Abstract: An electrochemical storage device which has electrode plates of different polarity which are alternately stacked on one another to form an electrode stack. Each of the electrode plates is formed from an electrode framework with a current-collecting lug arranged thereon. Identically polarized current-collecting lugs of an electrode stack are connected in an electrically conductive fashion to a terminal yoke. In order to ensure better welding, the terminal yoke has at the location of the current-collecting lugs a transverse slot into which the free end region of a current-collecting lug projects. The current-collecting lug is attached to the terminal yoke on the flat side that is remote from the electrode stack.

Abstract: An electrochemical storage device and a process for making the same has electrode plates of differing polarity which are stacked one upon the other. Each one of the electrode plates exhibits a metallized electrode structure and a current tapping vane which is resistant to bending and which is electrically conductively secured to a welding margin of the electrode structure. The same-polarity current tapping vanes of the electrode plates are electrically connected to a connecting strap extending parallel to the electrode plate stack and within the storage device housing. In order that, inter alia, the service life of the electrochemical storage device should be increased, the current tapping vanes disposed at the electrode structures are permanently shaped in accordance with their installation position essentially only outside the welding margin, in such a manner that in the installed condition they are free from mechanical stresses in the region of the welding margin onto the electrode structure.

Abstract: An electrode plate is formed from a porous electrode framework with welded-on current discharge lug for use in electrochemical storage cells. The electrode framework is formed from metallized plastic and has a current discharge lug welded on in a unilateral and overlapping manner on the weld-on edge of the electrode framework. The material thickness of the current discharge lug decreases in the weld-on end towards the weld-on edge. The material of the electrode framework assigned to the weld-on end of the current discharge lug is compressed in the region of the overlap. For greater stability of the welding, the weld-on end of the current discharge lug is formed by teeth spaced apart from one another by teeth interspaces. The teeth interspaces are at least wide enough that, when there is pressing during the welding on of the current discharge lug, the material of the electrode framework can swell between the teeth.

Abstract: An aqueous cadmium oxide paste of high flowability for the vibration filling of foam-structure and fiber-structure electrode plaques is characterized by a cadmium oxide content of about 25 to 35% by volume, a pH of about 10 to 12.5, a content of about 0.5 to 2.5% by weight, based on cadmium oxide, of one or more dispersants from the group comprising the water-soluble salts of polyphosphoric acids, di- and polyphosphonic acids and their derivatives, gluconic acid or of antimonyl tartrate. The paste has a plastic viscosity of about 0.1 to 1 Pa.s and also a yield value of between about 10 and 120 Pa. This cadmium oxide paste makes it possible to fill foam-structure and fiber-structure electrode plaques completely in one operation.

Abstract: A process and apparatus for the hermetic adhesive bonding of plastic casing parts of a battery or of a galvanic cell. The casing comprises a plastic casing container and a top or bottom of the same type of plastic, preferably of polyamide, which are adhesively bonded to each other by means of a pair of joining surfaces. For adhesive bonding, the joining surface of one of the two parts is wetted at specific locations with a solvent dissolving the plastic, preferably with formic acid, over a time period of 5 to 7 seconds. The joining surface is aired at room temperature in still air over a time period of about 15 to 25 seconds, and the casing parts are then joined to each other and pressed together with pressure maintained over a time period of about to 5 to 10 minutes.

Abstract: An electrode matrix with hollow or fibrous structure made of metallized and, optionally, subsequently removed plastic fibers, and a current-collector lug welded-on on one side for electrochemical storage cells. The current-collector lug overlaps the electrode matrix at the periphery on one side, the latter being compressed in the vicinity of the overlap in such a way that the current-collector lug remains within the nominal thickness of the electrode matrix. The current-collector lug has, in the overlap region, a plurality of material projections which project in the direction of the electrode matrix, whose diameters correspond at least approximately to the material thickness of the current-collector lug and which are pressed into the electrode matrix, each material projection pressed into the electrode matrix still remaining, however, completely inside the electrode matrix even at the point of its highest elevation.

Abstract: A method and apparatus for filling fibrous-structure electrode plaques for rechargeable batteries with an active compound paste, with simultaneous sizing of the plaque. The fibrous-structure electrode plaque is fed by means of a conveyor device to a roll mill whose roll nip is uniformly filled with a flowable active compound paste over the nip width. As the plaque passes through the roll nip, it is filled with active compound paste from both sides, simultaneously sized for thickness, its surface is smoothed and excess paste is removed from the main surface.

Abstract: A battery box for a plurality of electrochemical cells which are arranged in rows one behind the other, a circulating-flow channel being formed by a spacing of the cells from one another within each row, through which a fluid can flow. The circulating-flow channels are all fluidically connected to an inlet channel which tapers in the flow direction and is arranged in the vicinity of the box bottom, and to an outlet channel which expands in the flow direction and is arranged in the vicinity of the box lid. To secure the individual cells, the side walls are provided, in the vicinity of the box bottom, with step-type ledges on which the cells are arranged in a vertically staggered manner in the vicinity of their bottom side edges. The slope of the ledges corresponds in magnitude and direction to the taper of the inlet channel on the bottom side, and the width of a step of the ledge corresponds to the depth of the housing of a cell, plus the corresponding clearance of the circulating-flow channel.

Abstract: An alkaline nickel-cadmium storage battery in which the active material with which the negative electrode is filled with, or the electrolyte in the storage battery, contains polyvinylpyrrolidone as an expander. Polyvinylpyrrolidone compounds having a mean molecular weight of 5,000 to 35,000 g/mol have proved particularly advantageous.

