Abstract: A polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1?), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2?), and units (3) derived from ethylene (3?), the polymer comprising at least 75 mole % of units (1), from 0.01 to 5 mole % of units (2), and up to 20 mole % of units (3), the polymer having a branching factor BF 0.75.
Type:
Grant
Filed:
June 13, 2002
Date of Patent:
March 20, 2007
Assignee:
Dow Global Technology Inc.
Inventors:
Daniel J Arriola, Francis J. Timmers, David D. Devore, Oscar D. Redwine
Abstract: A process for producing olefin polymers, which comprises the steps of polymerizing an olefin monomer in a polymerization zone in the presence of a catalyst comprising a transition metal compound to form an olefin polymer, and adding at the end of or downstream from the polymerization zone a composition having a weight averaged molecular weight of at least 100 and containing a group R, a cation Y, an anionic group —C(R1)2—X?, and optionally a group —C(R1)2—X—H, the composition having a relative the composition having a relative mole fraction n of cations Y and a relative mole fraction m of group —C(R1)2—X—H, wherein 0<n?1, 0??m<1, and n+m=1. Use of such m=1. Use of such a composition for rendering inert undesired quantities of acidic compounds or halogen-containing compounds present in an olefin polymer by mixing the olefin polymer intimately with the additive composition.
Type:
Grant
Filed:
December 13, 2002
Date of Patent:
March 20, 2007
Assignee:
Dow Global Technologies Inc.
Inventors:
Pascal E. R. E. J. Lakeman, Johan A. Thoen
Abstract: Single component compositions for making a moisture-cured polyurethane foam are disclosed. Foam produced from the compositions of the present invention produce very low foaming pressure due to their 60-95 percent open-cell content. After these compositions are applied and cure, they form a permanent seal around the perimeter of installed fenestration products.
Type:
Application
Filed:
October 10, 2006
Publication date:
March 8, 2007
Applicant:
Dow Global Technologies Inc.
Inventors:
Robert Braun, Deborah Schutter, Jess Garcia
Abstract: The invention is directed to a polypropylene resin, which is suitable for manufacturing an air quenched blown film. The resin has a melt flow rate of greater than 5 g/10 min, less than 2% xylene solubles, a pentad isotacticity of greater than 95%, an isotactic pentad/triad ratio of greater than 95%, a crystallinity of at least 65%, and a crystallization temperature of at least 127° The polypropylene resin contains from 500 ppm to 2500 ppm of a nucleator/clarifier additive. A quenched blown film made from resin exhibits a crystallization onset temperature of at least 116° C. and a crystallization half-life time of less 4.1 seconds or less when tested using fast DSC analysis with a scan rate of 200° C./minute.
Abstract: A method is provided for making an automobile assembly having a molded plastics structural member and a reinforcing member in which a polymerisable adhesive is employed to bond the two members together and an automobile assembly having a bonded structural member and a reinforcing member. The assembly is suitably used as a “front end carrier” or a bumper system in an automobile.
Type:
Grant
Filed:
June 14, 2002
Date of Patent:
March 6, 2007
Assignee:
Dow Global Technologies Inc.
Inventors:
Peter J. Cate, Pádraig Naughton, Hein J. Koelman
Abstract: An automotive part containing at least one component formed from a composition comprising the following: (i) a crystalline, isotactic propylene homopolymer, (ii) an ethylene/?-olefin elastomeric impact modifier, and (iii) a reinforcing grade of filler, for example, talc. The crystalline isotactic propylene homopolymer has a flex modulus of greater than about 1930 MPa and a heat deflection temperature (HDT) of greater than about 100° C.; the ethylene/?-olefin interpolymer has a Tg of less than about ?30° C., and a tan delta measured at 0.1 radians/s at 190° C. of less than about 2; and the filler has a HDT reinforcing efficiency of at least about 2. The automotive part has an HDT of greater than about 100° C. and a flex modulus of greater than about 1930 MPa.
Type:
Application
Filed:
June 23, 2006
Publication date:
February 15, 2007
Applicants:
Dow Global Technologies Inc., Delphi Automotive Systems L.L.C.
Abstract: Compositions comprising (i) a crystalline, isotactic propylene homopolymer, (ii) an ethylene/?-olefin elastomeric impact modifier, and (iii) a reinforcing grade of filler, for example, talc. The crystalline isotactic propylene homopolymer has a flex modulus of greater than about 1930 MPa and a heat deflection temperature (HDT) of greater than about 100° C.; the ethylene/?-olefin interpolymer has a Tg of less than about ?30° C., and a tan delta measured at 0.1 radians/s at 190° C. of less than about 2; and the filler has a HDT reinforcing efficiency of at least about 2. The composition has an HDT of greater than about 100° C. and a flex modulus of greater than about 1930 MPa.
Abstract: The present invention relates to substantially free-flowing polymer particles. The polymer particles are those which have a one millimeter penetration temperature of less than about 75° C. as determined by thermal mechanical analysis or an unconfined yield strength of greater than about 15 pounds per square foot (73 kilograms per square meter). The composition also comprises an effective amount of an anti-blocking agent in the presence or absence of a binding agent.
Type:
Application
Filed:
October 17, 2006
Publication date:
February 15, 2007
Applicant:
Dow Global Technologies Inc.
Inventors:
James McMichael, Jeffrey Montanye, Friedhelm Bunge, Shrikant Dhodapkar
Abstract: A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.
Type:
Grant
Filed:
September 14, 2004
Date of Patent:
February 13, 2007
Assignee:
Dow Global Technologies Inc.
Inventors:
Bob R. Maughon, Kenneth A. Burdett, Zenon Lysenko
Abstract: A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 1 to 99 percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 99 to 1 percent of one or more alkoxysilane compounds.
