Abstract: Polyaspartic acid is produced by thermal condensation of ammonium maleate derived from maleic acid and ammonia. Solid ammonium maleate in particulate form is heated to a temperature of at least about 170.degree. C. to effect thermal condensation to a polysuccinimide which is then base hydrolyzed to a polyaspartic acid salt.
Abstract: .beta.-Polyaspartic acid having a weight average molecular weight of 1000 to 5000 produced by hydrolysis of anhydropolyaspartic acid exhibits a high degree of calcium carbonate and calcium phosphate inhibition.
Type:
Grant
Filed:
January 26, 1994
Date of Patent:
December 13, 1994
Assignee:
Donlar Corporation
Inventors:
Larry P. Koskan, Kim C. Low, Abdul R. Y. Meah, Anne M. Atencio
Abstract: Water-soluble poly(organic acids) having a molecular size of more than 1,500 Daltons enhance fertilizer uptake and promote plant growth. Particularly suitable for this purpose are the poly(amino acids) such as poly(aspartic acid) and copolymers thereof.
Type:
Grant
Filed:
November 5, 1992
Date of Patent:
September 27, 1994
Assignee:
Donlar Corporation
Inventors:
Alan M. Kinnersley, Larry P. Koskan, David J. Strom, Abdul R. Y. Meah
Abstract: Polyaspartic acid having a weight average molecular weight of 1000 to 5000 is produced by hydrolysis of anhydropolyaspartic acid that has been produced by condensation polymerization of L-aspartic acid. Conversion in excess of 80 percent is achievable utilizing "temperature vs. time" profiles.
Type:
Grant
Filed:
June 21, 1993
Date of Patent:
May 24, 1994
Assignee:
Donlar Corporation
Inventors:
Larry P. Koskan, Kim C. Low, Abdul R. Y. Meah, Anne M. Atencio
Abstract: Production of polysuccinimide by reacting maleic anhydride and ammonia at elevated temperatures. The base hydrolyzed polyaspartic acid product.
Abstract: Water soluble salts of a .beta.-polyaspartic acid, i.e., a polyaspartic acid having predominantly beta linkages in the amino acid residue chain thereof, are eminently well suited as dispersants for particulate matter in an aqueous medium.
Abstract: Polyaspartic acid having a weight average molecular weight of 1000 to 5000 is produced by hydrolysis of anhydropolyaspartic acid. Anhydropolyaspartic acid is produced by condensation polymerization of L-aspartic acid. Greater than 80% conversion is achievable utilizing "temperature vs time" profiles.
Type:
Grant
Filed:
February 22, 1991
Date of Patent:
June 22, 1993
Assignee:
Donlar Corporation
Inventors:
Larry P. Koskan, Kim C. Low, Abdul R. Y. Meah, Anne M. Atencio
Abstract: A method of producing high molecular weight polysuccinimide and high molecular weight polyaspartic acid. Reacting maleic anhydride with ammonia and further reacting with polymerized polysuccinimide. Hydrolyzing the resultant product to form polyaspartic acid.
Abstract: .beta.-Polyaspartic acid having a weight average molecular weight of 1000 to 5000 produced by hydrolysis of anhydropolyaspartic acid, exhibits a high degree of calcium carbonate and calcium phosphate inhibition.
Type:
Grant
Filed:
March 19, 1991
Date of Patent:
October 6, 1992
Assignee:
Donlar Corporation
Inventors:
Larry P. Koskan, Kim C. Low, Abdul R. Y. Meah, Anne M. Atencio
Abstract: Polyaspartic acid as a calcium sulfate and barium sulfate inhibitor. Generally all forms of polyaspartic acid can be used. .beta.-polyaspartic acids are preferred.