Abstract: Flexible polyurethane foams are made by reacting a hydrophilic quasi-prepolymer, water and a polymer polyol in the presence of a silicone surfactant and an ethylene oxide/higher alkylene oxide block copolymer. The foams exhibit desirably low densities and compression sets, and have good thermal and moisture-wicking properties. The foams are useful in bedding and other comfort applications in which they are exposed to body heat and bear at least a portion of the weight of the user. The thermal and moisture wicking properties contribute to perceived comfort for the user.

Abstract: A spray-dried zirconocene catalyst system comprising a zirconocene catalyst and a hydrophobic fumed silica, which supports the zirconocene catalyst. A spray-drying method of making same. Polyolefins; methods of making and using same; and articles containing same.

Abstract: According to at least one embodiment of the present disclosure, a multilayer elastic film comprises a core layer, a first outer layer, and a second outer layer. The core layer comprises at least 75 wt % polyolefin elastomer such as an ethylene/alpha-olefin block copolymer or a propylene-based plastomer. The first outer layer and the second outer layer each comprise at least 75 wt % of an ethylene-based copolymer, wherein the ethylene-based copolymer is selected from the group consisting of: (I) greater than 50 wt % of ethylene, from 5 to 16 wt % of an ?,?-ethylenically unsaturated C3-C8 carboxylic acid, and optionally, from 0.5 to 10 wt % of an alkyl acrylate; (II) from 86 to 95 wt % of ethylene, and from 5 to 14 wt % of an alkyl acrylate; and (III) combinations thereof.

Abstract: A method for processing a chemical stream includes contacting a feed stream with a catalyst in a reactor portion of a reactor system that includes a reactor portion and a catalyst processing portion. The catalyst includes platinum, gallium, or both and contacting the feed stream with the catalyst causes a reaction which forms an effluent stream. The method includes separating the effluent stream from the catalyst, passing the catalyst to the catalyst processing portion, and processing the catalyst in the catalyst processing portion. Processing the catalyst includes passing the catalyst to a combustor, combusting a supplemental fuel in the combustor to heat the catalyst, treating the heated catalyst with an oxygen-containing gas to produce a reactivated catalyst, and passing the reactivated catalyst from the catalyst processing portion to the reactor portion. The supplemental fuel may include a molar ratio of hydrogen to other combustible fuels of at least 1:1.

Abstract: A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.

Abstract: Embodiments of the present disclosure directed towards synthetic lubricant compositions. In various embodiments, the present disclosure provides a synthetic lubricant compositions including an aromatic amine antioxidant comprising 0.25 to 5 weight percent of a total weight of the synthetic lubricant composition, dithiocarbamate antioxidant comprising 0.25 to 5 weight percent of the total weight of the synthetic lubricant composition, and a polyalkylene glycol PAG comprising 99.25 to 85 weight percent of the total weight of the synthetic lubricant composition, where the synthetic lubricant composition has a total acidic number (TAN) increase of 2 milligrams of potassium hydroxide per gram of the synthetic lubricant composition over 27 days or greater as measured in accordance with modified ASTM D-664, and where the synthetic lubricant composition does not include any of a Group I, II, III, IV base oil.

Abstract: A method for producing an optical waveguide by: (a) depositing a first composition: (i) a polysiloxane comprising epoxy and alkenyl groups with refractive index no greater than 1.50, (ii) a compound comprising at least one epoxy group and refractive index no greater than 1.49, and (iii) a polysiloxane having refractive index at least 1.50; (iv) a photo acid generator; (v) a hydrosilylation catalyst, (vi) an inhibitor for hydrosilylation; (b) curing by exposure to ultraviolet light; (c) removing the uncured portion to produce a patterned core layer; (d) after a time from 20 to 300 hours depositing a second composition comprising: (i) a polysiloxane comprising epoxy groups with refractive index no greater than 1.49, and (ii) a compound comprising at least two epoxy groups with a refractive index no greater than 1.49 and an alcohol having refractive index no more than 1.45 (iii) at least one photo acid generator.

Abstract: A polyethylene composition comprising (A) an ethylene-based (co) polymer, (B) a styrenic unit-containing copolymer, and (C) a polyorganosiloxane. Also a method of making the composition; a crosslinked polyethylene product made by curing the composition; manufactured articles comprising a shaped form of the inventive composition or product; and methods of using the inventive composition, product, or articles.

Abstract: Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one cyclic 1,3-diketone compound, at least one aminoalcohol or alkylhydroxylamine and an alkali metal, phosphonium or ammonium sulfite. Foams so produced emit low levels of formaldehyde, acetaldehyde, acrolein and propionaldehyde.

Abstract: A method for processing a chemical stream includes contacting a feed stream with a catalyst in an upstream reactor section of a reactor having the upstream reactor section and a downstream reactor section, passing an intermediate product stream to the downstream reactor section, and introducing a riser quench fluid into the downstream reactor section, upstream reactor section, or transition section and into contact with the intermediate product stream and the catalyst to slow or stop the reaction. The method includes separating at least a portion of the catalyst from the product stream, passing the product stream to a product processing section, cooling the product stream, and separating a portion of the riser quench fluid from the product stream. The riser quench fluid separated from the product stream may be recycled back to the downstream reactor section, upstream reactor section, or transition section as the riser quench fluid.

