Patents Assigned to Dow Silicones Corporation
  • Patent number: 11480873
    Abstract: A method for producing an optical waveguide by: (a) depositing a first composition: (i) a polysiloxane comprising epoxy and alkenyl groups with refractive index no greater than 1.50, (ii) a compound comprising at least one epoxy group and refractive index no greater than 1.49, and (iii) a polysiloxane having refractive index at least 1.50; (iv) a photo acid generator; (v) a hydrosilylation catalyst, (vi) an inhibitor for hydrosilylation; (b) curing by exposure to ultraviolet light; (c) removing the uncured portion to produce a patterned core layer; (d) after a time from 20 to 300 hours depositing a second composition comprising: (i) a polysiloxane comprising epoxy groups with refractive index no greater than 1.49, and (ii) a compound comprising at least two epoxy groups with a refractive index no greater than 1.49 and an alcohol having refractive index no more than 1.45 (iii) at least one photo acid generator.
    Type: Grant
    Filed: July 9, 2018
    Date of Patent: October 25, 2022
    Assignees: Dow Global Technologies LLC, Dow Silicones Corporation
    Inventors: Brandon W. Swatowski, Kai Su, Maynard G. Hyer, William K. Weidner
  • Patent number: 11472983
    Abstract: A composition which provides a coating film having excellent foul releasing property is disclosed. The composition comprises, based on the solid contents of the composition: (A) 20 to 80 weight % of a resin which has a polydialkylsiloxane unit and an epoxy resin unit within its structure; (B) 0.1 to 5 weight % of an amino silane; (C) 0.5 to 5 weight % of a hydrophilic additive; and (D) 0.1 to 5 weight % of a catalyst. A coating, e.g. a coating film, formed from the composition generally has an amphiphilic surface. Thus, the composition is suitable for coatings which prevent both hydrophobic and hydrophilic fouling.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: October 18, 2022
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, DOW SILICONES CORPORATION
    Inventors: Linfei Wang, Xiaomei Song, Hongyu Chen, Guodong Shen, Yunlong Guo
  • Patent number: 11466154
    Abstract: A room temperature curable organopolysiloxane composition comprises: (A) an organopolysiloxane having alkoxysilyl-containing groups at both molecular terminals; (B) an organopolysiloxane resin; (C) an alkoxysilane; and (D) a condensation-reaction catalyst. The room temperature curable organopolysiloxane composition exhibits good to excellent storage stability. In addition, the room temperature curable organopolysiloxane composition can form a cured product exhibiting good to excellent mechanical properties.
    Type: Grant
    Filed: March 21, 2019
    Date of Patent: October 11, 2022
    Assignee: DOW SILICONES CORPORATION
    Inventors: Jody J. Henning, John B. Horstman, Vennesa O. Jansma, Steven Swier
  • Patent number: 11453805
    Abstract: A curable polysiloxane release coating composition comprises (A) an organopolysiloxane containing at least two (2) ethylenically unsaturated groups, (B) an organopolysiloxane containing at least 2 Si—H groups per molecule, and (C) a hydrosilylation catalyst. If the organopolysiloxane (A) contains only 2 ethylenically unsaturated groups, the organopolysiloxane (B) contains on average more than 2 Si—H groups per molecule. The composition further comprises (D1) a hydrosilylation inhibitor comprising a maleimide of the general formula (I). In formula (I), A3? represents a hydrogen atom or a hydrocarbyl or substituted hydrocarbyl group having 1 to 18 carbon atoms, and A1? and A2? each represent a hydrogen atom or a hydrocarbyl or substituted hydrocarbyl group having 1 to 18 carbon atoms.
