Abstract: A vessel for storing and/or processing polymer particulates includes main outer walls defining an upper end, a lower end, and a main interior space, a frustum-shaped outlet region positioned below the lower end of the main outer walls, a plurality of internal frustum sections positioned within the main outer walls, where a lower portion of each internal frustum section defines a passage extending through each of the plurality of internal frustum sections, an internal member including an internal member wall defining an internal member interior space separated from the main interior space, the internal member positioned within the main outer walls and extending from the upper end to the lower end of the main outer walls, the internal member extending through each passage of the plurality of internal frustum sections, and a purge gas source in communication with the internal member inner space.

Abstract: Embodiments are directed to catalyst systems comprising a metal-ligand complex procatalyst, a Lewis base, and an activator, wherein the activator comprises an anion and a cation, the anion having a structure according to formula (I).

Abstract: Embodiments of the present disclosure are directed towards methods of enhanced oil recovery from a subterranean reservoir, the method includes co-injecting a gas and a foam formulation into the subterranean reservoir, wherein the gas comprises steam and the foam formulation comprises a sulfonate composition, a glycol compound, and water.

Abstract: A film structure including: (a) at least one functionalized film layer, wherein the at least one film layer comprises a polar-reactive group polyolefin layer used as an internal layer in the film structure; and (b) a lamination adhesive composition present on, and in contact with, a least a portion of a surface of the internal layer; wherein the green tack value of the adhesive composition is greater than 0.772 Newtons/centimeter; a laminate including the above film structure bonded to a substrate layer; a process for producing the film structure; a process for producing the laminate; and a laminated article made from the above laminate.

Abstract: A method of making a homogeneous mixture of polyolefin solids and liquid additive without melting the polyolefin solids during the making. The method comprises applying acoustic energy at a frequency of from 20 to 100 hertz to a heterogeneous mixture comprising the polyolefin solids and the liquid additive for a period of time sufficient to substantially intermix the polyolefin solids and the liquid additive together and while maintaining temperature of the heterogeneous mixture above the freezing point of the at least one liquid additive and below the melting temperature of the polyolefin solids, thereby making the homogeneous mixture without melting the polyolefin solids.

Abstract: Embodiments of the present disclosure are directed towards methods of making an alkylated metallocene having one or more tetrahydropentalenyl groups, the method comprising: reacting a chloride compound with a lithium compound to make a reaction mixture comprising an intermediate dichloride compound; and reacting the intermediate dichloride compound with an alkylating agent to make the alkylated metallocene having one or more tetrahydropentalenyl groups, wherein the dichloride compound is not isolated from the reaction mixture, wherein the lithium compound is represented by: wherein R1, R2, R3, R4, and R5 are each independently H or a (C1-C4) alkyl.

Abstract: Methods for preparing end-functionalized polyolefin, The methods include polymerizing one or more olefin monomers in the presence of an aluminum chain transfer agent to produce a polymeryl aluminum species; treating the polymeryl aluminum species with sulfur oxide compound at a reactor temperature to form a polymeryl sulfinate; and oxidizing the polymeryl sulfinate; wherein the end-functionalized polyolefin comprises a polymer backbone having at least 30 carbon atoms; and the end-functionalized polyolefin comprises a sulfur containing group,

Abstract: A polyurethane adhesive composition, such as a two-component polyurethane adhesive, including (A) at least one isocyanate group-containing component including at least one isocyanate group-containing compound; and (B) at least one polyol component including: (Bi) at least one polyester polyol compound; and (Bii) at least one phosphate ester polyol compound; and a process for making the above composition.

Abstract: A method of making a homogeneous mixture of polyolefin solids and a particulate solid additive without melting the polyolefin solids or the particulate solid additive during the making. The method comprises applying acoustic energy at a frequency of from 20 to 100 hertz to a heterogeneous mixture comprising the polyolefin solids and the particulate solid additive for a period of time sufficient to substantially intermix the polyolefin solids and the particulate solid additive together and while maintaining temperature of the heterogeneous mixture below the melting point of the at least one particulate solid additive and below the melting temperature of the polyolefin solids, thereby making the homogeneous mixture without melting the polyolefin solids or the at least one particulate solid additive.

Abstract: A carbon molecular sieve (CMS) membrane may advantageously be made by pyrolyzing a membrane precursor composition comprised of a carbon forming polymer (e.g., polyimide) blended with a polyvinylidene chloride copolymer (PVDC), the polyvinylidene chloride copolymer being the reaction product of at least 60% to 97% by weight of vinylidene chloride and at least one other comonomer and the carbon forming polymer to polyvinylidene chloride copolymer has a weight ratio of greater than 1 to 99. The membrane precursor composition may be formed by dissolving the carbon forming polymer and PVDC in a solvent to form a dope solution. The dope solution may be shaped, for example, into an asymmetric hollow fiber. The asymmetric hollow fiber may be heated to a temperature to dehydrochorinate the PVDC and then subsequently heated in a non-oxidizing atmosphere to carbonize the polymers of the shaped membrane to form the CMS membrane.

