20130078397
    Abstract: An insulated glass sealant includes an elastomeric matrix that is the reaction product of a carboxyl-terminated polymer and a polycarbodiimide. A method of sealing an insulated glass unit includes applying the insulated glass sealant to one or more glass sheets, a spacer to be disposed between the glass sheets, or both; and contacting the one or more glass sheets with the spacer to define an annular space between the glass sheets and to produce the insulated glass unit. The sealants maintain the excellent attributes of traditional polyurethane sealants, such as low water swell, low moisture vapor transmission, good adhesion to the window frame, low migration of the insulating gas, and good workability, but without the use of polyisocyanates in the curing process. Methods for making the sealant and for sealing insulated glass panels, such as glass windows, with these rugged sealants, and the resulting articles, are also provided.
    Type: Application
    Filed: September 22, 2011
    Publication date: March 28, 2013
    Applicant: Cray Valley USA, LLC
    Inventors: Herbert Shin-I Chao, Nan Tian
  • Patent number: 7901695
    Abstract: A controlled continuous release composition, articles comprising the continuous release composition, methods of using the composition, and methods of preparing the composition are disclosed. The composition comprises an elastomeric matrix which is a reaction product of a carboxyl-terminated polymer with a polycarbodiimide and at least one active agent which is released from the matrix into the environment substantially continuously over an extended period of time.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: March 8, 2011
    Assignee: Cray Valley USA, LLC
    Inventors: Herbert Chao, Nan Tian