    Type: Grant
    Filed: March 16, 2018
    Date of Patent: September 27, 2022
    Assignee: DOW SILICONES CORPORATION
    Inventors: Aswini K. Dash, Zhenbin Niu, David A. Rich
  • Patent number: 11453149
    Abstract: An injection moldable composition, comprising: A) a silicone resin (I) [R13SiO1/2]a[R2R3SiO2/2]b[SiO4/2]c, wherein R1, R2, and R3 are hydrocarbyl, hydrocarbyloxy, or hydroxyl, at least one of R2 or R3 is alkenyl, subscripts a, b, and c are each >0 and a+b+c=1, B) 0 to 90% (w/w), based on the weight of A) and B), of a silicone resin (II) [R43SiO1/2]d[SiO4/2]e wherein R4 is hydrocarbyl, hydrocarbyloxy, or hydroxyl, at least one of R4 is alkenyl, subscripts d and e are each >0, and d+e=1, C) a siloxane polymer having formula (III), [R53SiO1/2]fR6R7SiO2/2]g. wherein R5-7 are hydrocarbyl or hydroxyl, at least one of R5-7 is alkenyl, subscripts f and g are each >0, and f+g=1, D) a silicone crosslinker having at least two silicon-bonded hydrogen atoms per molecule, and E) a hydrosilylation catalyst, wherein the ratio of silicon-bonded hydrogen atoms to carbon-carbon double bonds is from 1.2 to 2.2.
    Type: Grant
    Filed: August 6, 2018
    Date of Patent: September 27, 2022
    Assignee: Dow Silicones Corporation
    Inventors: Michelle R. Cummings, Stanton Dent, Joel P. McDonald, Jacob Steinbrecher, Michael Strong, Bradley W. Tuft, Clinton Whiteley
  • Patent number: 11446859
    Abstract: A method of forming a porous three-dimensional (3D) silicone article is disclosed. The method comprises I) printing a first composition with a 3D printer to form a first layer from the first composition. The method further comprises II) printing a second composition on the first layer with the 3D printer to form a second layer from the second composition on the first layer. At least one of the first and second compositions comprises a silicone composition. In the method, step II) may optionally be repeated with independently selected composition(s) for any additional layer(s). At least one of the first and second layers does not consist of linear filaments. Finally, the method comprises III) exposing the layers to a solidification condition. The porous three-dimensional (3D) silicone article defines a plurality of voids.
    Type: Grant
    Filed: March 30, 2018
    Date of Patent: September 20, 2022
    Assignee: DOW SILICONES CORPORATION
    Inventors: Herschel Henry Reese, Bizhong Zhu
  • Patent number: 11434371
    Abstract: A composition containing the following components: (a) a polysiloxane having at least one alkenyl functional group and at least one alkoxy functional group; (b) a mercapto-functional polysiloxane with at least one mercapto functionality; (c) a silane crosslinker with at least two alkoxy groups per molecule; (d) a photoinitiator; (e) a combination of zirconium tetraalkoxylate and alkylacetoacetate at a mole ratio in a range of 1:1 to 1:4.
    Type: Grant
    Filed: November 5, 2020
    Date of Patent: September 6, 2022
    Assignee: Dow Silicones Corporation
    Inventor: Jong-Ok Lim
  • Patent number: 11433595
    Abstract: According to various embodiments, a device for formfree printing a three-dimensional object in layers using at least one printing material includes: at least one printing head to output printing material in at least one printing material string; a printing platen to receive the at least one printing material string output by the at least one printing head; a rod-shaped heating device movably arranged over the printing platen; a heat controller configured to control the rod-shaped heating device to emit a heat irradiation directed to the printing platen to heat the at least one printing material string; at least one motor coupled to the rod-shaped heating device to move it over the printing platen; a motor controller configured to control the at least one motor to move the rod-shaped heating device over the printing platen to harden the at least one printing material string printed on the printing platen.
    Type: Grant
    Filed: November 10, 2017
    Date of Patent: September 6, 2022
    Assignees: Dow Silicones Corporation, innovatiQ GmbH + KG
    Inventors: Hans Peter Wolf, Michael Backer, Stephan Baumann, Florian Bautz
  • Publication number: 20220275189
    Abstract: A polyvinyl chloride (PVC) composition and a method for preparing a polymer composite article. The composition comprises (A) a mineral filler in an amount of from 7.5 to 75 wt. %. The composition also comprises (B) a polyvinyl chloride polymer in an amount of from 20 to 92 wt. %. Further, the composition comprises (C) a polydiorganosiloxane in an amount of from greater than 0 to 5 wt. %; the (C) polydiorganosiloxane being a compound of unit formula: (R2R?SiO1/2)a(R3SiO1/2)b(R2SiO2/2)c(RR?SiO2/2)d, where each R is an independently selected monovalent hydrocarbon group of 1 to 18 carbon atoms that is free of aliphatic unsaturation, each R? is an independently selected alkenyl group of 2 to 18 carbon atoms, subscript a is 0 to 2, subscript b is 0 to 2, a quantity (a+b)=2, subscript c?0, subscript d?0, a quantity (a+d)?1, and a quantity (a+b+c+d) is sufficient to give the polydiorganosiloxane a viscosity of 2,000 mPa·s to 60,000 mPa·s at 25° C. measured at 0.
