Patents Assigned to Dai Nippon Toryo Co., Ltd.
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Patent number: 6514357Abstract: A composition for metal surface treatment which comprises an aluminum ion, a magnesium ion, a manganese ion, a water-soluble organic resin, an acid and water; and a surface treated metal material which has been treated with the composition. The resultant surface treated metal material is free from the danger of water contamination owing to chromium, since the composition is free of chromium, and also is excellent in both electrical conductivity and corrosion resistance. Accordingly, the metal material can be used in a wide variety of applications in place of a conventional chromate-treated steel sheet and the like.Type: GrantFiled: June 21, 2001Date of Patent: February 4, 2003Assignees: Kawasaki Steel Corporation, Dai Nippon Toryo Co., Ltd.Inventors: Chiyoko Tada, Hiroyuki Ogata, Shigeru Umino
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Patent number: 6410655Abstract: A resin composition for an aqueous paint containing different phase structure emulsion particles obtained by multi-stage emulsion polymerization as a binder, wherein the different phase structure emulsion particles have an outermost phase formed by an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 10° C., and satisfy the following conditions (1) to (3): (1) the emulsion polymer forming the outermost phase contains from 1 to 20 mass % of an ethylenic unsaturated monomer having at least one of a polyethylene glycol chain and a polypropylene glycol chain, (2) at least one phase of inner phases from the outermost phase of the different phase structure emulsion particles comprises an emulsion polymer of an ethylenic unsaturated monomer having a glass transition temperature of from 30° C. to 110° C., and (3) the binder has a minimum film-forming temperature of at most 10° C.Type: GrantFiled: December 8, 2000Date of Patent: June 25, 2002Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Masayoshi Okubo, Shinya Sakaguchi, Atsushi Takamatsu, Hiroharu Sasaki, Kazuyoshi Tsuneta
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Publication number: 20020013405Abstract: A resin composition for an aqueous paint, which comprises (a) a binder composed of different phase structure emulsion particles obtained by multi-stage emulsion polymerization, and (b) a compound having at least two hydrazide groups in its molecule, wherein the different phase structure emulsion particles have an outermost phase formed of an emulsion polymer which is an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 15° C.Type: ApplicationFiled: June 19, 2001Publication date: January 31, 2002Applicant: Dai Nippon Toryo Co., Ltd.Inventors: Shinya Sakaguchi, Atsushi Takamatsu, Hiroharu Sasaki, Kazuyoshi Tsuneta
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Patent number: 6329490Abstract: Disclosed are polyhedral organosilicon compounds which are possible to be polymerized and can form a film excellent in adhesiveness to a substrate, having a high hardness, a high transparency and having water and oil repellency, and comprise organofluoro groups or both of organofluoro groups and reactive functional groups, the compounds being soluble in an organic solvent and stable. Organosilicon compounds which have perfluoroalkyl groups or both perfluoroalkyl groups and reactive functional groups and which have a polyhedral structure have the following formulas of (I), (II) and (III): [Rf1—X1—(CH2)a—SiO1.5]m (I) [Rf1—X1—(CH2)a—SiO1.5]m[Rf2—(X2)c—(CH2)b—SiO1.5]n (II) [Rf1—X1—(CH2)a—SiO1.5]m[R—(X2)c—(CH2)b—SiO1.Type: GrantFiled: March 31, 2000Date of Patent: December 11, 2001Assignees: Mitsubishi Materials Corporation, Dai Nippon Toryo Co., Ltd.Inventors: Yukiya Yamashita, Kenji Hayashi, Masaoki Ishihara
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Publication number: 20010003770Abstract: A resin composition for an aqueous paint containing different phase structure emulsion particles obtained by multi-stage emulsion polymerization as a binder, wherein the different phase structure emulsion particles have an outermost phase formed by an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 10° C.Type: ApplicationFiled: December 8, 2000Publication date: June 14, 2001Applicant: Dai Nippon Toryo Co., Ltd.Inventors: Masayoshi Okubo, Shinya Sakaguchi, Atsushi Takamatsu, Hiroharu Sasaki, Kazuyoshi Tsuneta
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Patent number: 6228981Abstract: A process for preparing an aqueous dispersion coating material containing a resin component having a softening temperature of from 10 to 250° C., which comprises: (1) a step of mixing various starting materials which will be coating film-constituting components, to obtain a blend material, (2) a step of melting and kneading the blend material at a temperature of at least the softening temperature of said resin component, to obtain a homogenized material, (3) a step of cooling and solidifying the homogenized material, followed by crushing, to obtain coarse particles, and (4) a step of wet-pulverizing the coarse particles in an aqueous dispersant, to obtain an aqueous dispersion coating material containing fine particles having an average particle size of at most 10 &mgr;m.Type: GrantFiled: June 1, 1999Date of Patent: May 8, 2001Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Haruhiko Okazaki, Akiko Tagami
