Patents Assigned to Denka Kogyo Kabushiki Kaisha
  • Patent number: 4701448
    Abstract: A metal salt of an organic phosphate, having good stability and cholesterol-lowering activity, is produced by reacting a known compound ##STR1## wherein R.sub.4 and R.sub.5 are hydrogen or methyl, with a reaction agent such as metal hydroxide.
    Type: Grant
    Filed: January 29, 1986
    Date of Patent: October 20, 1987
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Akira Endo, Haruyuki Yamashita
  • Patent number: 4637937
    Abstract: A bacteria-free foamable oil-in-water emulsion including chocolate is prepared by forming an emulsion containing (1) 5-35 wt % of oil, (2) 3-30 wt % of chocolate component, (3) 10-30 wt % of sugar component, (4) 0.5-4 wt % of sodium caseinate, (5) 0.02-0.1 wt % of phosphoric acid salt, (6) 0.05-3 wt % of stabilizer, (7) 2-6 wt % of defatted milk solid, (8) 3-10 wt % of emulsifier based on the oil and (9) 40-60 wt % of all solid components in the emulsion and by sterilizing the said emulsion by heating at ultra high temperature. The bacteria-free foamable oil-in-water emulsion including chocolate has long time stability and high foamability, and it meets the current demand for baking or confectionary products having softness and wetness.
    Type: Grant
    Filed: July 23, 1984
    Date of Patent: January 20, 1987
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Kimio Terada, Michio Mori, Yoichi Goto, Takashi Nakazawa, Kunio Muto, Shozo Usami
  • Patent number: 4613514
    Abstract: A cacao butter substitute is disclosed having a medium melting point fraction of palm oil, having a solid fat content of 70% or more at 20.degree. C., 10% or more at 30.degree. C., 1% or less at 33.degree. C. and 0% at 35.degree. C., and showing an initial curve in cooling curve which is identical down to 19.degree. C. to the initial curve of a palm soft oil having an iodine value of 65 or above in which the medium melting point fraction is removed and the high melting point fraction is completely removed. The cacao butter substitute has very sharp melting characteristics and excellent compatibility with cacao fat.
    Type: Grant
    Filed: June 25, 1984
    Date of Patent: September 23, 1986
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Shoji Maruzeni, Toshimichi Yanagihara, Nozomi Yasuda
  • Patent number: 4610802
    Abstract: Activating thiourea dioxide is characterized by incorporating in the thiourea dioxide a substance which dissolves in water or an acidic aqueous solution and produces hydrogen.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: September 9, 1986
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Koichiro Fujiyasu, Shigeki Yoneyama, Haruhiko Ito
  • Patent number: 4581152
    Abstract: Disclosed is a water-soluble coolant for formation of drawn and ironed cans, which comprises an aqueous solution containing 0.1 to 20% by weight of a phosphorus-containing compound obtained by esterifying an epoxidation product of at least one higher unsaturated fatty acid or its ester with phosphoric acid.
    Type: Grant
    Filed: July 25, 1984
    Date of Patent: April 8, 1986
    Assignees: Toyo Seikan Kaisha, Ltd., Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Hisashi Hotta, Toshiyuki Noda, Yoshiharu Tobita, Isao Watabiki, Yasu Ishimoto, Takuro Handa, Masashi Umemura
  • Patent number: 4568667
    Abstract: An aqueous preparation containing vitamin E prepared by emulsifying or solubilizing vitamin E in an aqueous phase in the presence of a saponin shows excellent transparency and thermal stability, and can be widely used in the fields of medicines, cosmetics, foodstuffs, animal feeds and the like. Quillaiasaponin is the preferred saponin.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: February 4, 1986
    Assignees: Eisai Company, Ltd., Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Yoichi Shirakawa, Makoto Itoh, Keigi Koyama, Yoshio Minowa
  • Patent number: 4396638
    Abstract: An edible emulsion having good whipping characteristics comprising an aqueous phase containing lipoprotein material and optionally lipoprotein film coated globular fat particles, and a continuous fat phase having dispersed therein globular fat particles which are coated with lipoprotein film. The emulsion consists essentially of between about 25% and 90% by weight of total fat based on the weight of the emulsion and between about 10% and 75% of total aqueous phase based on the weight of the emulsion, said total fat comprising the globular fat particles and the continuous fat phase, and said globular fats being present in an amount more than about 0.1 ml per gram of total fat when the amount of said globular fat particles is determined by the analytical procedure disclosed in the specification.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: August 2, 1983
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Edo, Yasuo Okutomi
  • Patent number: 4382147
    Abstract: 4,4'-Dihydroxydiphenyl sulfone is isolated from a mixture of dihydroxydiphenyl sulfone isomers by heat dissolving the mixture in phenol and then cooling the resulting solution thereby allowing 4,4'-dihydroxydiphenyl sulfone to precipitate as an adduct with phenol.
