Patents Assigned to Diafloc Co., Ltd.
  • Patent number: 5296577
    Abstract: There is disclosed a process for producing an acrylamide polymer which comprises polymerizing acrylamide monomer alone or a monomer mixture composed of 50 mole % or more of acrylamide monomer and a monomer capable of copolymerizing with acrylamide monomer in the presence of an azo series polymerization initiator and 0.1% by weight or more of 2-mercaptobenzothiazole or a salt thereof based on the weight of the monomer in an aqueous medium having a pH of 6 or higher at a temperature range of 5 to 100.degree. C., and then drying the resulting material.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: March 22, 1994
    Assignees: Diafloc Co., Ltd., Nitto Chemical Industry Co., Ltd.
    Inventors: Hitoshi Tamura, Teruzo Otsuka, Shoichi Kanda, Masaharu Nagahama
  • Patent number: 4734238
    Abstract: The invention relates to a process for producing a powder of a cationic polymer by spreading on a moveable carrier a layer of an aqueous solution of a vinyl monomer, carrying out continuous polymerization followed by peeling off hydrous polymer from the carrier in a hot state, and cutting said hydrous polymer in a hot state by a shearing stress.
    Type: Grant
    Filed: March 20, 1986
    Date of Patent: March 29, 1988
    Assignees: Mitsubishi Rayon Co., Ltd., Nitto Chemical Indutry Co., Ltd., Diafloc Co., Ltd.
    Inventors: Teruhiko Sugimori, Hideaki Habara, Ken-ichi Inukai, Akihisa Furuno
  • Patent number: 4535131
    Abstract: Polyacrylamide in the form of aquagel is partially hydrolyzed in such a manner that small pieces of the aquagel are mixed with an alkali agent in a specified quantity and maintained at a temperature of 50.degree. to 95.degree. C. until the hydrolysis reaches substantial completion. The quantity of the alkali agent is that corresponding to 1/1.1 to 1/3 of the hydrolysis percentage desired of the final partially hydrolyzed polyacrylamide. The partially hydrolyzed polyacrylamide thus produced is characterized by uniform hydrolysis evidenced by its improved solubility in water and a pH around 7 of its aqueous solution. The term "aquagel" is herein used interchangeably with a term "hydrogel".
    Type: Grant
    Filed: April 2, 1984
    Date of Patent: August 13, 1985
    Assignees: Nitto Kagaku Kabushiki Kaisha, Mitsubishi Rayon Co., Ltd., Diafloc Co., Ltd.
    Inventors: Ryoji Handa, Jun Hosoda, Norimasa Yoshida
  • Patent number: 4514551
    Abstract: A process for preparing a cationic polymer which comprises polymerizing a monomer mixture containing acrylamide and a cationic alkenyl monomer represented by the general formula: ##STR1## wherein R.sup.1 represents H or CH.sub.3 ; R.sup.2 and R.sup.3 represent independently CH.sub.3 or C.sub.2 H.sub.5 ; R.sup.4 represents H, CH.sub.3, C.sub.2 H.sub.5 or a benzyl group; A represents --OC.sub.n H.sub.2n -- (wherein n=2 or 3), ##STR2## or --NC.sub.n H.sub.2n -- (wherein n=2 or 3); and X.sup.- represents Cl.sup.-, Br.sup.-, I.sup.-, CH.sub.3 SO.sub.4.sup.-, C.sub.2 H.sub.5 SO.sub.4.sup.-, 1/2SO.sub.4.sup.-- or CH.sub.3 COO.sup.-, in the form of a sheet in an aqueous medium, characterized in that the composition ratio of acrylamide/cationic alkenyl monomer is within the range of 95/5 to 5/95, and the polymerization is carried out in the presence of a phosphite. The polymers obtained according to this process are free from insolubles produced under the influence of oxygen.
    Type: Grant
    Filed: January 23, 1984
    Date of Patent: April 30, 1985
    Assignees: Nitto Chemical Industry Co., Ltd., Mitsubishi Rayon Co., Ltd., Diafloc Co., Ltd.