Abstract: A process treats the waste water which accumulates as used activation solution in the one-step activation, on the basis of acidic palladium/tin solutions, of large-surface plastic substrates, in particular of non-woven fabric, needled felt or open-pored foam sheets, for the purpose of a subsequent chemical metallization. A concentrate composed of palladium chloride and sodium chloride and then a solid tin salt in a molar ratio of 1:1.5 to 1:4, based on the palladium, is added to the waste water. After a certain maturing time, a ready-to-use activation solution is again obtained for activating a plastic substrate and reduces the amount of the waste water hitherto accumulating after the activation has taken place.

Abstract: A nickel-cadmium storage battery with improved electrical properties is described in which one or more copolymers of vinyl pyrrolidone is/are added as expander to the active material with which the negative electrode is filled or to the electrolyte. The polymers have a mean molecular weight of 10,000 g/mol to 100,000 g/mol, with a vinyl pyrrolidone content of between 5 and 95 mol-%. The copolymers are added to the active material or to the electrolyte in an amount of 0.1 to 1.0% by weight, based on the active material. As a result of adding the copolymers, a malfunction-free operation of the storage battery is achieved, accompanied by a simultaneously equally as good degree of utilization of the cadmium active material compared with a storage battery which contains homopolymeric polyvinyl pyrrolidone.

Abstract: A process manufacturing positive and negative fiber structure electrodes for open as well as gastight electrochemical current sources, particularly nickel-cadmium accumulators. After the filling of the calibrated plate with an active mass and the subsequent drying of the plate filled with a moist a mass, the plate is calibrated again by means of calibrating presses or calibrating rollers. The calibrating plates or rollers are cleaned to remove adhering or deposited active mass or other dirt by means of ductors or rotating brush rollers while being at the same time subjected to suction. Thus electrodes are created which have plane surfaces for cells for the highest standards with respect to the individual active components and the mounted stack in the given dimensions.

Abstract: A paste for vibration filling of foam-structure or fiber-structure electrode plates for galvanic cells, particularly for electrical accumulators, said paste having an active substance content of about 25 to 60 percent by volume, a maximum active particle size of about 0.04 mm and in an unvibrated state a yield value of approximately 10 to 120 Pa and a plastic viscosity of about 1.0 to 1.0 Pas at 20.degree. C. The paste is preferably set in vibration with a frequency of about 40 to 125 Hz and an amplitude of about 0.1 to 1.5 mm by a vibration transmitter fitted inside a tank containing the paste.

Abstract: A fiber structure electrode plaque for accumulators made from a needle felt web made of synthetic fibers which, after activation, is chemically metallized, and galvanically reinforced by being metal-plated. The needle felt web has a weight per unit area of between 50 and 150 g/m.sup.2 with a porosity of from 60 to 96%, the synthetic fibers having a diameter of from 10 to 30 .mu.m, and the length of the staple fibers amounting to from 20 to 40 mm. Over its whole surface, the needle felt web is needled from both sides and has a nominal thickness of from 0.5 to 1.0 mm.

Abstract: A method and apparatus for vibration-filling electrodes in a paste bath. A holding tool connected to a vertical rotary shaft carries the electrode and, arranged above it, a vibration reflection body. The electrode and vibration reflection body are immersed in the paste bath, filling of the electrode is carried out, and the holding tool, electrode and reflection body are withdrawn from the paste path. Above the paste bath, the excess paste is spun off the electrode by rotating the vertical rotary shaft, the reflection body also being cleaned of the paste.

Abstract: A process and device provide for the virtually continuous vibration filling with active compound of empty fiber structure electrode plaques having a welded-on current discharge lug for electric accumulators. The empty fiber structure electrode plaques are inserted into a transport device having an adjustable cycle time which passes the plaques through a trough filled with active compound in which the active compound is vibrated. The fiber structure electrode plaques are then removed from the trough, excess active compound is stripped off, sides and the edges of plaque are freed from residues of excess active compound by various brushes. The filled fiber structure electrode plaque is then removed from the transport device, after prior drying, if required.

Abstract: An apparatus for the chemical metallization of open-pored foams, nonwovens, needle felts of plastic material or similar textile material, in particular those having a porosity of 45 to 98%, has three processing stations. The first processing station is a laying station, the second is a chemical metallization station and the third is a centrifugal station. The material of the substrate webs treated in the apparatus is made of polypropylene, polyethylene, polyamide, polyester or aminoplasts.

Abstract: A simple device for the vibration filling of porous fiber structure electrode plaques for voltaic cells includes a vibrating plate having a principal extension arranged substantially vertical within a filling chamber. An electrode plaque is arranged with a principal surface substantially parallel to the principal surface of the vibrating plate at a distance of about 2 to 50 mm from the vibrating plate (when swung in to the maximum extent). The distance of the vibrating plate from the base of the filling chamber is at least about 1 mm. It is possible to fill a series of electrode plaques with one charge of the filling chamber, the filling operation for the electrode plaque proceeding very rapidly and with considerably less noise then known devices, in which the entire filling vessel is vibrated.

Abstract: A process for washing and rinsing substrate sheets, in particular of nonwoven fabric or needle-punched felt sheets, is used after previously carried out activation and electroless chemical metallization. The pores or the surfaces of the substrate sheets are adequately freed from the salt residues of the metallizing solution. In this process, the textile material is wound spirally onto the rotor of a drum, and the washing or rinsing water is fed into the textile material via a hollow shaft of the rotor. The washing, rinsing, and spinning operations proceed in one apparatus, resulting in an appreciable savings in the amounts of water supplied. The entire washing and spinning operations in the drum lends itself to complete automation.

Abstract: An electroplating rack for the electrochemical surface treatment of metallic substrates or metallized plastic substrates is described. The metallic rack is, moreover, covered with an insulating layer of enamel, contact points being left bare at which the substrate to be treated is connected in an electrically conducting manner to the rack during the electroplating process.