Abstract: A crosslinking composition for hydrocarbon gels containing phosphate ester gelling agents comprising a modified imidazoline or pyrimidine including an alkyl group (or unsaturated carbon chain) or of 10 to 22 carbon atoms, a polyamine, and ferric sulfate. The method of making the crosslinking agent features adding the polyamine after reaction of the other ingredients; unique gels formed with the crosslinking agent are particularly effective for LNG at very cold temperatures.
Type:
Grant
Filed:
August 14, 2012
Date of Patent:
March 31, 2015
Assignee:
CST Performance Products Corp.
Inventors:
Larry W. Gatlin, Glen E. Walden, Ernest McMillan
Abstract: A composition useful for crosslinking phosphate esters in hydrocarbon gels used in formation fracturing performs especially well in cold temperatures, such as temperatures lower than (?)20° C. Methods of making the crosslinking composition and the gel are described; also methods of fracturing subterranean formations. Specific forms of ferric sulfate and ferric ammonium citrate are useful as ingredients of the crosslinking composition.
Type:
Grant
Filed:
June 27, 2011
Date of Patent:
February 10, 2015
Assignee:
CST Performance Products Corp.
Inventors:
Larry W. Gatlin, Glen E. Walden, Ernest McMillan, Richard A. Gatlin
Abstract: Where the loss of volatile organics during storage of high gravity oil is minimized by forming a flowable or pumpable gel in the high gravity oil, (and/or condensates and distillates), as they are introduced to a storage vessel, the gel is broken by the addition of a small amount of an amine/formaldehyde reaction product, which may be either a triazine or a mixture of non-triazine reaction products. The previously gelled hydrocarbon may then by more readily moved by draining or pumping into a pipeline.
Type:
Grant
Filed:
September 30, 2011
Date of Patent:
April 29, 2014
Assignee:
CST Performance Products Corp.
Inventors:
Larry W. Gatlin, Glen E. Walden, Ernest McMillan, Richard A. Gatlin, Wayne Mueller