    Type: Grant
    Filed: September 9, 1981
    Date of Patent: May 3, 1983
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Hirotsugu Kitamura, Yasumasa Shimizu, Osami Ohura
  • Patent number: 4244690
    Abstract: According to this invention, there is provided an improved method of dyeing fibrous products characterized in that, in the dyeing of fibrous products using an oxidation-reduction dyeing type dye and an aqueous alkali solution of thiourea dioxide as a reducing solution, the reduction of the dye with the said aqueous alkali solution of thiourea dioxide is carried out in the presence of one or more substances selected from the group consisting of saturated aliphatic ketones having 3 to 10 carbon atoms, saturated aliphatic ketocarboxylic acids having 3 to 10 carbon atoms and alicyclic ketones having 3 to 10 carbon atoms.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: January 13, 1981
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Kazuyoshi Kushibe, Masaru Nishii, Yasuhiro Kanaya, Yasumasa Kawabe
  • Patent number: 4240791
    Abstract: According to this invention, there is provided a method of dyeing fibrous products characterized in that, in the dyeing of fibrous products using an oxidation-reduction dyeing type dye and an aqueous alkali solution of thiourea dioxide as a reducing solution, the reduction of the dye with the said aqueous alkali solution of thiourea dioxide is carried out in the presence of one or more dialdehyde compounds selected from dialdehyde compounds represented by the general formulaOHC--R--CHO (I)in which R is a saturated or unsaturated aliphatic or aromatic organic compound radical.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: December 23, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Kazuyoshi Kushibe, Masaru Nishii, Yasuhiro Kanaya, Yasumasa Kawabe
  • Patent number: 4238411
    Abstract: According to this invention there is provided a method of recovering thiourea dioxide characterized in that in the production of thiourea dioxide by the reaction of thiourea and hydrogen peroxide in an aqueous solvent, the waste liquor after separation of the crystals of thiourea dioxide after reaction is treated with an ion-exchange resin to remove side reaction products and impurities contained therein, and is then concentrated with a reverse-osmotic membrane to crystallize the thiourea dioxide dissolved therein.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: December 9, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Osami Ohura, Osamu Fujimoto
  • Patent number: 4235812
    Abstract: According to this invention there is provided a process for preparing thiourea dioxide characterized in that in the production of thiourea dioxide by the reaction of thiourea and hydrogen peroxide in an aqueous solvent, ammonium bicarbonate is added to the reaction solution at a proper time.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: November 25, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Osamu Fujimoto, Jiro Watanabe, Kazuyoshi Kushibe
  • Patent number: 4233238
    Abstract: According to this invention there is provided a process for preparing thiourea dioxide characterized in that in the production of thiourea dioxide by the reaction of thiourea and hydrogen peroxide in an aqueous solvent, the filtrate after separation of the crystals of thiourea dioxide after reaction is treated with an ion-exchange resin to remove side reaction products and impurities contained therein and then is used again as a reaction solvent.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: November 11, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Osami Ohura, Osamu Fujimoto
  • Patent number: 4197256
    Abstract: According to this invention, there is provided a method of stabilizing an alkaline aqueous solution of thiourea dioxide characterized in that one or more substances selected from the group consisting of aliphatic ketones, alicyclic ketones and aliphatic dialdehydes are added to the said alkaline aqueous solution of thiourea dioxide.