    Type: Application
    Filed: August 6, 2020
    Publication date: September 1, 2022
    Applicants: Rohm and Haas Company, Dow Silicones Corporation
    Inventors: Hailan Guo, Manoj Nerkar, Sharon M. Vuong, Igor Chorvath
  • Patent number: 11401422
    Abstract: A liquid silicone rubber (LSR) composition, and articles and coatings made therewith are disclosed. Also disclosed is a process to provide for the composition, and a process to coat on textile.
    Type: Grant
    Filed: July 12, 2018
    Date of Patent: August 2, 2022
    Assignees: DOW SILICONES CORPORATION, DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Humen Phukan, Parag Sawant, Tushar Shinde, Padmadas Nair, Shamit Pillay
  • Patent number: 11390748
    Abstract: A dually curable resin composition is provided. The composition comprises: (A) a first polyorganosiloxane comprising at least one alkenyl group and at least one alkoxy group in one molecule; (B) a second polyorganosiloxane comprising at least two photoreactive functional groups in one molecule on its side chain of siloxane backbone; (C) at least one silane compound represented by a particular chemical formula herein or its partially hydrolyzed compound; (D) at least one photoinitiator; and (E) at least one condensation reaction catalyst. A cured body prepared by curing the dually curable resin composition, and an electronic device comprising the cured body, are also provided.
    Type: Grant
    Filed: July 31, 2018
    Date of Patent: July 19, 2022
    Assignee: DOW SILICONES CORPORATION
    Inventor: Jong-Ok Lim
  • Patent number: 11390746
    Abstract: The present disclosure relates to a light curable, light-heat or light-moisture dually curable, or light-heat-moisture multiple curable polyorganosiloxane composition, which has ease of synthesis, low volatile content, rapid curability, excellent toughness and/or superior optical/physical stability in a variety of fields such as coating materials, encapsulants, sealants and adhesives, a cured body obtained by curing said compositions, and an electronic device comprising the same.
    Type: Grant
    Filed: October 26, 2018
    Date of Patent: July 19, 2022
    Assignees: Dow Silicones Corporation, Dow Toray Co., Ltd.
    Inventors: Takuya Ogawa, Yungjin Park, Juyoung Yook
  • Patent number: 11390747
    Abstract: A composition for forming a silicone elastomer is disclosed. The composition comprises: A) a linear organopolysiloxane having at least two silicon-bonded ethylenically unsaturated groups per molecule; B) a linear organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule; C) at least one cross-linker; and D) a hydrosilylation catalyst. The cross-linker C) is selected from the group consisting of: C1) an organopolysiloxane having at least three silicon-bonded ethylenically unsaturated groups per molecule; and C2) an organopolysiloxane having at least three silicon-bonded hydrogen atoms per molecule. At least one of the silicon-bonded ethylenically unsaturated groups of component C1) has a lower reactivity relative to the silicon-bonded ethylenically unsaturated groups of component A). Moreover, at least one of the silicon-bonded hydrogen atoms of component C2) has a lower reactivity relative to the silicon-bonded hydrogen atoms of component B).
    Type: Grant
    Filed: August 28, 2019
    Date of Patent: July 19, 2022
    Assignee: Dow Silicones Corporation
    Inventors: Jon V. Degroot, Jr., Eun Sil Jang, Eric Joffre, Bizhong Zhu
  • Patent number: 11390775
    Abstract: A composition for forming a release coating is disclosed. The composition comprises (A) the reaction product of (1) a branched organopolysiloxane including M, D and Q siloxy units and an average of at least two silicon-bonded ethylenically unsaturated groups per molecule; and (2) an organosilicon compound having an average of at least two silicon-bonded hydrogen atoms per molecule; in the presence of a hydrosilylation catalyst. The composition further comprises (B) an organopolysiloxane having an average of at least two silicon-bonded ethylenically unsaturated groups per molecule.
