Abstract: A powdery coating composition having excellent anti-caking ability, which comprises polymer particles having an average particle size of 0.5 to 200.mu. composed of a polymer having a softening point not exceeding 90.degree. C. as a core component and a polymer having a softening point of at least 100.degree. C. as an outer component covering said core component, and to a process for the preparation of such powdery coating composition.