Patents Assigned to Dowa IP Creation Co., Ltd.
  • Patent number: 9429862
    Abstract: A method for manufacturing carrier core particles for electrophotographic developer that include manganese, magnesium, and iron as a core composition. The method includes a granulation step (A) of granulating a mixture of raw materials containing manganese, magnesium, and iron with a reducing agent added at a ratio of 0.10% to 1.00% by mass to a total mass of the raw materials containing manganese, magnesium, and iron, and a firing step of firing the granular material granulated in the granulation step. The firing step includes a first heating step (C) of applying heat at a constant temperature ranging from 500° C. to 800° C. in an atmosphere with an oxygen concentration of 1000 ppm to 15000 ppm for a predetermined period of time and a second heating step (D) of applying heat at a temperature higher than 800° C. for a predetermined period of time after the first heating step.
    Type: Grant
    Filed: October 16, 2015
    Date of Patent: August 30, 2016
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventor: Takeshi Kawauchi
  • Patent number: 9329514
    Abstract: A carrier core particle for an electrophotographic developer includes a composition expressed by a general formula: MnxFe3?xO4+y (0<x?1, 0<y), a full width at half maximum z of the most intense peak (311) plane in a powder X-ray diffraction pattern satisfying 0.16 (degree)?z, and a magnetization of 50 emu/g or higher in an external magnetic field of 1000 Oe.
    Type: Grant
    Filed: September 25, 2014
    Date of Patent: May 3, 2016
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventors: Takeshi Kawauchi, Sho Ogawa
  • Patent number: 9274446
    Abstract: A method for manufacturing carrier core particles for electrophotographic developer that include manganese, magnesium, and iron as a core composition. The method includes a granulation step (A) of granulating a mixture of raw materials containing manganese, magnesium, and iron with a reducing agent added at a ratio of 0.10% to 1.00% by mass to a total mass of the raw materials containing manganese, magnesium, and iron, and a firing step of firing the granular material granulated in the granulation step. The firing step includes a first heating step (C) of applying heat at a constant temperature ranging from 500° C. to 800° C. in an atmosphere with an oxygen concentration of 1000 ppm to 15000 ppm for a predetermined period of time and a second heating step (D) of applying heat at a temperature higher than 800° C. for a predetermined period of time after the first heating step.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: March 1, 2016
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventor: Takeshi Kawauchi
  • Patent number: 9268246
    Abstract: Provided is a method for manufacturing carrier core particles for electrophotographic developer capable of stably maintaining high chargeability over a long time. The method for manufacturing carrier core particles includes a granulation step of granulating a mixture of raw materials containing manganese, iron, strontium, and calcium and a firing step of firing the mixture granulated in the granulation step. The firing step includes a heating process of heating the granular mixture with an increase in temperature to a predetermined degree and a cooling process of cooling the granular mixture, after the heating process, in an atmosphere with an oxygen concentration ranging from 5000 ppm to 20000 ppm. The molar ratio of the sum of strontium and calcium to the sum of the manganese, iron, strontium, and calcium is 0.0026 to 0.013.
    Type: Grant
    Filed: February 20, 2014
    Date of Patent: February 23, 2016
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventors: Takeshi Kawauchi, Sho Ogawa, Haruka Seki
  • Patent number: 9195157
    Abstract: A method for manufacturing carrier core particles for electrophotographic developer including a slurrying step (A) of making an iron-containing raw material and a strontium-containing raw material into slurry, a granulation step (B) of granulating the slurry mixture obtained in the slurrying step, and a firing step (C) of firing a powdery material, which is obtained by granulating the slurry mixture in the granulation step, at a predetermined temperature to form a magnetic phase. The slurrying step makes the iron-containing raw material into the slurry containing the iron-containing raw material having a volume diameter D50 of 1.0 to 4.0 ?m and a volume diameter D90 of 2.5 to 7.0 ?m, and makes the strontium-containing raw material into the slurry so that the carrier core particles for electrophotographic developer contain 0<y?5000 ppm, where y denotes the content of the strontium in the carrier core particles.
    Type: Grant
    Filed: March 2, 2012
    Date of Patent: November 24, 2015
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventors: Takeshi Kawauchi, Tomohide Iida
  • Patent number: 9164411
    Abstract: There is provided a carrier core material for electrophotographic developer containing a soft ferrite, expressed by (MgXMn1?X)Fe2O4 (wherein X is in a range of 0.1?X<1.), wherein an analysis value of P on the surface of the carrier core material is 0.1 mass % or more, an analysis value of Mg is 2 mass % or more, a content of Mg on the surface of the carrier core material is 2 mass % or more by EDS, and when the content of Mg in the carrier core material is expressed by M1, and the analysis value of Mg on the surface of the carrier core material by EDS is expressed by M2, a value of M2/M1 exceeds 1.0.