Abstract: The fluid compositions of the present invention include an alkoxy glycol component, where the composition includes no more than about 10 wt % of a borate ester based on the weight of the composition. The physical properties of the compositions of include a high dry equilibrium reflux boiling point (ERBP), a high wet equilibrium reflux boiling point (WERBP), and a low temperature viscosity. These compositions are particularly useful because their physical properties (e.g., WERBP, ERBP, and low temperature viscosity) meet or exceed the provisions for DOT 3 brake fluids under the Federal Motor Vehicle Standard No. 116.
Abstract: A method and apparatus for curtain coating of a moved substrate, particularly for high-speed curtain coating of a continous paper web substrate, wherein a substrate (12) is moved below a hopper means (14), provides one or more liquid coating materials in the form of a free-falling curtain (16) impinging the substrate at a dynamic wetting line. (21) Edge guide elements (22, 24) are used for stabilizing the width and equalizing the flow speed of the coating curtain and allowing disturbance free provision of an auxiliary liquid (13) as well as practically compelte removal of the auxiliary liquid (23) wilst preventing the forming of solidification on the edge guides elements. An auxiliary liquid is injected (32) essentially parallel to the flow direction of the coating film at an edge of the coating film wilst moving along a slide of said hopper arrangement.
Abstract: A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)?cd, wherein: A* is a proton or a cation of from 1 to 80 atoms, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a; Z* is an anion group of from 1 to 50 atoms, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites, said Z* being the conjugate base of an inorganic Bronsted acid or a carbonyl- or non-cyclic, imino-group containing organic Bronsted acid; J* independently each occurrence is a Lewis acid of from 1 to 80 atoms, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality; j is a number from 1 to 12; and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.
Abstract: The invention relates to a polyethylene composition with a bimodal molecular weight distribution, methods for making the same, and articles made therefrom, such as high topload blow moldings and transmission and distribution pipes. The composition comprises a low-molecular-weight (LMW) ethylene homopolymer component and a homogeneous, high-molecular-weight (HMW) ethylene interpolymer component, wherein the LMW component is characterized as having a molecular weight distribution, MWDL, of less than about 8. In some embodiments, the HMW component is characterized by a reverse comonomer distribution.
Type:
Application
Filed:
June 30, 2006
Publication date:
January 25, 2007
Applicant:
Dow Global Technologies Inc.
Inventors:
Jozef Van Dun, Peter van den Berghe, Patrick Schouterden, Ruddy Nicasy, Johan Vanvoorden, Frederik Gemoets, Kalyan Sehanobish, Noorallah Jivraj, Ravi Dixit
Abstract: A process for the preparation of blends including an ethylene copolymer by copolymerizing ethylene and at least one comonomer selected from a compound represented by the formula H2C?CHR wherein R is an alkyl group or an aryl group, and a diene, in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
Type:
Grant
Filed:
June 7, 2002
Date of Patent:
January 23, 2007
Assignee:
Dow Global Technologies, Inc.
Inventors:
Grant B. Jacobsen, Jozef J. Van Dun, Pak-Wing S. Chum, Larry A. Meiske, Fumio Matsushita, Akira Miyamoto
Abstract: A process for the preparation of a Group 4 metal amide complex comprising a monovalent or divalent Lewis base ligand the steps of the process comprising contacting a Group 4 metal amide with a neutral source of a monovalent or divalent, Lewis base ligand group and a solid Lewis acid scavenging agent under amine elimination conditions to form a Group 4 metal amide complex containing at least one less amide group per metal moiety than the initial Group 4 metal amide.
Abstract: Compositions having good impact performance can be made from a thermoplastic (e.g., a polyolefin such as polypropylene or HDPE) and an ethylene multi-block copolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.
Type:
Application
Filed:
March 15, 2006
Publication date:
January 11, 2007
Applicant:
Dow Global Technologies Inc.
Inventors:
Mridula Kapur, Mehmet Demirors, Shaofu Wu, Yunwa Cheung, Pradeep Jain, David Fuchs
Abstract: The present invention provides a method for designing a plastic article having a desired appearance. The process includes having a desired appearance and then obtaining fabrication parameters from the set of virtual article parameters. The present invention can include steps for characterizing an appearance of a target article (target article appearance) and then fitting virtual article parameters to the target article appearance.
Type:
Grant
Filed:
April 21, 2003
Date of Patent:
January 9, 2007
Assignee:
Dow Global Technologies Inc.
Inventors:
Jan C. Torfs, Cornelis F. J. Den Doelder, Eduardus L. L. Broekaart, Evelien M. Dedeyne, Patrick A. Carey
Abstract: A spray-dried composition comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from about 1 ?m to about 12 ?m, and a polymerization process using the same.
Type:
Grant
Filed:
July 13, 2004
Date of Patent:
January 9, 2007
Assignee:
Dow Global Technologies Inc.
Inventors:
Burkhard Eric Wagner, Mark Wilton Smale, Robert James Jorgensen
Abstract: A package assembly comprising a sealed water-impermeable bag enclosing: a spiral wound filtration element comprising a piperazine-based membrane, and an aqueous solution comprises a substantially non-oxidizable buffer having capacity to sequester at least 0.0025 moles per liter of hydrogen ions. The assembly preferably further includes a reducing agent. The assembly provides improved preservation for piperazine-based membranes and elements incorporating such membranes.
Type:
Grant
Filed:
October 5, 2001
Date of Patent:
January 2, 2007
Assignees:
Dow Global Technologies Inc., Filmtec Corporation
Inventors:
Allyn R. Marsh, Russ Schaffenberg, Steven D. Jons, Roy A. Davis