Abstract: The present invention relates to method for the preparation of a particulate reversibly-crosslinked polymeric material comprising: treating a particulate water-soluble hydroxyl-functional polymer in a liquid phase comprising a solvent mixture in that the hydroxyl-functional polymer is insoluble containing an organic solvent and water; a tetracarboxylic acid dianhydride represented by formula (I), 10 (I) wherein: U and V are independently selected from CH, N and P; 15 X is selected from a single bond, a saturated divalent (C1-C10) hydrocarbon group, O, S, NR, and PR, wherein R is selected from hydrogen and (C1-C4) alkyl; n and m are independently selected from 0 and 1; w is 1 or 2 with the proviso that; 20 if w is 1 then Y is X and if w is 2 then Y is selected from H and (C1-C4) alkyl, whereby there is no bond between both Y; and optionally a catalyst; to form a particulate reversibly-crosslinked polymeric material and 25 to a particulate reversibly-crosslinked polymeric material obtainable thereby.
Abstract: The present invention relates to the use of particular blends of LLDPE and LDPE together with specific fabrication conditions to make foamed sheets of thin gauge with MD tear properties similar to an equivalent gauge non-foamed sheet of the same composition. In particular, blends which combine a high MI LLDPE rich fraction with a low MI branched LDPE minor fraction provide the adequate balance of mechanical strength of the polymer base with its melt strength, extensibility and stress relaxation, allowing a thin foam film with MD tear strength which is comparable to non foamed counterparts of similar gauge and composition. The foamed films of the present invention are thin (generally from about 1 to 10 mils thick), and have an MD tear strength of at least about 160 grams for a 3 mil film as measured by ASTM D 1922. The foamed films of the present invention are preferably made at least in part from blends which comprise from 10 to 95 percent by weight of LLDPE having a relatively high (1.
Abstract: A diblock copolymer blend containing a unique combination of an ordered poly(styrene)-b-poly(methyl methacrylate) diblock copolymer and a disordered poly(styrene)-b-poly(methyl methacrylate) diblock copolymer is provided. Also provided are substrates treated with the diblock copolymer blend.
Type:
Grant
Filed:
February 10, 2012
Date of Patent:
August 20, 2013
Assignee:
Dow Global Technologies LLC
Inventors:
Rahul Sharma, Valeriy V. Ginzburg, Phillip D. Hustad, Jeffrey D. Weinhold
Abstract: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; and; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145° C.) and 1H-NMR (125° C.), (2) a graft polymer to enhance the adhesion, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.
Type:
Application
Filed:
June 6, 2011
Publication date:
August 15, 2013
Applicant:
Dow Global Technologies LLC
Inventors:
John A. Naumovitz, Rajen M. Patel, Shaofu Wu, Debra H. Niemann
Abstract: A method of continuously manufacturing organometallic compounds is provided where two or more reactants are conveyed to a reactor having a laminar flow contacting zone, a heat transfer zone, and a mixing zone having a turbulence-promoting device; and causing the reactants to form the organometallic compound.
Type:
Application
Filed:
August 15, 2012
Publication date:
August 15, 2013
Applicants:
Rohm and Haas Electronic Materials LLC, Dow Global Technologies Inc.
Inventors:
Ravindra S. Dixit, Hua Bai, Curtis D. Modtland, Robert A. Ware, John G. Pendergast, JR., Christopher P. Christenson, Deodatta Vinayak Shenai-Khatkhate, Artashes Amamchyan, Kenneth M. Crouch, Robert F. Polcari
Abstract: A method of continuously manufacturing an organometallic compound is provided where two or more reactants are conveyed to a contacting zone of a reactor in a manner so as to maintain a laminar flow of the reactants; and causing the reactants to form the organometallic compound.
Abstract: The disclosure is directed to a plasticizer system with improved electrical properties. The plasticizer system includes (a) a primary plasticizer consisting of an epoxidized vegetable oil and (b) a secondary plasticizer consisting of an epoxidized fatty acid ester, where the primary plasticizer is present in an amount greater than 50% by weight of the total plasticizer system weight.
Type:
Application
Filed:
November 3, 2011
Publication date:
August 15, 2013
Applicant:
Dow Global Technologies LLC
Inventors:
Robert F. Eaton, Abhijit Ghosh-Dastidar, Jeffrey M. Cogen, Bharat I. Chaudhary, Caroline H. Laufer
Abstract: A synergistic antimicrobial composition containing a glyphosate compound and one of 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one or 2-n-octly-4-isothiazolin-3-one or N-Butyl-1,2-benzisothiazolin-3-one is provided. Also provided is a method of inhibiting the growth of or controlling the growth of microorganisms in a building material by adding such a synergistic antimicrobial composition. Also provided is a coating composition containing such a synergistic antimicrobial composition, and a dry film made from such a coating composition.
Abstract: A tubesheet, modules incorporating tubesheets and methods for making and using the same. In one embodiment the invention includes a tubesheet comprising: i) a plurality of aligned semi-permeable hollow fiber membranes each comprising a cylindrical porous structure surrounding a lumen and extending between a first and second end and further comprising a first segment located adjacent the first end and a second segment located adjacent to the second end and ii) a block of potting material including an interfacial surface. The first segment of the hollow fiber membrane is embedded within the block of potting material and the second segment extends from the interfacial surface of the block. The tubesheet further comprises a penetrating extension of potting material within the porous structure of the second segment of the hollow fiber membrane that extends along a length from the interfacial surface of the block to a distal end.
