Abstract: A method of producing an aqueous polymer composition and a method of reducing yellowing of an aqueous polymer composition and a coating made therefrom.

Abstract: A free standing film is provided including: a partially hydrolyzed polyvinyl acetate; a poly(ethylene oxide); a polyalkylene glycol; a plasticizer; optionally, a poly(isobutylene-co-maleic anhydride) copolymer; and optionally an additive. Unit dose packages including the free standing film are also provided.

Abstract: A polymer composite comprising quantum dots; said polymer composite comprising: (a) quantum dots; (b) polymerized units of a first compound having at least one readily polymerizable vinyl group, a molecular weight from 300 to 20,000 and at least one continuous acyclic hydrocarbyl chain of at least five carbon atoms; and (c) polymerized units of a second compound having at least one readily polymerizable vinyl group and a molecular weight from 100 to 750; wherein a readily polymerizable vinyl group is part of a (meth)acrylate ester group or is attached directly to an aromatic ring, and the molecular weight of the first compound minus the molecular weight of the second compound is at least 100.

Abstract: Embodiments are directed to catalyst systems comprising: a procatalyst; and a co-catalyst dissolved in a non-halogenated aprotic hydrocarbon solvent, the co-catalyst comprising: a non-coordinating borate dianion having the formula: (III) and two cations, each cation being independently chosen from a cation according to formula (I) or formula (II).

Abstract: A composition comprising an ethylene-based polymer which comprises the following properties: a) MWD(conv) from 3.0 to 7.0; b) an ADF IR between 0.230 and 0.260 for molecular weight ?15,000 g/mol c) 12 from 4.0 to 6.5 g/10 min.

Abstract: An aqueous polymer emulsion comprising: i) as polymerized units, from 20% to 80% by dry weight, based on total dry weight of the polymer, of vinyl acetate; ii) as polymerized units, from 20% to 80% by dry weight, based on total dry weight of the polymer, of an ?, ?-ethylenically unsaturated carboxylic ester monomer; iii) as polymerized units, from 0.1% to 5% by dry weight, based on total dry weight of the polymer, of a stabilizer monomer; iv) from 0.05% to 1% by dry weight, based on total dry weight of the polymer, of a surfactant, wherein said aqueous polymer emulsion has a viscosity of less than 100 cps. An aqueous adhesive composition comprising said aqueous polymer emulsion.

Abstract: Disclosed is a composition and process for making a water blown semi-rigid polyurethane foam wherein the polyisocyanate side and the polyol side are combined under ambient temperature conditions. Said foams are particularly suited for sound and vibration management, especially in motor vehicles.

Abstract: An olefin polymerization catalyst system comprising: a procatalyst component comprising a metal-ligand complex of Formula (I) wherein each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic, wherein n is an integer, and wherein X and n are chosen such that the metal-ligand complex of Formula (I) is overall neutral; wherein each R1 and R5 independently is selected from (C1-C40)hydrocarbyls, substituted (C1-C40)hydrocarbyls; (C1-C40)heterohydrocarbyls and substituted (C1-C40)heterohydrocarbyls; wherein each R2 and R4 independently is selected from (C1-C40)hydrocarbyls and substituted (C1-C40)hydrocarbyls; wherein R3 is selected from the group consisting of a (C3-C40)hydrocarbylene, substituted (C3-C40)hydrocarbylene, [(C+Si)3-(C+Si)40]organosilylene, substituted [(C+Si)3-(C+Si)40]organosilylene, [(C+Ge)3-(C+Ge)40]organogermylene, or substituted [(C+Ge)3-(C+Ge)40]organogermylene; wherein each N independently is nitrogen; and optionally, two or more R1-5 groups each

Abstract: The invention provides a composition comprising a first ethylene-based polymer, formed by a high pressure, free-radical polymerization process, and comprising the following properties: a) a Mw(abs) versus I2 relationship: Mw(abs)<A×[(I2)B], where A=5.00×102 (g/mole)/(dg/min)B, and B=?0.40; and b) a MS versus I2 relationship: MS?C×[(I2)D], where C=13.5 cN/(dg/min)D, and D=?0.55.

Abstract: Polymer polyols are made in a seeded process, in which styrene and acrylonitrile are polymerized in the presence of a base polyol, a seed dispersion and a solvent. The seed dispersion contains an unsaturated macromer. The process produces a polymer polyol in which the dispersed phase particles have a particle size of 1 to 3 ?m and a particle size span of less than 1.25. The polymer polyols are very useful for making flexible polyurethane foam for cushioning applications, in which high airflows and good load bearing are needed.

Abstract: Embodiments of polymer compositions and articles comprising such compositions containing at least one LDPE and at least one multimodal ethylene-based polymer having at least three ethylene-based components.

Abstract: Catalyst compositions and polymerization systems include at least one thiourea complex according to Formula (I): MQaX4-a (I) in which M is Ti, Zr, or Hf; a is 1 or 2; each group Q of the thiourea complex is a bidentate thiourea ligand bound to the metal center and having Formula (Ia), Formula (Ib), or Formula (Ic): (Formulas should be inserted here). In Formulas (Ia), (Ib), and (Ic), each group R1, R2, and R3 is independently chosen from alkyl groups or aryl groups; each group Z1 or Z2 is independently chosen from alkylene groups. If a=2, groups R1 of the two groups Q are optionally linked, or groups R3 of the two groups Q are optionally linked. Each X is covalently bonded or coordinated to the metal center and is independently chosen from alkyl groups or halides. The polymerization systems may be configured to copolymerize ethylene and ?-olefins.

Abstract: An additive elastomeric manufactured part having improved surface finish is made by repeatedly extruding through a nozzle to build up layers of a material comprised of a prepolymer comprised of an isocyanate terminated prepolymer and a filler in an amount such that the material has a shear storage modulus G? of 100,000 to 300,000 Pa measured at an oscillation rate of 1 Hz and a relaxation time of 20 seconds to 360 seconds. It has been discovered that the particular material having these rheological properties is able to improve the surface finish of the additive manufactured part without slumping and is believed to be due to surface flow of material into valleys between the extrudates as they are being built up.

Abstract: A stretch-modified elastomeric multilayer film comprising a core layer comprising a first ethylene-?-olefin block copolymer, wherein the first ethylene-?-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (I2) from 0.5 g/10 min to 5 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, and at least one outer layer independently comprising a second ethylene-?-olefin block copolymer and from 2.5 to 30 wt. % of an antiblock agent, wherein the second ethylene-?-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (I2) from 0.5 g/10 min to 25 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, wherein the density of the first ethylene-?-olefin block copolymer is equal to or greater than the density of the second ethylene-?-olefin block copolymer.

Abstract: The present disclosure provides a composition. The composition includes a silanol functionalized polyolefin; an anhydride-free brominated flame retardant; antimony trioxide; and the composition has an antimony (Sb) to bromine (Br) molar ratio (Sb:Br molar ratio) from 0.37 to 1.05. The present disclosure also provides a coated conductor. The coated conductor includes a conductor and a coating on the conductor, the coating including a composition. The composition includes a silanol functionalized polyolefin; an anhydride-free brominated flame retardant; antimony trioxide; and the composition has an antimony (Sb) to bromine (Br) molar ratio (Sb:Br molar ratio) from 0.37 to 1.05.

Abstract: Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand complex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that the complex of Formula (I) is neutral; each R1 and R10 is a (C6-C40)aryl, substituted (C6-C40)aryl, (C3-C40)heteroaryl, or substituted (C3-C40)heteroaryl; each R2, R3, R4, R7, R8, and R9 is a hydrogen; (C1-C40)hydrocarbyl; substituted (C1-C40)hydrocarbyl; (C1-C40)heterohydrocarbyl; substituted (C1-C40)heterohydrocarbyl; halogen; or nitro (NO2) group; and each R5 and R6 is a (C1-C)alkyl; substituted (C1-C40)alkyl; or [(Si)1—(C+Si)40] substituted organosilyl. Additionally, olefin-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefin polymerization catalyst systems are also provided.

Abstract: The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

Abstract: The present disclosure provides a process for producing an aliphatic sulfonyl azide anhydride and the resultant aliphatic sulfonyl azide anhydride composition. The process includes: (i) thio-acetoxylating an alkenyl carboxylic acid anhydride to form a thioacetate anhydride intermediate, (ii) oxy chlorinating the thioacetate anhydride intermediate to form a sulfonyl chlorideanhydride intermediate; and (iii) azidizing the sulfonyl chloride anhydride intermediate to form an aliphatic sulfonyl azide anhydride.

Abstract: The present invention relates to a method comprising an aqueous dispersion of polymer particles having a backbone comprising structural units of an acrylate monomer and a carboxylic acid monomer, wherein a portion of the structural units of the carboxylic acid monomer are functionalized with glycidyl methacrylate, wherein the glycidyl methacrylate functionalized polymer particles have a number average molecular weight in the range of 5,000 to 50,000 Daltons. The composition of the present invention provides a UV curable coating that achieves an excellent balance of hardness and flexibility, with less reliance on the use of multifunctional acrylates.

Abstract: Systems and methods for measuring corrosion rate of an equipment material are provided. A system may comprise a corrosion probe body for insertion within an interior of the equipment through which corrodant fluid flows. At least one sensor on the corrosion probe body includes an ultrasonic source configured to provide an ultrasonic signal into the probe body material, and a receiver configured to receive reflections of the ultrasonic signal from the probe body material and generate electrical response signals indicative of the travel time of the ultrasonic signal. A heat exchanger may be placed in fluid communication with the probe body to deliver heated or cooled fluids to the probe body. A processor is configured to process the electrical response signals and produce corresponding corrosion data.