Patents Assigned to Crompton and Knowles Corporation
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Patent number: 5904738Abstract: The invention is directed to (1) a method for increasing the color fastness of dyed textiles subject to exposure by atmospheric gases by treating said textiles with a fade-inhibiting amount of a composition comprising at least one polyalkylene imine and (2) the dyed textiles so treated.Type: GrantFiled: January 28, 1998Date of Patent: May 18, 1999Assignee: Crompton & Knowles CorporationInventor: James E. Purcell
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Patent number: 5874547Abstract: A process for diazotizing an amine comprises the steps of oxidizing nitric oxide in solution with an oxidizing agent to maintain an equilibrium concentration of a diazotizing agent and reacting a primary aromatic amine in situ with said diazotizing agent in said solution.Type: GrantFiled: June 5, 1997Date of Patent: February 23, 1999Assignee: Crompton & Knowles CorporationInventors: John W. Larsen, Tracey McCracken, Jay E. Rowe, Lee A. Schaeffer
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Patent number: 5779805Abstract: The invention is a process for recrystallizing sugar. The invention involves admixing a first quantity of a powdered sugar and a second quantity of an adjuvant, such as an invert sugar, to provide a sugar blend. The sugar blend has up to about 3 percent moisture. The invention then involves mixing the sugar blend with a high shear extruding means at a temperature between about 220.degree. F. and about 300.degree. F. with a residence time in the extruding means of between about 0.5 second and about 12 seconds. The invention includes the product of a combined phase recrystallized sugar.Type: GrantFiled: August 26, 1996Date of Patent: July 14, 1998Assignee: Crompton & Knowles CorporationInventor: James R. Morano
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Patent number: 5772699Abstract: An aqueous reactive dye composition is disclosed. The aqueous reactive dye composition has improved storage stability and contains a water-soluble reactive dye and a chelating agent. The chelating agent is present in a sufficient concentration to maintain the pH of the aqueous reactive dye composition in the range of about 3.0 to about 7.0 and, preferably, about 5.0 to about 6.5. Desirable chelating agents are dicarboxylic acids, such as succinic acid, or amino carboxylates, such as nitrilotriacetic acid. A method of stabilizing an aqueous reactive dye composition is disclosed and includes the step of dissolving a polycarboxylic acid or an amino carboxylate in an aqueous solution of a water-soluble reactive dye in a sufficient concentration to stabilize the pH of the composition.Type: GrantFiled: February 10, 1997Date of Patent: June 30, 1998Assignee: Crompton & Knowles CorporationInventor: Andrew D. Boyer
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Patent number: 5723164Abstract: The invention is a composite food subsystem that provides a sweet or savory flavored thermostable filling having an ultra-low water activity. The thermostable filling is, also, thixotropic or "shear thinning". The filling includes an edible hydrophilic liquid phase. A stabilizing network of ultrahigh surface area cellulose particulates are dispersed and reactivated in the hydrophilic livid phase. A solid phase admixture can be added as a fine powder. The thermostable filling is desirable for use in methods for making co-extruded or co-laminated products of multi-textures.Type: GrantFiled: June 24, 1996Date of Patent: March 3, 1998Assignee: Crompton & Knowles CorporationInventor: James R. Morano
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Patent number: 5624692Abstract: A in-line extrusion die is disclosed including a cylindrical mandrel and a die bushing surrounding the mandrel and forming therebetween a passageway leading to an extrusion orifice. The mandrel is mounted to one side of a spider plate and a tailcone is attached to the other side thereof. A die body containing a melt chamber surrounds the tailcone and forms a conical passageway therebetween. A thermocouple is mounted at the apex end of the tailcone for measuring the temperature of the melt as the melt flows from the melt chamber and through the conical passageway. The spider plate contains a plurality of openings which communicate with both passageways and allow the melt to pass through the plate and thence to the extrusion orifice.Type: GrantFiled: January 30, 1996Date of Patent: April 29, 1997Assignee: Crompton & Knowles CorporationInventor: Paul M. Hendess
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Patent number: 5538411Abstract: An extrusion die apparatus for extruding a multiple layer tubular product including a plurality of annular die elements mounted co-axially one behind the other on a mandrel forming annular thickness control passages between the die elements and the mandrel. The die elements have inner and outer conical surfaces inclined rearwardly with respect to the longitudinal axis of the mandrel. The die elements are nested together with the outer conical surfaces of one die element facing the inner conical surfaces of an adjacent die element. The inner and outer conical surfaces form conical passages which communicate with the annular thickness control passages and a plurality of helical grooves are provided on the outer conical surface of each die element. A binary divider system is provided for distributing a molten thermoplastic material from an inlet to a plurality of outlets communicating with said grooves on each die element.Type: GrantFiled: October 25, 1994Date of Patent: July 23, 1996Assignee: Crompton & Knowles CorporationInventor: Peter C. Gates
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Patent number: 5529801Abstract: The invention is a composite food subsystem that provides a sweet or savory-flavored thermostable filling having an ultra-low water activity. The thermostable filling is, also, thixotropic or "shear thinning". The filling includes an edible hydrophilic liquid phase. A stabilizing network of ultrahigh surface area cellulose particulates are dispersed and reactivated in the hydrophilic liquid phase. A solid phase admixture can be added as a fine powder. The thermostable filling is desirable for use in methods for making co-extruded or co-laminated products of multi-textures.Type: GrantFiled: November 21, 1994Date of Patent: June 25, 1996Assignee: Crompton & Knowles CorporationInventor: James R. Morano
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Patent number: 5366750Abstract: The invention is a composite food subsystem that provides a sweet or savory flavored thermostable filling having an ultra-low water activity. The thermostable filling is, also, thixotropic or "shear thinning". The filling includes an edible hydrophilic liquid phase. A stabilizing network of ultrahigh surface area cellulose particulates are dispersed and reactivated in the hydrophilic liquid phase. A solid phase admixture can be added as a fine powder. The thermostable filling is desirable for use in methods for making co-extruded or co-laminated products of multi-textures.Type: GrantFiled: January 13, 1993Date of Patent: November 22, 1994Assignee: Crompton & Knowles CorporationInventor: James R. Morano
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Patent number: 5360551Abstract: A highly colored dye wastewater is treated by a sequence of steps to obtain a color reduction of 90 percent or more. The method requires acidifying the wastewater and adding a cationic flocculant. A reducing agent is then, optionally, added to further reduce the color value of the wastewater and produce an oxidation-reduction potential of at least -200 and, generally, about -400 to -800. The reducing agent is, preferably, either a hydrosulfite or both a bisulfite and an alkali metal borohydride.Type: GrantFiled: April 1, 1993Date of Patent: November 1, 1994Assignee: Crompton & Knowles CorporationInventor: Oscar W. Weber
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Patent number: 5221821Abstract: A method of manufacturing an extruder barrel is disclosed which fabricates a barrel in two longitudinal sections and joins the sections together by electron beam welding. In a preferred form, the barrel sections are formed by machining conical recesses longitudinally in each section whereby a complementary bore is defined by the assembled barrel sections. The machined recesses may be formed with spiral, longitudinal or radial grooves. The recesses may be a uniform conical shape, stepped conical or a dual tapered shape.Type: GrantFiled: January 10, 1992Date of Patent: June 22, 1993Assignee: Crompton & Knowles CorporationInventors: Michael T. Burns, Albert P. Brown, William A. Kramer, Edward J. McGrady
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Patent number: 5169479Abstract: A wire take-up apparatus for applying wire to a wire spool includes a tape applicator assembly for automatically applying a length of adhesive tape to the outer terminal end portion of the wire applied to a spool in order to prevent the wire from unraveling from the spool. The tape applicator assembly includes a vacuum roller assembly including a vacuum roller element which is operative for releasably retaining a portion of a length of tape on the outer surface thereof so that the adhesive surface of the tape faces outwardly. The vacuum roller assembly is movable to a position wherein the tape on the vacuum roller element thereof contacts the wire on a wire spool to apply the tape to the wire.Type: GrantFiled: April 18, 1991Date of Patent: December 8, 1992Assignee: Crompton & Knowles CorporationInventors: David C. Hoddinott, James P. Kudelchuk
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Patent number: 5149193Abstract: An extruder temperature controller for an extruder barrel and a method for controlling the temperature of an extruder barrel, includes a device for determining an actual screw speed and for storing a plurality of screw speeds. Each member of the plurality of stored screw speeds has a corresponding stored temperature reset value. The extruder temperature controller has a device for comparing and selecting that compares the actual screw speed to each of the plurality of stored screw speeds and selects a default screw speed. The default screw speed has a smaller deviation from the actual screw speed than any other member of the compared, stored screw speeds. The controller further includes a device for generating a control output driver signal to a heat exchanger. The control output driver signal is the corresponding stored temperature reset value for the default screw speed.Type: GrantFiled: January 15, 1991Date of Patent: September 22, 1992Assignee: Crompton & Knowles CorporationInventor: Louie M. Faillace
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Patent number: 4877538Abstract: This invention relates to a new process and group of products that are useful in preventing nylon and wool fibers, including carpeting and upholstery, from being permanently stained. Fibers can be permanently stained by food colors contained in food spilled on the fiber. This new group of sulfomethylated phenol-formaldehyde or naphthol-formaldehyde and anionic surfactant compounds not only block the stain from the fiber but also minimize any yellowing or discoloration of the treated fibers during the application and during the subsequent exposure to sunlight or commonly used lightfastness testing equipment.Type: GrantFiled: April 4, 1988Date of Patent: October 31, 1989Assignee: Crompton & Knowles CorporationInventors: Alexander S. Kirjanov, Michel A. Herlant
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Patent number: 4865885Abstract: This invention relates to a new process and group of products that are useful in preventing nylon and wool fibers, including carpeting and upholstery, from being permanently stained. Fibers can be permanently stained by food colors contained in foods spilled on the fiber. This new group of sulfonated phenol-formaldehyde or naphthol-formaldehyde and anionic surfactant compounds not only block the stain from the fiber but also minimizes any yellowing or discoloration of the treated fibers during the application and during the subsequent exposure to sunlight or commonly used lightfastness testing equipment.Type: GrantFiled: June 19, 1987Date of Patent: September 12, 1989Assignee: Crompton & Knowles CorporationInventors: Michel A. Herlant, Alexander S. Kirjanov, Vincent W. Bannigan, Jr.
