Patents Assigned to Degussa & Henkel Kommanditgesellschaft auf Aktien
  • Patent number: 4305916
    Abstract: There are produced crystalline zeolite powders of Type A with the composition1.0.+-.0.2M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5SiO.sub.2.yH.sub.2 Owhere M is a metal cation, n is it valence and y has a value up to 6 with 50 weight % of the particles not over 4.3.mu. and with a particle spectrum:______________________________________ Fraction (.mu.) Portion (weight %) ______________________________________ <3 18 to 38 <5 70 to 82 <10 93 to 99 <15 96 to 100 ______________________________________by hydrothermally crystallizing a SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O and water containing alkali aluminate, water, silicate synthesis mixture with an optional tempering step wherein in a given case during the crystallization or tempering step instead of stirring shearing forces are employed. The process comprises providing an aqueous alkali aluminate liquor having a temperature of 30.degree. to 100.degree. C. and containing 0.1 to 100 grams of Al.sub.2 O.sub.3 /l and 1 to 200 grams of Na.sub.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: December 15, 1981
    Assignee: Degussa & Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Hans Strack, Wolfgang Roebke, Dieter Kneitel, Ehrfried Parr
  • Patent number: 4303626
    Abstract: There are produced crystalline zeolite powders of Type A with the composition1.0.+-.0.2 M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5 SiO.sub.2 .multidot.y H.sub.2 Owhere M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 6.2.mu. and with a particle spectrum:______________________________________ Fraction (.mu.) Portion (weight %) ______________________________________ <3 10 to 60 <5 25 to 95 <10 80 to 99 <15 92 to 100 ______________________________________by hydrothermally crystallizing a SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O and water containing alkali aluminate, water, silicate synthesis mixture with an optional tempering step wherein in a given case during the crystallization or tempering step instead of stirring shearing forces are employed. The process comprises providing an aqueous alkali aluminate liquor having a temperature of 50.degree. to 90.degree. C. and containing 0.1 to 100 grams of Al.sub.2 O.sub.3 /l and 1 to 200 grams of Na.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: December 1, 1981
    Assignee: Degussa & Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans Strack, Wolfgang Roebke, Dieter Kneitel, Ehrfried Parr
  • Patent number: 4303628
    Abstract: There are produced crystalline zeolite powders of Type A with the composition1.0.+-.0.2 M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5 SiO.sub.2 .multidot.y H.sub.2 Owhere M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 4.9.mu. and with a particle spectrum______________________________________ Fraction (.mu.) Portion (weight %) ______________________________________ <3 10 to 60 <5 55 to 95 <10 93 to 99 <15 96 to 100 ______________________________________by hydrothermally crystallizing a SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O and water containing alkali aluminate, water, silicate synthesis mixture with an optional tempering step wherein in a given case during the crystallization or tempering step instead of stirring shearing forces are employed. The process comprises mixing with stirring (1) an aqueous alkali silicate solution and (2) an aqueous sodium hydroxide with a NaOH content of 0.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: December 1, 1981
    Assignee: Degussa & Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans Strack, Wolfgang Roebke, Dieter Kneitel, Ehrfried Parr
  • Patent number: 4303629
    Abstract: There are produced crystalline zeolite powders of Type A with the composition 1.0.+-.0.2 M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5 SiO.sub.2 .multidot.y H.sub.2 O where M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 4.0.mu. and with a particle spectrum______________________________________ Fraction (.mu.) Portion (weight %) ______________________________________ <3 35 to 60 <5 82 to 95 <10 93 to 99 <15 96 to 100 ______________________________________by hydrothermally crystallizing a SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O and water containing alkali aluminate, water, silicate synthesis mixture with optionally a tempering step wherein in a given case during the crystallization or tempering step instead of stirring shearing forces are employed. The process comprises providing an aqueous alkali silicate soluton, heating it to a temperature between 30.degree. and 80.degree. C.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: December 1, 1981
    Assignee: Degussa & Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans Strack, Wolfgang Roebke, Dieter Kneitel, Ehrfried Parr
  • Patent number: 4303627
    Abstract: There are produced crystalline zeolite powders of Type A with the composition 1.0.+-.0.2 M.sub.2/n O:Al.sub.2 O.sub.3 :1.85.+-.0.5 SiO.sub.2 .multidot.y H.sub.2 O where M is a metal cation, n is its valence and y has a value up to 6 with 50 weight % of the particles not over 5.9.mu. and with a particle spectrum______________________________________ Fraction (.mu.) Portion (weight %) ______________________________________ <3 15 to 25 <5 35 to 55 <10 80 to 94 <15 96 to 100 ______________________________________by hydrothermally crystallizing a SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O and water containing alkali aluminate, water, silicate synthesis mixture with an optional tempering step wherein in a given case during the crystallization or tempering step instead of stirring shearing forces are employed. The process comprises providing water in a container, simultaneously feeding into the water at a temperature of 30.degree. to 100.degree. C.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: December 1, 1981
    Assignee: Degussa & Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans Strack, Wolfgang Roebke, Dieter Kneitel, Ehrfried Parr