Type:
Grant
Filed:
September 28, 2010
Date of Patent:
August 13, 2013
Assignee:
Dow Global Technologies LLC
Inventors:
Scott T. Burr, Peter E. M. Aerts, Gavin D. Vogel, David J. Moll
Abstract: The instant invention is a device for producing dispersions. The device for producing dispersions includes a first stator, a second stator, a shell encasing the first stator and the second stator, a rotor being disposed therebetween the first stator and the second stator thereby forming a first chamber and a second chamber, at least one first inlet port into the first chamber, and at least one outlet port out of the second chamber. The device may optionally include at least one additional second inlet port into the second chamber.
Type:
Grant
Filed:
September 5, 2012
Date of Patent:
August 13, 2013
Assignee:
Dow Global Technologies LLC
Inventors:
Kenneth W. Skaggs, Bedri Erdem, Paul A. Gillis
Abstract: Polyolefin dispersions, froths, and foams and articles manufactured therefrom are disclosed. Also disclosed is a method for generating a thermoplastic foam from an aqueous dispersion. The aqueous dispersion may include a thermoplastic resin, water, and a stabilizing agent. The method may include adding at least one frothing surfactant to the aqueous dispersion to form a mixture, adding a flame retardant and/or a phase change material, frothing the mixture to create a froth, and removing at least a portion of the water to produce the foam.
Abstract: A synergistic antimicrobial composition containing a glyphosate compound and diiodomethyl-p-tolylsulfone is provided. Also provided is a method of inhibiting the growth of or controlling the growth of microorganisms in a building material by adding such a synergistic antimicrobial composition. Also provided is a coating composition containing such a synergistic antimicrobial composition, and a dry film made from such a coating composition.
Abstract: The present disclosure is directed to the production of 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate and the purification thereof. Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1,2-phenylene dibenzoate are provided. The precursor is 5-tert-butyl-3-methylcatechol.
Type:
Grant
Filed:
December 31, 2009
Date of Patent:
August 13, 2013
Assignee:
Dow Global Technologies LLC
Inventors:
Tak W. Leung, Gary A. Roth, Tao Tao, Kuanqiang Gao, Linfeng Chen
Abstract: The present invention relates to devices, particularly photovoltaic devices, incorporating Group IIB/VA semiconductors such phosphides, arsenides, and/or antimonides of one or more of Zn and/or Cd. In particular, the present invention relates to methodologies, resultant products, and precursors thereof in which electronic performance of the semiconductor material is improved by causing the Group IIB/VA semiconductor material to react with at least one metal-containing species (hereinafter co-reactive species) that is sufficiently co-reactive with at least one Group VA species incorporated into the Group IIB/VA semiconductor as a lattice substituent (recognizing that the same and/or another Group VA species also optionally may be incorporated into the Group IIB/VA semiconductor in other ways, e.g., as a dopant or the like).
Type:
Grant
Filed:
June 15, 2011
Date of Patent:
August 13, 2013
Assignees:
Dow Global Technologies LLC, California Institute of Technology
Inventors:
Gregory M. Kimball, Marty W. DeGroot, Nathan S. Lewis, Harry A. Atwater
Abstract: Processes and apparatus for purifying brine are provided including (1) providing an aqueous brine solution comprising one or more inorganic salts and one or more organic compounds and (2) conducting at least one unit operation for removing organic compounds from the brine solution to obtain a purified brine solution.
Type:
Grant
Filed:
August 18, 2008
Date of Patent:
August 6, 2013
Assignee:
Dow Global Technologies LLC
Inventors:
Bruce Hook, Dan Tirtowidjojo, Anil Mehta
Abstract: Stannous oxide particles having a methane sulfonic acid dissolution rate of 3.56 g stannous oxide in 8.1 g of 70% methane sulfonic acid of 30 seconds at a temperature of 20 to 25° C. are disclosed, including methods of making them. Also disclosed are packaged stannous oxide particles that reduce the formation of stannic oxide on the surface of the particles over time.
Abstract: A compound of formula M(AlH3OR1)y, wherein R1 is phenyl substituted by at least one of: (i) an alkoxy group having from one to six carbon atoms; and (ii) an alkyl group having from three to twelve carbon atoms; wherein M is an alkali metal, Be or Mg; and y is one or two.
Type:
Grant
Filed:
March 22, 2011
Date of Patent:
August 6, 2013
Assignees:
Rohm and Haas Company, Dow Global Technologies LLC
Inventors:
Nathan Tait Allen, Robert Butterick, III, Arthur Achhing Chin, Dean Michael Millar, David Craig Molzahn
Abstract: The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species amine complex and in the second part one or more compounds capable of free radical polymerization and a cure accelerator comprising a) at least one compound containing a quinone structure or b) at least one compound containing at least one aromatic ring and one or more, preferably two substituents on the aromatic ring selected from hydroxyl, ether and both, where there are two substituents they are located either ortho or para with respect to one another and a peroxide containing compound. The second part may further contain an agent capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprises one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts.