Patents Assigned to Daicel Chemical Industries, Ltd.
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Alicyclic diepoxy compound, epoxy resin composition comprising the same, and cured article therefrom
Patent number: 7989523Abstract: Disclosed is an alicyclic diepoxy compound which gives a cured article suffering from no deterioration in properties even when used in hot and humid surroundings or used under such conditions as to give a strong acid, which is highly reactive upon curing, and which gives a cured article superior typically in thermal stability. Specifically, the alicyclic diepoxy compound includes a 3,4,3?,4?-diepoxybicyclohexyl compound represented by following Formula (1): wherein R1 to R18 each represent a hydrogen atom, a halogen atom, a hydrocarbon group which may have an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group, in which the alicyclic diepoxy compound contains isomers of the 3,4,3?,4?-diepoxybicyclohexyl compound in a content of less than 20% based on the total of the 3,4,3?,4?-diepoxybicyclohexyl compound and the isomers thereof in terms of peak area ratio as determined by gas chromatography.Type: GrantFiled: June 29, 2007Date of Patent: August 2, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Atsushi Sato, Hideyuki Takai, Hisashi Maeshima, Kyuhei Kitao -
Patent number: 7985866Abstract: Disclosed is an oxetane-containing vinyl ether compound including one or more aromatic or non-aromatic carbocycles and/or two or more vinyl ether structures, such as a compound of Formula: wherein Ring Z1 is non-aromatic carbocycle; Ra is vinyl group of Formula: wherein each of R1, R2, and R3 is hydrogen or C1-C4 alkyl; Wa is single bond or organic group having a valence of (m+1); X1 is, for example, hydrocarbon; “m” and “q” are each 1 or 2; and “p” is 0 to 5. Also disclosed is an alicyclic epoxy-containing vinyl ether compound of Formula: wherein Ring Z2 is non-aromatic carbocycle; Rb is vinyl group of Formula: wherein R4, R5 and R6 are each hydrogen or C1-C4 alkyl; Wb is single bond or organic group having a valence of (r+1); Rc and Rd are hydrogen or alkyl; and “r” and “s” are 1 or 2.Type: GrantFiled: March 20, 2008Date of Patent: July 26, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Takahiro Iwahama, Tatsuya Nakano, Keizo Inoue, Hiroto Miyake, Tsukasa Yoshida, Mitsuru Ohno, Yoshinori Funaki
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Patent number: 7942990Abstract: The present invention provides a hybrid inflator including: a pressurized gas and a solid gas generating agent that generates a combustion gas as a gas source, the solid gas generating agent including at least an oxidizing agent and a binder, the pressurized gas including 15 mol % or more of oxygen.Type: GrantFiled: December 17, 2007Date of Patent: May 17, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Kenji Kitayama, Shogo Tomiyama, Masayuki Nakayasu
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Patent number: 7942154Abstract: The present invention provides a cigarette filter material useful for selectively and efficiently reducing formaldehyde while maintaining a palatable component such as nicotine or tar. The cigarette filter material is obtained by coating-treating a substrate (such as a cellulose acetate fiber) with a solution (particularly, an aqueous solution) containing a polysaccharide having an amino group (e.g. chitosan) and a polar solvent (e.g., water) [and optionally an acid such as a hydroxy acid (e.g., lactic acid)]. A cigarette filter of such a cigarette filter material can efficiently and selectively reduce formaldehyde. For example, the cigarette filter ensures a retention of formaldehyde of not more than 65% while maintaining retentions of nicotine and tar of not less than 80%, respectively, in main stream smoke.Type: GrantFiled: December 21, 2005Date of Patent: May 17, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroki Taniguchi, Takashi Hibi
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Patent number: 7938962Abstract: A separating agent which combines a high optical resolving power inherent in polysaccharide derivatives with sufficient solvent resistance and a method with which the separating agent can be produced efficiently in short steps. The separating agent for enantiomeric isomers is characterized in that a polymerizable polysaccharide derivative of a polysaccharide derivative having polymerizable functional groups and a polymerizable monomer having polymerizable unsaturated groups are copolymerized with a carrier having polymerizable functional groups to be chemically bound mutually. The separating agent is preferably used for high performance liquid chromatography (HPLC) and has an excellent solvent resistance.Type: GrantFiled: November 15, 2007Date of Patent: May 10, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Yoshio Okamoto, Chiyo Yamamoto, Takateru Kubota