    Type: Grant
    Filed: November 13, 2020
    Date of Patent: July 19, 2022
    Assignee: Dow Silicones Corporation
    Inventors: Zhenbin Niu, Pierre Chevalier, Sze-Sze Ng, Deana Dujardin, Alex Knott, Lori Dehlin, David Rich
  • Patent number: 11383182
    Abstract: A foam control agent comprising a linear polyorganosiloxane-polyoxyalkylene block copolymer comprising a single block of polyorganosiloxane having a DP of from 10 to 200 and a single block polyoxyalkylene block having a DP of from 2 to 60.
    Type: Grant
    Filed: April 6, 2020
    Date of Patent: July 12, 2022
    Assignees: Dow Silicones Corporation, Dow Global Technologies LLC
    Inventors: Jacqueline L'Hostis, Xiao Meng, Oguz Türünç, Hatice Turgut
  • Patent number: 11377557
    Abstract: The present invention relates to a hydrosilylation-curable silicone composition comprising: a maleate compound, and a hydrosilylation inhibitor other than the maleate compound, wherein the content of the maleate compound is in an amount of 50 to 6,000 ppm and the content of the hydrosilylation inhibitor is in an amount of 200 to 20,000 ppm, with respect to the present composition in terms of mass units, respectively. The hydrosilylation-curable silicone composition exhibits good storage stability, and can be cured to form a cured product that suffers no surface wrinkling.
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: July 5, 2022
    Assignee: DOW SILICONES CORPORATION
    Inventors: Sun Hee Kim, Min Hee Kwon
  • Patent number: 11377561
    Abstract: An alkenyl-functional polydiorganosiloxane is useful in a composition and a method for preparing a wood plastic composite article. The wood plastic composite article is useful as a building material. The polydiorganosiloxane may be added in liquid form to a composition, or may form part of a solid carrier component, used to make the wood plastic composite article.
    Type: Grant
    Filed: June 10, 2020
    Date of Patent: July 5, 2022
    Assignee: Dow Silicones Corporation
    Inventors: Igor Chorvath, Marc-Andre Courtemanche, James Keenihan, Keith Bruce, Sean Gaal, Jodi Mecca
  • Patent number: 11370888
    Abstract: A silsesquioxane resin, photoresist composition comprising the silsesquioxane resin and a photoacid generator, etching mask composition comprising the silsesquioxane resin, products prepared therefrom, methods of making and using same, and manufactured articles and semiconductor devices containing same. The silsesquioxane resin comprises silicon-bonded hydrogen atom T-units and T-units having a silicon-bonded group of formula —CH2CH2CH2CO2C(R1a)3 or —CH(CH3)CH2CO2C(R1a)3, wherein each R1a is independently an unsubstituted (C1-C2)alkyl.
    Type: Grant
    Filed: June 8, 2017
    Date of Patent: June 28, 2022
    Assignee: Dow Silicones Corporation
    Inventors: Peng-Fei Fu, Wonbum Jang
  • Patent number: 11370867
    Abstract: The present invention relates to a composition comprising an aqueous dispersion of polymeric composite microspheres comprising an aqueous dispersion of polymeric composite microspheres that comprise a polysiloxane and a polymer, as defined herein, and a suspension polymerization process for making the composition. The composition is useful for making defect free coatings with a relatively low coefficient of friction.
    Type: Grant
    Filed: February 5, 2020
    Date of Patent: June 28, 2022
    Assignees: Rohm and Haas Company, Dow Silicones Corporation
    Inventors: Ibrahim Eryazici, Joseph Grant, Joshua M. Katzenstein, Yihan Liu, Edwin A. Nungesser, Brett L. Zimmerman
  • Patent number: 11359167
    Abstract: The present disclosure relates to fabric-care compositions comprising an uncured silicone based polymer. In particular, the present disclosure relates to fabric-care compositions comprising at least one uncured silicone based polymer; and at least one fabric-care ingredient, optionally in an acceptable medium. Also disclosed are processes to prepare the fabric-care compositions and uses of the fabric-care compositions.
    Type: Grant
    Filed: December 17, 2018
    Date of Patent: June 14, 2022
    Assignee: DOW SILICONES CORPORATION
    Inventors: Tatiana Dimitrova, Jonathan Thill, Severine Cauvin