Abstract: Embodiments are directed to catalyst systems comprising: a procatalyst; and a co-catalyst dissolved in a non-halogenated aprotic hydrocarbon solvent, the co-catalyst comprising: a non-coordinating borate dianion having the formula: (III) and two cations, each cation being independently chosen from a cation according to formula (I) or formula (II).

Abstract: Embodiments of the present invention relate to multilayer structures and articles formed therefrom. In one aspect, a multilayer structure comprises (a) a biaxially oriented polyethylene film comprising a linear low density polyethylene having a density of 0.910 to 0.

Abstract: A polyolefin-polydiorganosiloxane block copolymer may be prepared by Piers-Rubinsztajn reaction.

Abstract: A multilayer foam panel member including: (a) at least one top sheet substrate; (b) at least one bottom sheet substrate; and (c) a middle substrate of foam material disposed inbetween, and integral with, the top and bottom sheet substrates; wherein the foam material is produced by dispensing a reactive foam-forming fluid mixture onto a moving or stationary bottom sheet substrate of a foam manufacturing line; and wherein the foam manufacturing line includes a flexible film fluid dispensing device for dispensing the reactive foam-forming fluid mixture onto the moving or stationary bottom sheet substrate to form a multilayer foam panel member; wherein the middle substrate of foam material of the panel member has improved thermal and mechanical properties; and a process for manufacturing the above multilayer foam panel member.

Abstract: A process for preparing C2 to C4 hydrocarbons includes introducing a feed stream including hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor, and converting the feed stream into a product stream including C2 to C4 hydrocarbons in the reaction zone in the presence of a formed hybrid catalyst. The formed hybrid catalyst includes a metal oxide catalyst component including gallium oxide and zirconia, a microporous catalyst component that is a molecular sieve having 8-MR (Membered Ring) pore openings, and a binder including alumina, zirconia, or both.

Abstract: Composites having a polymer or natural leather skin layer and a polyurethane foam layer are made in a molding process. The polyurethane foam layer is made from a foam formulation that includes certain polyester polyols. The presence of the polyester polyol improves flow characteristics of the foam formulation. The foam so produced has unexpectedly low quantities of VOCs.

Abstract: Phenyl isocyanates are removed from a solvent stream obtained from an MDI and/or PMDI manufacturing process by reaction in the presence of a carbodiimidization catalyst to form the corresponding N,N-diphenylcarbodiimides. The N,N-diphenylcarbodiimides can be recycled into the MDI and/or PMDI manufacturing process where they can react with MDI and/or PMDI to form uretonimines. The uretonimines have at most minimal effect on the properties and usefulness of the MDI and/or PMDI product and so can be left in the MDI and/or PMDI product.

Abstract: A method of making a homogeneous mixture of polyolefin solids and carbon solids without melting the polyolefin solids during the making. The method comprises applying acoustic energy at a frequency of from 20 to 100 hertz to a heterogeneous mixture comprising the polyolefin solids and the carbon solids for a period of time sufficient to substantially intermix the polyolefin solids and the carbon solids together while maintaining temperature of the heterogeneous mixture below the melting temperature of the polyolefin solids, thereby making the homogeneous mixture without melting the polyolefin solids.

Abstract: A composition comprising the following components: A) a first ethylene/alpha-olefin interpolymer with a melt index I2A; B) a second ethylene/alpha-olefin interpolymer with a melt index I2B; and wherein the difference in melt index (I2): (I2A?I2B)?400, and wherein I2B?100 g/10 min; C) a filler, and wherein the filler is present in an amount ?50 wt %, based on the weight of the composition; D) a tackifier; and wherein the melt viscosity, at 165 C, of the composition, excluding the filler (component C), is ?30,000 cP.

Abstract: A method for preparing C2 to C5 paraffins includes introducing a feed stream including hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. Converting the feed stream into a product stream including C2 to C5 paraffins in the presence of a hybrid catalyst. The hybrid catalyst includes a microporous catalyst component; and a metal oxide catalyst component selected from (A) a bulk material consisting of gallium oxide, (B) gallium oxide present on a titanium dioxide support material, and (C) a mixture of gallium oxide and at least one promoter present on a support material selected from Group 4 of the IUPAC periodic table of elements.