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Patent number: 7887650Abstract: The present invention provides a gas generating composition comprising a fuel and an oxidizing agent and further a copper powder.Type: GrantFiled: March 1, 2007Date of Patent: February 15, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Kenji Kitayama, Shogo Tomiyama
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Patent number: 7884241Abstract: A mixture containing hydrogen iodide and water and having a water content of not more than 5% by weight (particularly not more than 3% by weight) in a distillation system is distilled to prevent condensation of hydrogen iodide in the distillation system. The mixture may comprise hydrogen iodide, water, methanol, methyl iodide, acetic acid, and methyl acetate. Even when the mixture contains hydrogen iodide at a concentration of 1 to 3000 ppm on the basis of weight, an acetic acid product having a concentration of hydrogen iodide of not more than 50 ppm can be obtained by withdrawing a fraction containing hydrogen iodide from the top of the column, and withdrawing acetic acid as a side-cut stream or a stream from the bottom of the column. Such a process (distillation process) effectively inhibits condensation of hydrogen iodide in the distillation system and corrosion in the distillation system.Type: GrantFiled: December 5, 2005Date of Patent: February 8, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroyuki Miura, Kenichiro Kawazumi
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Publication number: 20110023898Abstract: The present invention provides a packaging method for a filter tow bale, including excessively compressing a distance between press bases to a height lower than a desired height of a packaged bale by 50 to 250 mm, more preferably 80 to 200 mm, further preferably 90 to 180 mm, then adjusting the distance between the press bases to the desired height in a packaged or non-packaged state, and then releasing a pressing force applied on a pressed bale.Type: ApplicationFiled: March 30, 2010Publication date: February 3, 2011Applicant: Daicel Chemical Industries, Ltd.Inventors: Takashi HIBI, Hirofumi Tsujita
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Patent number: 7868069Abstract: A shaped article (e.g., a porous material, and a spherical particle) comprising (A) a resin component is produced by kneading the resin component (A) (e.g., a thermoplastic resin) and a water-soluble auxiliary component (B) to prepare a dispersed composition, and eluting the auxiliary component (B) from the dispersed composition. The auxiliary component (B) may comprise 100 parts by weight of an oligosaccharide (B1) and 0.5 to 100 parts by weight of a water-soluble plasticizing component (B2) for plasticizing the oligosaccharide. The oligosaccharide (B1) may comprise a tetrasaccharide. The plasticizing component (B2) may comprise a saccharide or a sugar alcohol. Use of the dispersed composition ensures to form a shaped article having a given shape industrially with advantage even in the case of using a wide variety of resin components.Type: GrantFiled: February 17, 2009Date of Patent: January 11, 2011Assignee: Daicel Chemical Industries, Ltd.Inventor: Hisayoshi Ito
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Patent number: 7863439Abstract: The present invention provides a cellulose ester in which heat resistance under wet condition is compatible with both releasability and spinnability even when the amount of the residual solvent is small in a casting process. The cellulose ester fulfills the following formula: 0.5<(B)/(A)<1.5 wherein (A) and (B) represent the total amount (in terms of molar amount) of residual sulfuric acid in 1 gram of the cellulose ester and the total amount (in terms of molar amount) of calcium contained in 1 gram of the cellulose ester, respectively.Type: GrantFiled: February 25, 2004Date of Patent: January 4, 2011Assignee: Daicel Chemical Industries, Ltd.Inventors: Toru Ozaki, Toru Shibata, Shu Shimamoto
