Abstract: A liquid coating composition of matter for application to wooden barrels or casks used in distilling, the composition of matter includes a polymer vulcanized with a silane crosslinking agent that is oxime-functional, acetoxy-functional, or alkoxy-functional, an OH-terminated polysiloxane that exhibits moisture curing, condensation reactions when in the presence of water vapors and silane crosslinkers, a low to medium molecular weight polysiloxane that exhibits low-permeance after curing via moisture-cure, condensation reaction, a transition metal catalyst that provides a reaction crosslink density that allows for minimal transport of ethanol vapors and water vapors after curing, a second transition metal catalyst that provides a reaction crosslink density with minimal impact on the rate of oxygen gas transport rate after curing, and inorganic polymers with a siloxane backbone that exhibits no leaching, migration or notable reaction with a liquid alcohol and water mixture upon curing.