Abstract: A reaction system for forming a step-growth polymerized sulfur-containing polyester polyol includes at least one sulfur-containing component selected from the group of a sulfur-containing polyol or a sulfur-containing polycarboxylic acid, an amount of the at least one sulfur-containing component being from 1 wt % to 60 wt %, at least one aromatic component selected from the group of an aromatic multi-functional ester, an aromatic multi-functional carboxylic acid, and an aromatic anhydride, an amount of the at least one aromatic component being from 1 wt % to 60 wt %, at least one simple polyol that excludes sulfur and is different from the sulfur containing polyol, an amount of the at least one simple polyol being from 0 wt % to 60 wt %, and at least one polymerization catalyst. The reaction system for forming the sulfur-containing polyester polyol has a sulfur content that is from 2 wt % to 20 wt %.

Abstract: Adhesion promoter systems and methods of producing same, the systems including the admixing product of at least 60 percent by weight of a first functionalized polyolefin, and less than 40 percent by weight of a second functionalized polyolefin, based on the total weight of the solid content, and one or more solvents. The second functionalized polyolefin includes homopolymers of propylene or copolymers of propylene with hexene, octene and/or other alpha-olefins. The homopolymers or copolymers have a single unsaturation a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone. The succinic anhydride substitution ranges from about 5 to about 45 weight percent of second functionalized polyolefin.

Abstract: The surface of a carbon fiber is electrochemically treated by a method to form nitrogen containing groups on the surface of the carbon fiber. The method comprises contacting a carbon fiber surface with an aqueous solution comprised of a non-cyclic aliphatic amine and water soluble inorganic hydroxide with said aqueous solution having a pH of at least 9. A positive electrical bias is then applied to the carbon fibers in the aqueous solution relative to another electrode in contact with the aqueous solution, wherein the positive electrical bias is at a voltage above the oxidation potential of water. The treated carbon fibers are useful for making epoxy reinforced carbon fiber composites.

Abstract: An insulation box of an insulating barrier in a liquefied gas carrier includes a box structure that includes a bottom panel, a top panel, external pillars, and optionally at least one internal partition that define at least one void. The at least one void includes at least one multilayer insulation board. Each of the at least one multilayer insulation board includes at least one facer layer, at least one first polyurethane layer having a first density from 100 kg/m3 to 2000 kg/m3 according to ASTM D 1622, and at least one second polyurethane layer having a second density of less than 100 kg/m3 according to ASTM D 1622.

Abstract: A film includes 20.0 weight percent to 69.5 weight percent of a linear low density polyethylene (LLDPE) based polymer. The LLDPE having a high density fraction (HDF) from 3.0% to 8.0%, an I10/I2 ratio from 5.5 to 6.9, and a short chain branching distribution (SCBD) of less than or equal to 8.0° C. The film also includes 0.0 weight percent to 10.0 weight percent low density polyethylene (LDPE) based polymer, and 30.0 weight percent to 70.0 weight percent pore former.

Abstract: A process for converting a feed stream having carbon to C2 to C5 olefins, includes introducing a feed stream including methane and oxygen to a first reaction zone, reacting the methane and oxygen in the first reaction zone to form a first reaction zone product stream having a mixture of C2 to C5 alkanes, transporting the mixture of C2 to C5 alkanes to a second reaction zone, introducing a fresh stream of at least one of ethane and propane to the second reaction zone, converting the C2 to C5 alkanes to C2 to C5 olefins in the second reaction zone, producing one or more product streams in the second reaction zone, where a sum of the one or more product streams includes C2 to C5 olefins, and producing a recycle stream comprising hydrogen in the second reaction zone, where the recycle stream is transported to the first reaction zone.

Abstract: A two-component adhesive composition is disclosed. The adhesive composition comprises an isocyanate component comprising an isocyanate-terminated prepolymer that is the reaction product of a polyisocyanate and an isocyanate reactive component having an average molecular weight less than 1,500. The NCO content of the isocyanate component without solvent is between 9 and 18%. The composition further comprises a polyol component comprising a polyester polyol having a molecular weight greater than 1,500 that is the reaction product of a polyhydric alcohol and a polybasic acid. The composition still further comprises an adhesion promoter. The average functionality of the adhesive composition is from 2 to 2.4. The adhesive composition provides for improved performance and processability at a solid content greater than 45 wt %. A methods of forming the adhesive composition is also disclosed. A laminate formed by this method is also disclosed.