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Patent number: 7856821Abstract: An actuator includes an ignition device having an igniter main body fixed to an igniter collar and a cylinder connected to the igniter collar. The cylinder has a first sliding chamber located in a position facing the ignition device and a second sliding chamber formed in a direction perpendicular to the first sliding chamber. A first piston is disposed inside the first sliding chamber, one end surface of the first piston having a first inclined surface inclined in one direction, and the other end surface opposing the ignition device, and a second piston is disposed inside the second sliding chamber. A circumferential surface of the second piston is provided with a recess formed with a second inclined surface inclining in the central axis direction, and the second piston is provided such that the first inclined surface abuts against the second inclined surface.Type: GrantFiled: September 6, 2007Date of Patent: December 28, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Nobuyuki Katsuda, Kenji Numoto
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Patent number: 7854201Abstract: An igniter assembly includes, an electric igniter and igniter collar, and a resin fixing the electric igniter into the igniter collar. The electric igniter has an igniter main body and a conductive pin which extends from the igniter main body. The igniter collar has a first through hole formed in the axial direction and at least one second through hole formed separately from the first through hole and being provided to the igniter collar. The electric igniter is fixed inside the first through hole by the resin, and the resin is also charged into the second through hole.Type: GrantFiled: November 2, 2006Date of Patent: December 21, 2010Assignee: Daicel Chemical Industries, Ltd.Inventor: Shingo Oda
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Patent number: 7851583Abstract: An oxirane compound of following Formula (1), such as glycidol, is reacted in the presence of a powdered activated carbon, where necessary, with an initiator such as a polyhydric alcohol, an aliphatic alcohol, or an aliphatic carboxylic acid, to yield, for example, a polyglycidol, a polyglycidol alkyl ether, or a polyglycidol alkyl ester. wherein R1 and R2 may be the same as or different from each other and each represent one selected from hydrogen (H); a branched- or straight-chain alkyl group having one to thirty carbon atoms or an aryl group; and a functional group represented by —CH2-M, wherein M represents OH, F, Cl, Br, or —OR3, wherein R3 represents an alkyl group having one to twenty carbon atoms, allyl group, or an aryl group. A target compound can be obtained in a high yield with high quality according to this invention, from which the catalyst can be easily separated.Type: GrantFiled: February 3, 2006Date of Patent: December 14, 2010Assignees: Daicel Chemical Industries, Ltd., Hokoku CorporationInventors: Toshio Endo, Tetsuro Taguchi, Keiji Fujiyoshi
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Patent number: 7834217Abstract: Disclosed is a method for industrially efficiently producing a corresponding useful oxidation product such as a cycloalkyl hydroperoxide, a cycloalkanol, and/or a cycloalkanone, especially a particularly useful cycloalkanone, from a cycloalkane with a high selectivity in a good yield at low cost. This method is advantageous in respect of energy and process. Specifically, an oxidation product of a cycloalkane is obtained by oxidizing the cycloalkane in a liquid-liquid two phase system using an aqueous solvent in the presence of a nitrogen atom-containing cyclic compound which contains, as its ring constituent, a structure represented by following Formula (I): wherein X represents an oxygen atom or an —OR group, and wherein R represents a hydrogen atom or a hydroxyl-protecting group, and which has a solubility in water at 25° C. of 0.5 g/100 g-H2O or more.Type: GrantFiled: November 30, 2007Date of Patent: November 16, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Takumi Omori, Yasushi Sato
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Patent number: 7834114Abstract: Disclosed is a polycyclic ester containing a cyano group and a lactone skeleton, represented by following Formula (1): wherein Ra represents, for example, a hydrogen atom or an alkyl group having one to six carbon atoms which may have a halogen atom; R1s each represent, for example, a halogen atom or an alkyl or haloalkyl group having one to six carbon atoms; “m” is the number of R1s; “n” is the number of cyano groups; and CH2?C(Ra)COO— group may have either of an endo conformation and an exo conformation. Accordingly, there is provided a novel polycyclic ester containing a cyano group and a lactone skeleton which is useful typically as a monomeric component for highly functional polymers. A polymer, for example, derived from this compound is highly soluble in an organic solvent while remaining stable typically to chemicals and exhibits improved hydrolyzability and/or improved solubility in water after hydrolysis.Type: GrantFiled: December 1, 2009Date of Patent: November 16, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Keizo Inoue, Takahiro Iwahama, Masamichi Nishimura, Kiyoharu Tsutsumi
