Patents Assigned to Dic-Hercules Chemicals, Inc.
  • Patent number: 5270355
    Abstract: A paper coated resin has been provided which simultaneousy provides coated papers with improved ink receptivity, water resistance and blister resistance in a good balance. The resin is obtainable by introducing alicyclic amino and/or alicyclic epoxy compounds into a polyalkylenepolyamine-urea-aldehyde(epihalohydrin) resin or by introducing alicyclic amino and/or alicyclic epoxy compounds into a polyalkylenepolyamine-urea-aldehyde(epihalohydrin) resin and/or an amine-epihalohydrin resin and reacting or mixing these resins.
    Type: Grant
    Filed: January 13, 1992
    Date of Patent: December 14, 1993
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventors: Hiroharu Kawano, Satoshi Takizawa, Hiroki Owaki, Haruka Hirayama
  • Patent number: 5229504
    Abstract: There is disclosed a process for preparing a sulfonated chitosan wherein C3/C6-position hydroxyl groups are selectively sulfonated with inexpensive sulfonating agents which comprises dissolving or swelling chitosan in an acetic acid in water, regenerating chitosan with an alkaline aqueous solution, washing the regenerated chitosan with water and then with alcohol, immersing the chitosan in a polar solvent and pressing the solvent out of the same and sulfonating the chitosan with SO.sub.3 -DMF complex or ClHSO.sub.3an -DMF complex in a non-polar solvent. Separation of the product can be easily effected by way of filtration and the like.
    Type: Grant
    Filed: September 6, 1991
    Date of Patent: July 20, 1993
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventor: Jisuke Hayashi
  • Patent number: 5115065
    Abstract: A papermaking additive useful for papermaking in a neutral to alkaline pH region, which comprises as an active component a water-soluble copolymer comprising as constituent monomers (a) 0.1 to 20 mole % of a specific bisquaternary ammonium (meth)acrylamide, (b) 0 to 20 mole % of a specific acrylamide or acrylic ester derivative such as an aminoalkyl (meth)acrylamide or an aminoalkyl (meth)acrylate, or a salt thereof, (c) 50 to 99.9 mole % of acrylamide and/or methacrylamide, and (d) 0 to 10 mole % of an alpha,beta-unsaturated carboxylic acid and/or a salt thereof. The additive increases paper strength and filler retention and size retention.
    Type: Grant
    Filed: March 9, 1988
    Date of Patent: May 19, 1992
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventors: Masatomi Ogawa, Mitsuhiro Murata
  • Patent number: 5079303
    Abstract: A surface treatment agent for paper comprising a quaternized product of a copolymer containing at least (a) styrene and/or a styrene derivative and (b) N,N-dialkylaminoalkyl (meth) acrylamide is disclosed. This surface treatment agent is excellent in slip prevention and sizing effect, the sizing effect not being impaired at a pH over 7.
    Type: Grant
    Filed: July 12, 1989
    Date of Patent: January 7, 1992
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventors: Tsuyoshi Ikeda, Toshiyuki Hakata, Tsugumi Ikegaya
  • Patent number: 5013775
    Abstract: A novel paper sizing composition comprising a ketene dimer and a hydrophilic vinyl polymer containing an alkylmercaptan having 6-22 carbon atoms. The composition has excellent storage and mechanical stability and sizing effect.
    Type: Grant
    Filed: April 27, 1989
    Date of Patent: May 7, 1991
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventors: Hideo Oikawa, Masatomi Ogawa, Kiyoshi Iwai, Mayumi Narushima
  • Patent number: 4943608
    Abstract: A rosin emulsion sizing agent comprising a fortified rosin, an at least partially quarternized product copolymer principal consisting of a (meth)acrylic acid alkylaminoalkyl ester or amide monomer and water exhibits excellent sizing effect in a papermaking system of higher pH, higher water hardness and higher temperature, in which conventional anionic rosin emulsion sizing agents cannot effectively function.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: July 24, 1990
    Assignee: Dic-Hercules Chemicals, Inc.
    Inventors: Mizunori Takahashi, Tsuyoshi Ikeda, Yoshiharu Yamaguchi
  • Patent number: 4717758
    Abstract: A papermaking additive useful for papermaking in a neutral to alkaline pH region which comprises a water-soluble copolymer comprising (a) 1 to 20 mole % of dimethylaminopropyl (meth)acrylamide or its quaternized product, (b) 0.1 to 12 mole % of itaconic acid or its salt, and (c) 98.9 to 68 mole % of acrylamide, the (b)/(a) mole ratio being from 0.1 to 0.6.
    Type: Grant
    Filed: August 21, 1986
    Date of Patent: January 5, 1988
    Assignee: DIC-Hercules Chemicals, Inc.
    Inventors: Masatomi Ogawa, Mayumi Narushima
  • Patent number: 4681909
    Abstract: A rosin emulsion sizing agent comprising 20 to 50% by weight of fortified rosin, 2 to 30% by weight of a saponification product of a styrene/acrylic acid copolymer or a styrene/methacrylic acid copolymer, and the remainder being water.
    Type: Grant
    Filed: October 22, 1985
    Date of Patent: July 21, 1987
    Assignee: Dic-Hercules Chemicals, Inc.
    Inventors: Koji Ohta, Masaaki Yoshimura, Mizunori Takahashi
  • Patent number: 4654386
    Abstract: A ketene dimer aqueous dispersion for paper sizing comprising a ketene dimer compound, an acrylamide type polymer having cationic groups and optionally an anionic dispersant and an aqueous medium is disclosed. This dispersion has a ketene dimer content as high as about 25 -30% and good storage stability.
    Type: Grant
    Filed: September 4, 1985
    Date of Patent: March 31, 1987
    Assignee: Dic-Hercules Chemicals, Inc.
    Inventors: Tetsuya Hara, Toshiyuki Hakata, Keigo Goshiki