Abstract: The present invention provides uniaxially oriented films and packages formed from such films. In one aspect, a uniaxially oriented film comprises (a) a first layer including (i) a first composition including an ethylene-based polymer prepared in the presence of a single-site catalyst, wherein the first composition has a density of 0.935 g/cm3 to 0.965 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, and (ii) a Ziegler-Natta catalyzed ultra low density polyethylene having a density of 0.880 g/cm3 to 0.912 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, (b) a second layer including at least one polyolefin, and (c) at least one inner layer between the first layer and the second layer including a high density polyethylene. The film is oriented in the machine direction at a draw ratio of between 4:1 and 10:1, and can exhibit a machine direction 2% secant modulus of 85,000 psi or more when measured as per ASTM D882.

Abstract: A mixture of octanols, nonanols and decanols is useful for the preparation of alkoxylates, which alkoxylates may be used as surfactants, which surfactants have surprisingly good biodegradability.

Abstract: Embodiments are directed to monophosphaguanidine ligands and the bis ligated metal-complexes formed therefrom, wherein the metal-ligand complexes are polymerization catalysts comprising the following structure (I).

Abstract: An adhesive formulation comprising a) a polyurethane composition; and b) a latent catalyst which is the reaction product of i) an amidine-containing compound, a guanidine-containing compound, or an amine-containing compound; ii) carbon dioxide; and iii) water, an alcohol, an amine, or a thiol, is disclosed.

Abstract: A composition and a method for preparing a polymer composite article. The composition comprises (A) a filler in an amount of from 10 to 90 wt. The composition also comprises (B) a polymer in an amount of from 10 to 90 wt %, wherein the (B) polymer is selected from polyolefins, polyamides, polyesters, or combinations thereof. Further, the composition comprises (C) an organopolysiloxane in an amount of from greater than 0 to 10 wt. %; the (C) organopolysiloxane having at least one silicon-bonded hydroxyl group and a viscosity of from 1,000 to 60,000 mPa·s at 25° C. The ranges for components (A)-(C) are based on the total weight of components (A), (B) and (C) in the composition.

Abstract: A process for preparing C2 to C5 paraffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2 to C5 paraffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component.

Abstract: The present disclosure relates to an olefin polymerization catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract: Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: Formula I.

Abstract: A heterogeneous catalyst comprising a support and a noble metal. The catalyst has an average diameter of at least 200 microns and at least 90 wt % of the noble metal is in the outer 50% of catalyst volume.

Abstract: An ethylene-based resin comprising a high molecular weight component and a low molecular weight component, wherein the high molecular weight component comprises an ethylene/alpha-olefin copolymer or ethylene homopolymer, and has a density ranging from 0.940 g/cc to 0.960 g/cc, and a high load melt index (I21.6) ranging from 4 g/10 min to 15 g/10 min, and wherein the ethylene-based resin has: an overall density ranging from greater than 0.955 to less than or equal to 0.970 g/cc, an overall melt index (I2.16) ranging from 0.5 g/10 min to 7 g/10 min, and less than 0.2 vinyls per 1000 carbon atoms.

Abstract: The present disclosure provides for an aqueous coating composition to coat and form a film on porous construction materials to help in controlling efflorescence in the porous construction materials. The aqueous coating composition includes a binder having an acrylic polymer in an acrylic polymer waterborne dispersion, wherein the acrylic polymer has a glass transition temperature (Tg) of 1° C. to 60° C.; and an alkoxy silane coalescing agent in a waterborne silane coalescing emulsion. The aqueous coating composition optionally further includes an additive selected from the group consisting of a pigment, a filler and combinations thereof. In one embodiment, the alkoxy silane coalescing agent provides the only coalescing agent for the acrylic polymer waterborne dispersion in the aqueous coating composition.

Abstract: Embodiments of the present disclosure are directed towards foam formulations that include a high functionality polyether polyol, an aromatic polyether polyol, an amine initiated aliphatic polyether polyol, and a diol.

Abstract: According to one or more embodiments presently disclosed, a method for processing a chemical stream may include contacting a feed stream with a catalyst in a reactor portion of a reactor system that includes a reactor portion and a catalyst processing portion. Contacting the feed stream with the catalyst may cause a reaction forming an effluent. The method may include separating the effluent stream from the catalyst, passing the catalyst to the catalyst processing portion, and processing the catalyst in the catalyst processing portion. Processing the catalyst may include passing the catalyst to a combustor, combusting a supplemental fuel stream in the combustor to heat the catalyst, and treating the heated catalyst with an oxygen-containing gas. The supplemental fuel stream may include at least 1 mol % of one or more hydrocarbons, and a weight ratio of catalyst to hydrocarbons in the combustor may be at least 300:1.