    Type: Grant
    Filed: February 15, 1979
    Date of Patent: April 8, 1980
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Kanji Sato, Kazuyoshi Kushibe, Masaru Nishii, Yasuhiro Kanaya, Yasumasa Kawabe
  • Patent number: 4137136
    Abstract: This invention relates to a method for electrolyzing an alkali metal halide aqueous solution in a three-chamber horizontal type electrolytic cell which comprises a top cathode chamber bounded by a cation exchange membrane, a middle chamber, and a bottom anode chamber bounded by a diaphragm. Halogen gas and dilute alkali metal halide solution are taken out of the anode chamber in such a manner as to make the anode chamber work as a gas chamber.
    Type: Grant
    Filed: October 12, 1977
    Date of Patent: January 30, 1979
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Tadao Ueda, Teruo Nagaya, Koji Kawada
  • Patent number: 4097478
    Abstract: According to the present invention, there is provided a process for preparing pyrazines characterized in that a diol represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen atom or a hydrocarbon radical, and a diamine represented by the formula ##STR2## wherein R.sub.3 and R.sub.4 are each a hydrogen atom or a hydrocarbon radical, are subjected to a gas phase contact reaction in the presence of a zinc-containing catalyst.
    Type: Grant
    Filed: March 31, 1977
    Date of Patent: June 27, 1978
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventor: Kanji Sato
  • Patent number: 4040863
    Abstract: In the surface treatment of copper and its alloys with an acidic aqueous solution of hydrogen peroxide, methylcyclohexanol or cyclohexanol or both of the two are added to the solution thereby inhibiting the hindering action of chlorine ion in removal of metals and oxide scales by dissolution.
    Type: Grant
    Filed: October 26, 1976
    Date of Patent: August 9, 1977
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventor: Koji Kitamura
  • Patent number: 3957442
    Abstract: Glycerol dichlorohydrin is prepared by dissolving allyl chloride vapor in an upwardly flowing aqueous stream, dissolving chlorine gas in a separate second upwardly flowing aqueous stream to form a hypochlorous acid solution, mixing the two streams and flowing them downwardly in a reaction column where they react to form glycerol dichlorohydrin.
    Type: Grant
    Filed: October 31, 1974
    Date of Patent: May 18, 1976
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Hiroaki Yamamoto, Hideo Harada, Hiroshi Miyaoka, Minoru Tanaka, Osamu Kubota, Shizuo Nakamura, Yasusi Nakamura
  • Patent number: 3948703
    Abstract: This invention provides a method of chemically polishing copper and copper alloys which comprises using a solution with one or more members selected from azoles having the structure represented by the general formulae ##SPC1##Wherein X, X' and X" represent any of hydrogen, amino, aminoalkyl containing 1-3 carbon atoms and alkyl containing 1-3 carbon atoms added to an acid aqueous solution of hydrogen peroxide containing hydrogen peroxide and sulfuric or nitric acid.
    Type: Grant
    Filed: November 26, 1973
    Date of Patent: April 6, 1976
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventor: Kazuyoshi Kushibe
  • Patent number: 3948795
    Abstract: This invention provides a method for activating peroxides, particularly hydrogen peroxide or hydrogen peroxide adducts and for thereby furnishing the said peroxides with excellent bleaching effects, cleaning effects, and sterilizing effects at low temperatures, by adding to the said peroxides an aromatic compound containing in the molecule one or several groups represented by the formula ##EQU1## wherein R is a substituted or unsubstituted monovalent aromatic group and X is either CO or SO.sub.2. The activation according to this invention is preferably carried out in an aqueous solution at a pH value ranging from 7 to 11, at a temperature below 40.degree.C.
    Type: Grant
    Filed: December 21, 1973
    Date of Patent: April 6, 1976
    Assignee: Tokai Denka Kogyo Kabushiki Kaisha
    Inventors: Yasumasa Kawabe, Masaaki Suzuki