Abstract: According to one or more embodiments of the present disclosure, chemical streams may be processed by a method which may comprise operating a first chemical process, stopping the first chemical process and removing the first catalyst from the reactor, and operating a second chemical process. The reaction of the first chemical process may be a dehydrogenation reaction, a cracking reaction, a dehydration reaction, or a methanol-to-olefin reaction. The reaction of the second chemical process may be a dehydrogenation reaction, a cracking reaction, a dehydration reaction, or a methanol-to-olefin reaction. The first reaction and the second reaction may be different types of reactions.

Abstract: The present disclosure provides a method for sealing a fitment to a flexible container. In an embodiment, the method includes placing a fitment into the neck of a four panel flexible container formed from flexible film. The process includes complementarily aligning a multiseal around a base of the fitment. The process includes providing a plurality of primary seals (and flaps), secondary seals, and tertiary seals onto the base with respective primary sealing jaws, secondary sealing jaws, and tertiary sealing jaws to form the multiseal, wherein the secondary seals overlap the primary seals, and the tertiary seals overlap the primary seals and the secondary seals.

Abstract: Processes of polymerizing olefin monomers using catalyst systems and catalysts systems that include a procatalyst having a structure according to formula (I): (I).

Abstract: A polyisocyanate component, a polyurethane foaming system, and an article made therefrom, wherein the polyisocyanate component includes (a) a preformed mixture including an aromatic oxazolidone compound that is the reaction product of at least one aromatic epoxide and at least one first polyisocyanate having an average isocyanate functionality of no more than 2.7 and greater than 1.8, in the presence of at least one catalyst, the aromatic oxazolidone compound includes at least one free isocyanate group and at least one aromatic oxazolidone group, the aromatic oxazolidone group includes an aromatic group and an oxazolidone group, and (b) at least one second polyisocyanate has an average isocyanate functionality equal to or greater than 2.7 and less than 6.0. The second polyisocyanate is added to the preformed mixture to form the polyisocyanate component. The polyisocyanate component has a viscosity of no more than 4.0 Pa-sat 25° C.

Abstract: The present invention provides a flexible wrapping material comprising a coolant gel composition comprising, i) at least one hydrophilic polyurethane prepolymer, ii) a coolant agent, iii) water, and iv) thermally conductive filler.

Abstract: A carbon molecular sieve (CMS) membrane having improved separation characteristics for separating olefins from their corresponding paraffins is comprised of carbon with at most trace amounts of sulfur and a transition metal, wherein the transition metal is one or more of a group 4-10 and 12 transition metal. The CMS membrane may be made by pyrolyzing a precursor polymer devoid of sulfur in which the precursor polymer has had a transition metal incorporated into it. The pyrolyzing for the precursor having the transition metal incorporated into it is performed in a nonoxidizing atmosphere and at a heating rate and temperature such that the metal has a valence greater than zero (i.e., not metal bonded) to a valence desirably closer to its maximum valence.

Abstract: An (electron beam)-curable (EBC) formulation comprising an EBC polyolefin compound having a crystallinity of from 0 to less than 50 weight percent (wt %) and/or having a density of 0.930 gram per cubic centimeter (g/cm3) or less; and an alkenyl-functional monocyclic organosiloxane (“silicon-based coagent”). Also included are a cured polyolefin product prepared by electron-beam irradiating the EBC formulation; methods of making and using the EBC formulation or cured polyolefin product; and articles containing or made from the EBC formulation or cured polyolefin product.

Abstract: Recyclable, all-polyethylene laminate film structures suitable for use in a flexible packaging are disclosed. The structures comprise a film layer consisting essentially of an ethylene-based polymer and a barrier adhesive layer disposed on a surface of the film layer, wherein the structure has an oxygen transmission rate not greater than 100 O2/m2/day, measured according to ASTM Method D3985. Recyclable, all-polyethylene laminate film structures suitable for use in a flexible packaging are disclosed comprising (A) a sealant film layer consisting essentially of an ethylene-based polymer, (B) an intermediate film layer consisting essentially of an ethylene-based polymer, (C) a structural film layer consisting essentially of an ethylene-based polymer, and (D) a barrier adhesive layer, wherein the recyclable, all-polyethylene laminate film structure has an oxygen transmission rate not greater than 100 O2/m2/day, measured according to ASTM Method D3985.

Abstract: A filling composition comprises (A) a mineral oil having a kinematic viscosity from 80 cSt to 100 cSt at 40° C.; (B) a styrene-ethylene/propylene diblock copolymer; and (C1) a propylene/ethylene copolymer having a weight average molecular weight (Mw) from 5,000 to 200,000 or (C2) an ethylene/propylene copolymer having a weight average molecular weight (Mw) from 5,000 to 200,000. The filling composition is used as a filling composition in a buffer tube.

Abstract: Embodiments of thermoplastic bags which yield elasticity and stiffness include a first drawtape disposed within the first channel, wherein the first drawtape comprises a linear low density polyethylene having a density of from 0.902 g/cc to 0.920 g/cc, and a second drawtape disposed within the second channel, wherein the second drawtape comprises a high density polyethylene having a density of from 0.940 g/cc to 0.965 g/cc.