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: October 20, 2015
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventors: Masahiro Nakamura, Takeshi Kawauchi, Toshiya Kitamura
  • Publication number: 20150220014
    Abstract: This invention is directed to a method for manufacturing carrier core particles for electrophotographic developer containing iron, manganese, and calcium as a core composition. The method includes (A) a mixing step of mixing an iron-containing raw material, a manganese-containing raw material, and a calcium-containing raw material to prepare a mixture thereof, (C) a granulation step of granulating the mixture after the mixing step, and (D) a firing step of firing a powdery material, which is obtained by granulating the mixture in the granulation step, at a predetermined temperature to form a magnetic phase. The calcium-containing raw material is provided in a granular form, and primary particles of the calcium-containing raw material have a volume mean diameter of 1 ?m or less.
    Type: Application
    Filed: August 30, 2012
    Publication date: August 6, 2015
    Applicants: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventors: Takeshi Kawauchi, Tomohide Iida
  • Patent number: 9034552
    Abstract: The carrier core particles for electrophotographic developer have a volume size distribution with a median particle size ranging from 30 ?m to 40 ?m, the ratio of the carrier core particles having a diameter of 22 ?m or lower in the volume size distribution is from 1.0% to 2.0%, the ratio of the carrier core particles having a diameter of 22 ?m or lower in a number size distribution is 10% or lower, and the magnetization of the carrier core particles in an external magnetic field of 1000 Oe is from 50 emu/g to 75 emu/g.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: May 19, 2015
    Assignees: DOWA ELECTRONICS MATERIALS CO., LTD., DOWA IP CREATION CO., LTD.
    Inventors: Tomohide Iida, Tomoya Yamada, Takashi Fujiwara
  • Publication number: 20150010462
    Abstract: A carrier core particle for an electrophotographic developer includes a composition expressed by a general formula: MnxFe3?xO4+y (0<x?1, 0<y), a full width at half maximum z of the most intense peak (311) plane in a powder X-ray diffraction pattern satisfying 0.16 (degree) ?z, and a magnetization of 50 emu/g or higher in an external magnetic field of 1000 Oe.
    Type: Application
    Filed: September 25, 2014
    Publication date: January 8, 2015
    Applicant: DOWA IP CREATION CO., LTD.
    Inventors: Takeshi KAWAUCHI, Sho OGAWA
  • Patent number: 8883388
    Abstract: A carrier core particle for an electrophotographic developer including a core composition expressed by a general formula: (MnxMgyCaz) FeWO4+V (x+y+z+w=3, ?0.003<v) as a main ingredient, wherein 0.05?y?0.35 and 0.005?z?0.024.
    Type: Grant
    Filed: July 26, 2011
    Date of Patent: November 11, 2014
    Assignees: Dowa Electronics Materials Co., Ltd., Dowa IP Creation Co., Ltd.
    Inventors: Takeshi Kawauchi, Yukihiro Matsuda
  • Patent number: 8865386
    Abstract: A carrier core particle for an electrophotographic developer includes a core composition expressed by a general formula: MnxFe3?xO4+y (0<x?1, 0<y) as a main ingredient, 0.1 wt % or more of Si, and 0.03 wt % or more of at least one metal element selected from the group consisting of Ca, Sr and Mg.
    Type: Grant
    Filed: March 29, 2011
    Date of Patent: October 21, 2014
    Assignees: Dowa Electronics Materials Co., Ltd., Dowa IP Creation Co., Ltd.
    Inventors: Takeshi Kawauchi, Sho Ogawa
  • Publication number: 20140242511
    Abstract: Provided is a method for manufacturing carrier core particles for electrophotographic developer capable of stably maintaining high chargeability over a long time. The method for manufacturing carrier core particles includes a granulation step of granulating a mixture of raw materials containing manganese, iron, strontium, and calcium and a firing step of firing the mixture granulated in the granulation step. The firing step includes a heating process of heating the granular mixture with an increase in temperature to a predetermined degree and a cooling process of cooling the granular mixture, after the heating process, in an atmosphere with an oxygen concentration ranging from 5000 ppm to 20000 ppm. The molar ratio of the sum of strontium and calcium to the sum of the manganese, iron, strontium, and calcium is 0.0026 to 0.013.
    Type: Application
    Filed: February 20, 2014
    Publication date: August 28, 2014
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventors: Takeshi KAWAUCHI, SHO OGAWA, HARUKA SEKI
  • Publication number: 20140154623
    Abstract: The carrier core particles for electrophotographic developer include a core composition expressed by a general formula Fe3O4 as a main ingredient and 30 ppm to 400 ppm Na. Such carrier core particles can reduce environmental dependency thereof, while optimizing the resistivity.