    Inventors: Akihisa Furuno, Kenichi Inukai, Yasuo Ogawa
  • Patent number: 4455411
    Abstract: Acrylamide polymers having remarkably high molecular weights can be obtained by polymerizing acrylamide or a monomer mixture comprising a preponderant quantity of acrylamide in an aqueous medium with the use of a specific redox initiator and a specific azo compound initiator. The polymerization initiator used in this porcess comprises a combination of a persulfate, formaldehyde sodium sufoxylate and 2,2'-azobis-2-amidinopropane.
    Type: Grant
    Filed: June 14, 1983
    Date of Patent: June 19, 1984
    Assignees: Nitto Kagaku Kogyo Kabushiki Kaisha, Mitsubishi Rayon Co., Ltd., Diafloc Co., Ltd.
    Inventors: Ryoji Handa, Jun Hosoda, Kenzo Ariyama, Osamu Okushima, Nobuo Kurashige
  • Patent number: 4313863
    Abstract: When an alkaline substance is added to and mixed with aggregates of the mutually adhering blobs of a hydrogel of an acrylamide polymer, (1) a mixing tank in which the portion to be contacted with the hydrogel of an acrylamide polymer is made of a chromium-plated material is used, and (2) to said hydrogel aggregates is added at least one compound represented by the general formulae: ##STR1## wherein R.sub.1 is a residue obtained by removing two OH groups from a saturated dihydric alcohol having 2 to 4 carbon atoms, and R.sub.2 is a residue obtained by removing three OH groups from a saturated trihydric alcohol having 3 to 6 carbon atoms, and having an average molecular weight of 500 to 5,000, whereby the hydrolysis of the acrylamide polymer can be achieved at a high efficiency while preventing the mutual adhesion of the hydrogel aggregates and also reducing the adhesion of the aggregates to the interior surface of the mixing tank to such an extent that there is substantially no problem of adhesion.
    Type: Grant
    Filed: November 28, 1980
    Date of Patent: February 2, 1982
    Assignees: Nitto Chemical Industry Co. Ltd., Mitsubishi Rayon Co., Ltd., Diafloc Co., Ltd.
    Inventors: Ryoji Handa, Norimasa Yoshida, Jun Hosoda, Akihisa Furuno
  • Patent number: 4306045
    Abstract: In the production of a dried acrylamide polymer by polymerizing, in an aqueous medium, acrylamide alone or a monomer mixture comprising 50 mole % or more of acrylamide and at least one monomer copolymerizable therewith with a radical initiator, and then drying the resulting hydrous acrylamide polymer, the allowing of 2-mercaptobenzimidazole to be present in the drying step or a step prior thereto enables the dried acrylamide polymer having a high molecular weight and a good dissolvability in water to be obtained.
    Type: Grant
    Filed: June 2, 1980
    Date of Patent: December 15, 1981
    Assignees: Nitto Chemical Industry Co., Ltd., Mitsubishi Rayon Co., Ltd., Diafloc Co., Ltd.
    Inventors: Norimasa Yoshida, Yasuo Ogawa, Ryoji Handa, Jun Hosoda, Nobuo Kurashige, Akihisa Furuno
  • Patent number: 4165419
    Abstract: A method for producing a water-soluble cationic polymer by polymerizing, in the presence of water, a high concentration of (a) at least one vinyl monomer represented by the following general formula (I)ch.sub.2 .dbd.cr.sub.1 coor.sub.2 n.sup..sym. r.sub.3 r.sub.4 r.sub.5 x.sup..crclbar. (i)wherein R.sub.1 is --H or --CH.sub.3 ; R.sub.2 is --CH.sub.2 CH.sub.2 -- or --CH.sub.2 CH(OH)CH.sub.2 --; R.sub.3 and R.sub.4, which may be the same or different, each is --CH.sub.3 or --CH.sub.2 CH.sub.3 ; R.sub.5 is --C.sub.n H.sub.2n+1 where n is 0 or an integer of 1 to 4, --CH.sub.2 C.sub.6 H.sub.5, or --CH.sub.2 COOH; and X is Cl.sup.-, Br.sup.-, 1/2SO.sub.4.sup.-- or CH.sub.3 SO.sub.4.sup.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: August 21, 1979
    Assignees: Nitto Chemical Industry Co., Ltd., Mitsubishi Rayon Co., Ltd., Diafloc Co., Ltd.
    Inventors: Naoyuki Suzuki, Yoji Wada, Akihisa Furuno, Iwao Ohshima, Yukio Shibuya