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Patent number: 6180043Abstract: A method of in-mold coating, comprising steps of forming a molded product by applying a clamping pressure to a mold to mold a synthetic resin molding material in the mold according to an injection molding method, an injection compression molding method or an injection press molding method, then coating a surface of the molded product with a coating material in the mold, wherein the coating material is injected in such a state that the molded product has cured or solidified to such an extent that the surface of the molded product can withstand an injection pressure and a flow pressure of the coating material, and the clamping of the mold after injection of the coating material is carried out under certain multistagewise variable clamping pressures with certain clamping pressure transitional periods of time.Type: GrantFiled: January 25, 1999Date of Patent: January 30, 2001Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Kenji Yonemochi, Yoshiaki Yamamoto
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Patent number: 6037435Abstract: The present application to an underwater curable coating composition which is used for protecting or imparting an aesthetic appearance to various structures. An underwater curable coating composition consisting essentially of an epoxy resin component and its curing agent, wherein the epoxy resin component is a mixture comprising a liquid hydrophobic epoxy resin and a self-emulsifiable liquid epoxy resin. The curing agent is composed partly or solely of a ketimine.Type: GrantFiled: September 25, 1998Date of Patent: March 14, 2000Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Toshiharu Hayashi, Toshimoto Tsuji
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Patent number: 6034161Abstract: A cold-setting aqueous emulsion paint comprising a pigment and an aqueous emulsion resin consisting essentially of a copolymer of (a) a polymerizable monomer of the formula (I): ##STR1## wherein R is a hydrogen atom or a methyl group, and n is 1 or 2, (b) a polymerizable monomer having a carboxyl group and an ethylenic double bond, and (c) a polymerizable monomer having an ethylenic double bond copolymerizable with the above polymerizable monomers (a) and (b).Type: GrantFiled: June 2, 1998Date of Patent: March 7, 2000Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Tetsuo Nakamura, Hiroharu Sasaki, Kazuyoshi Tsuneta, Sadakazu Hokamura
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Patent number: 5902534Abstract: A method of injection-molding a thermoplastic resin, which involves the steps of(a) injecting a molten resin of a thermoplastic resin into a cavity provided in a mold composed of a fixed mold member and a movable mold member,(b) introducing a predetermined amount of a coating material into between the resin in the cavity and the cavity wall after the injection of the molten resin is completed, to allow the resin in the cavity to be compressed with the introduced coating material and/or to allow the movable mold member to move in the mold-opening direction, and(c) maintaining a molding pressure before the mold releasing at a level higher than 0 kgf/cm.sup.2.Type: GrantFiled: September 5, 1995Date of Patent: May 11, 1999Assignees: Mitsubishi Engineering-Plastics Corp., Dai Nippon Toryo Co., Ltd.Inventors: Takeshi Fujishiro, Toshiaki Izumida, Kazuyuki Akahori, Yoshiaki Yamamoto
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Patent number: 5883200Abstract: A coating composition characterized in that it contains a compound obtained by reacting an amino resin with an organic polyphosphonic acid.Type: GrantFiled: August 22, 1996Date of Patent: March 16, 1999Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Harufumi Tsuchiya, Hiroaki Omoto, Hiroyuki Mishima, Tsunehiko Toyoda
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Patent number: 5807511Abstract: A composition for forming a near infrared screening filter, which comprises a binder (i), a metal oxide or inorganic oxide powder (ii) having a light transmittance ratio (transmittance of light with a wavelength of 550 nm/transmittance of light with a wavelength of 1180 nm) of at least 3, and a dye (iii) having a light transmittance ratio (transmittance of light with a wavelength of 550 nm/transmittance of light with a wavelength of from 740 to 930 nm) of at least 2.7, as essential components.Type: GrantFiled: March 31, 1997Date of Patent: September 15, 1998Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Masaaki Kunimatsu, Yuji Yamazaki
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Patent number: 5763015Abstract: A method for sealing a zinc-aluminum pseudo alloy spray coating, which comprises forming a zinc-aluminum pseudo alloy spray coating on a substrate to be spray-coated, and then sealing the surface of the coating with a chromium-free sealing material containing phosphoric acid in an amount of from 0.1 to 7 wt %.Type: GrantFiled: October 29, 1996Date of Patent: June 9, 1998Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Kenji Hasui, Toshiaki Arakawa, Kazuyoshi Tsuneta
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Patent number: 5725911Abstract: A method for forming a metal spray coating, which comprises coating on a substrate to be metal-sprayed, one pack type cold self-crosslinking resin aqueous dispersion containing insoluble solid particles having an average particle size of from 5 to 200 .mu.m, to form a primer layer having a rough surface, and then spraying a metal on the primer layer.Type: GrantFiled: May 24, 1996Date of Patent: March 10, 1998Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Kazuyoshi Tsuneta, Kenji Hasui, Toru Taki