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Patent number: 7833365Abstract: The present invention provides a gas generating composition comprising a light rare earth compound.Type: GrantFiled: January 26, 2007Date of Patent: November 16, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Kenji Kitayama, Shogo Tomiyama
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Patent number: 7829186Abstract: A porous film with chemical resistance of this invention includes a porous film base covered with a chemical-resistant polymeric compound and has a multiplicity of communicating micropores having an average pore size of 0.01 to 10 ?m. The chemical-resistant polymeric compound can be, for example, any of phenolic resins, urea resins, melamine resins, benzoguanamine resins, polyimide resins, epoxy resins, benzoxazine resins, polypropylene resins, polyurethane resins, fluororesins, alkyd resins, cellulose acetate resins, phthalic resins, maleic resins, and silicone resins.Type: GrantFiled: September 15, 2004Date of Patent: November 9, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Yo Yamato, Michio Tsuyumoto
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Patent number: 7825197Abstract: A liquid thermosetting epoxy resin composition contains a base resin in combination with a curing agent and a curing accelerator or with a curing catalyst. The base resin includes a cycloaliphatic epoxy compound having at least one alicyclic skeleton and two or more epoxy groups per molecule, and a polyol oligomer having two or more terminal hydroxyl groups. An optical semiconductor device includes an optical semiconductor element sealed by using the liquid thermosetting epoxy resin composition. The composition yields a cured resinous product which is free from curing failure, is optically homogenous, has a low elastic modulus in bending, a high bending strength, a high glass transition temperature, a high optical transparency and is useful for optical semiconductors.Type: GrantFiled: December 9, 2005Date of Patent: November 2, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Hideyuki Takai, Hiroyuki Hirakawa
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Patent number: 7820281Abstract: A porous film of the invention is a porous film having a large number of continuous micropores. The film has a thickness of 5 to 200 ?m, has an average surface pore size A of 0.01 to 10 ?m, an average surface porosity C, and has an average inside pore size B and an average inside porosity D. The ratio A/B of A to B is 0.3 to 3. The porous film is produced by casting a polymer solution containing a polymer onto a substrate to form a film and subjecting the film to phase conversion to thereby form a porous film. In the method, the polymer constituting the porous film has a surface tension Sa [mN/m], the substrate has a surface tension Sb [mN/m], and Sa and Sb satisfy the following condition: Sa?Sb??10.Type: GrantFiled: August 19, 2003Date of Patent: October 26, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Michio Tsuyumoto, Yo Yamato
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Patent number: 7816471Abstract: Process for producing photoresist polymeric compound having repeated units corresponding to at least one monomer selected from monomer (a) having lactone skeleton, monomer (b) having group which becomes soluble in alkali by elimination with acid, and monomer (c) having alicyclic skeleton having hydroxyl group. Process includes (A) polymerizing mixture of monomers containing at least one monomer selected from the above monomers (a), (b), and (c), and (B) extracting polymer formed in the polymerization by using organic solvent and water to partition the formed polymer into organic solvent layer and metal component impurity into aqueous layer, or passing polymer solution, which contains polymer having repeated units corresponding to at least one of the above monomers (a), (b), and (c) and metal content of which is 1000 ppb by weight or less relative to the polymer through filter comprising porous polyolefin membrane having cation-exchange group.Type: GrantFiled: December 23, 2009Date of Patent: October 19, 2010Assignee: Daicel Chemical Industries, Ltd.Inventors: Hitoshi Watanabe, Hidetaka Hayamizu, Masaaki Kishimura