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Patent number: 4857392Abstract: This invention relates to a new composition and process that affords "total stain protection" finishing of polyamide products, i.e., carpet. This composition of non-ionic fluorocarbon and sulfomethylated phenolformaldehyde condensates provides protection against oil and waterborne soils and in addition, protects the treated substrate against food colors by means of a one-step application.Type: GrantFiled: June 15, 1988Date of Patent: August 15, 1989Assignee: Crompton & Knowles CorporationInventors: Alexander S. Kirjanov, Dieter Hoecklin
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Patent number: 4853466Abstract: This invention relates to disazo dyes, and their metal complexes, which are useful for dyeing cellulosic fibers in lightfast and washfast hues. In addition, these dyes have high water solubility, a high degree of fixation, acceptable migration and high water solubility with reasonable cost.The disazo dyes have the structure: ##STR1## Wherein: R is selected from ##STR2## Wherein the azo bonds are ortho to the --OH or NH.sub.2 groups;R.sub.1 is H, lower alkyl, lower alkoxy, or --CO.sub.2 M;R.sub.2 is H, lower alkyl, lower alkoxy, Cl;R.sub.3 is lower alkylene;R.sub.4 is H, --lower alkyl;R.sub.5 is H, lower alkyl, --CO.sub.2 M;R.sub.6 is OH or --NH.sub.2 ;R.sub.7 is H, --CH.sub.2 SO.sub.3 M;M is H, Na, Li, K, Mg, Ca, NH.sub.4 ; ##STR3## and n is 0, 1, 2.Type: GrantFiled: November 20, 1987Date of Patent: August 1, 1989Assignee: Crompton & Knowles CorporationInventor: James F. Feeman
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Patent number: 4851158Abstract: This invention relates to novel N-alkyl-N-(amino-phenylsulfonyl)-aminoalkylphosphonic acids and to processes for their preparation. These compounds are useful as intermediates, especially for the manufacture of dyes containing phosphonic acid groups in their structure. Such dyes are reactive with cellulosic fibers and fabrics in the presence of carbodiimides at elevated temperatures.Type: GrantFiled: November 20, 1987Date of Patent: July 25, 1989Assignee: Crompton & Knowles CorporationInventor: James F. Feeman
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Patent number: 4851516Abstract: This invention relates to novel disazo dyes and processes for their production having the structure: ##STR1## wherein: R.sub.1 is H, lower alkyl, chloro, lower alkoxy, --CO.sub.2 M;R.sub.2 is H, lower alkyl, lower alkoxy, chloro;R.sub.3 is lower alkylene;R.sub.4 is H or lower alkyl;R.sub.5 is H, lower alkyl, lower alkoxy, chloro, nitro, --NHCO-- lower alkyl; CF.sub.3 ;R.sub.6 is H, lower alkyl, lower alkoxy, chloro, --SO.sub.3 M;R.sub.7 is --SO.sub.3 M, --CO.sub.2 MM is H, Na, Li, K, N.sub.Type: GrantFiled: November 20, 1987Date of Patent: July 25, 1989Assignee: Crompton & Knowles CorporationInventor: James F. Feeman
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Patent number: 4840643Abstract: A trichromatic dye combination especially suited for the continuous dyeing of synthetic polyamide materials; the system including an acid red dye component, an acid blue dye component and an acid yellow dye component, each of said dye components being selected on the basis of minimum and compatible cold strike and compatible on tone strike rates.The trichromatic combination according to the invention dyes synthetic polyamide fibers from aqueous liquors, producing level dyeings having excellent fastness properties including good lightfastness and good ozone fastness.Type: GrantFiled: March 16, 1988Date of Patent: June 20, 1989Assignee: Crompton & Knowles CorporationInventor: Jay E. Rowe