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Patent number: 5723210Abstract: An organic composite coated steel sheet having excellent chromate dissolution resistance, wet adhesion, and corrosion resistance before and after working. The steel sheet comprises a chromate-silica film on at least one face of a zinc or zinc base alloy plated steel sheet, the silica-added chromate film having about 5 to 500 mg/m.sup.2 in terms of metal Cr content and being formed from a chromate solution containing about 25 to 70 wt % of Cr.sup.+6 based upon total Cr content. A resin coating film is adhered to the chromate-silica film and is formed from an aqueous paint. The aqueous paint includes an aqueous anionic resin and/or an aqueous nonionic resin, a reducing agent, and a water-dispersed silica. The resin coating film is deposited in a dry weight amount of about 0.1 to 3 g/m.sup.2.Type: GrantFiled: May 29, 1996Date of Patent: March 3, 1998Assignees: Kawasaki Steel Corporation, Dai Nippon Toryo Co. Ltd.Inventors: Shigeko Sujita, Takahiro Kusakabe, Kyoko Hamahara, Kazuo Mochizuki, Hiroyuki Tanabe, Masanori Nagai, Nobuyoshi Kato, Osamu Ogawa
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Patent number: 5608004Abstract: A water base coating composition having a solid content of from 50 to 80 wt % and having a binder component dissolved or dispersed in a solvent mixture comprising water and a hydrophilic organic solvent, said binder component comprising from 30 to 95 wt % of a polyester resin obtained from an aromatic polybasic carboxylic acid or its acid anhydride and a polyhydric alcohol and having a hydroxyl value of from 100 to 280 and an acid value of from 0 to 15, and from 70 to 5 wt % of a melamine resin and/or a benzoguanamine resin.Type: GrantFiled: April 5, 1995Date of Patent: March 4, 1997Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Tsunehiko Toyoda, Harufumi Tsuchiya, Hiroaki Omoto, Mitsuru Kohno, Maki Ii
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Patent number: 5504133Abstract: A composition for forming transparent conductive films comprises a tin-containing indium oxide (ITO) powder dispersed in a binder solution. The binder solution comprises a mixed organic solvent consisting of at least one polar solvent and at least one non-polar solvent, in which a polymer having a weight-average molecular weight of from 8,000 to 150,000 is dissolved. The polymer contains (a) an acidic functional group in such a proportion that the polymer has an acid number of from 0.5 to 15 mg-KOH/g, or (b) a polyalkylene glycol chain in a proportion of from 0.5% to 40% by weight, or both of (a) and (b) in the molecule. Alternatively, the binder solution comprises an actinic radiation-curable binder, which comprises an acrylate or methacrylate compound containing an acid phosphate group in the molecule. The composition can form, by coating, a transparent conductive film having improved electrical and optical properties.Type: GrantFiled: October 4, 1994Date of Patent: April 2, 1996Assignees: Mitsubishi Materials Corporation, Dai Nippon Toryo Co., Ltd.Inventors: Masato Murouchi, Toshiharu Hayashi, Akira Nishihara, Masaoki Ishihara
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Patent number: 5496509Abstract: A method for preparing a molded product which includes (i) molding a fiber-reinforced plastic material in a mold, (ii) injecting a coating composition into the mold, the coating composition containing a vehicle component including urethane acrylate oligomer and epoxy acrylate oligomer as the main ingredients and a filler component including calcium carbonate as the main ingredient, and (iii) taking the coated molded product from the mold and plating the surface of the product. According to the present invention, there can be obtained a molded product having a plated layer with a satisfactory smooth and uniform glossy surface and having an improved adhesion between the molded product and the plated layer.Type: GrantFiled: September 26, 1994Date of Patent: March 5, 1996Assignees: Dai Nippon Toryo Co., Ltd., Isuzu Motors LimitedInventors: Naotaka Yamamoto, Nobuo Yagi, Satoshi Fujii, Kenji Yonemochi, Mitsutoshi Myokei
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Patent number: 5403698Abstract: A negative type photosensitive electrodepositing resin composition comprising (a) a polymer obtained by neutralizing a copolymer of acrylic or methacrylic acid and having an acid number of 20 to 300 with a basic organic compound, (b) a non-water-soluble monomer having two or more photopolymerizable unsaturated bonds in the molecule, (c) a non-water-soluble photoinitiator, and (d) a benzotriazole derivative having one or more carboxyl groups, is effective for giving electrodeposited films with a low voltage or low electric current in a short time, and usable for forming resist patterns with high degree of resolution.Type: GrantFiled: October 11, 1991Date of Patent: April 4, 1995Assignees: Hitachi Chemical Company, Ltd., Dai Nippon Toryo Co., Ltd.Inventors: Sigeo Tachiki, Masahiko Hiro, Toshihiko Akahori, Takuro Kato, Hajime Kakumaru, Yoshitaka Minami, Yuhji Yamazaki, Toshiya Takahashi, Toshihiko Shiotani, Yoshihisa Nagashima
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Patent number: 5361616Abstract: A coating composition having photopolymerizability and heat curability, which comprises, as main components,(A) a vinyl copolymer having polymerizable double bonds and crosslinkable hydroxyl groups,(B) a condensation polymerizable compound of the following formula (i) or a condensation polymer thereof, and(C) a photopolymerization initiator: ##STR1## wherein each of the plurality of R which may be the same or different, is --H, --CH.sub.2 OH, --CH.sub.2 OCH.sub.3, --CH.sub.2 OC.sub.4 H.sub.Type: GrantFiled: June 9, 1992Date of Patent: November 8, 1994Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Toshiya Takahashi, Norio Uriya, Yoshihisa Nagashima