    Type: Application
    Filed: February 7, 2014
    Publication date: June 5, 2014
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventor: Takeshi KAWAUCHI
  • Patent number: 8652736
    Abstract: The present invention provides a carrier core material for use in the production of an electrophotographic developer which, even when applied, for example, to MFPs (multifunction printers), can realize stable, high-quality and high-speed development, and has a prolonged replacing life of magnetic carriers, and a method of manufacturing the same, a magnetic carrier including the carrier core material, and an electrophotographic developer manufactured from the magnetic carrier. An electrophotographic development carrier is prepared by adding resin particles, a binder, a dispersant, a wetting agent, and water to a raw material powder, wet pulverizing the mixture, drying the pulverized product to give granulated powder, calcinatng the granulated powder, and then sintering the granulated powder to prepare a carrier core material having an internally hollow structure, and coating the carrier core material with a resin.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: February 18, 2014
    Assignees: Dowa IP Creation Co., Ltd., Dowa Electronics Materials Co., Ltd.
    Inventors: Ryusuke Nakao, Takeshi Kawauchi
  • Publication number: 20140017606
    Abstract: A material expressed as a composition formula MXFe3-XO4 (where M is at least one of Mg and Mn, and 0?X?1) is a main component, and as a total amount, 0.1 to 2.5 weight percent of at least one of a Sr element and a Ca element is contained. Here, when ferrite particles are used as a carrier, in terms of obtaining a higher image density, the fluidity of the ferrite particles magnetized under a magnetic field of 1000/(4?) kA/m (1000 oersteds) is preferably 40 seconds or more. The residual magnetization ?r is preferably 3 Am2/kg or more.
    Type: Application
    Filed: March 19, 2012
    Publication date: January 16, 2014
    Applicants: DOWA IP CREATION CO., LTD, DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventors: Tomoya Yamada, Tomohide Iida
  • Publication number: 20140017609
    Abstract: A method for manufacturing carrier core particles for electrophotographic developer including a slurrying step (A) of making an iron-containing raw material and a strontium-containing raw material into slurry, a granulation step (B) of granulating the slurry mixture obtained in the slurrying step, and a firing step (C) of firing a powdery material, which is obtained by granulating the slurry mixture in the granulation step, at a predetermined temperature to form a magnetic phase. The slurrying step makes the iron-containing raw material into the slurry containing the iron-containing raw material having a volume diameter D50 of 1.0 to 4.0 ?m and a volume diameter D90 of 2.5 to 7.0 ?m, and makes the strontium-containing raw material into the slurry so that the carrier core particles for electrophotographic developer contain 0?y?5000 ppm, where y denotes the content of the strontium in the carrier core particles.
    Type: Application
    Filed: March 2, 2012
    Publication date: January 16, 2014
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventors: Takeshi Kawauchi, Tomohide IIda
  • Patent number: 8617781
    Abstract: The carrier core particles 11 for electrophotographic developer contain lithium as a core composition. When the carrier core particles 11 are immersed in pure water at a weight ratio of 1 part core particles 11 to 10 parts pure water and shaken, the amount of lithium that leaches out to the pure water is 0.10 ppm or lower.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: December 31, 2013
    Assignees: Dowa Electronics Materials Co., Ltd., Dowa IP Creation Co., Ltd.
    Inventor: Takeshi Kawauchi
  • Publication number: 20130344431
    Abstract: The carrier core particles for electrophotographic developer have a volume size distribution with a median particle size ranging from 30 ?m to 40 ?m, the ratio of the carrier core particles having a diameter of 22 ?m or lower in the volume size distribution is from 1.0% to 2.0%, the ratio of the carrier core particles having a diameter of 22 ?m or lower in a number size distribution is 10% or lower, and the magnetization of the carrier core particles in an external magnetic field of 1000 Oe is from 50 emu/g to 75 emu/g.
    Type: Application
    Filed: March 1, 2012
    Publication date: December 26, 2013
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventors: Tomohide Iida, Tomoya Yamada, Takashi Fujiwara
  • Patent number: 8592123
    Abstract: To provide a carrier for electrophotographic developer, capable of realizing a high image quality and full colorization and reducing carrier scattering, and a manufacturing method of the same, and an electrophotographic developer containing the carrier. A carrier core material for electrophotographic developer, with a general formula expressed by MgxMn(1-x)FeyO4 (where 0<x<1, and 1.6?y?2.4), wherein a half-value width B of a peak having a maximum intensity in a powder XRD pattern satisfies B?0.180 (degree), is manufactured and from this carrier core material for electrophotographic developer, the carrier for electrophotographic developer and the electrophotographic developer are manufactured.
    Type: Grant
    Filed: April 9, 2008
    Date of Patent: November 26, 2013
    Assignees: Dowa Electronics Materials Co., Ltd., Dowa IP Creation Co., Ltd.
    Inventors: Tomoya Yamada, Takashi Fujiwara, Ryusuke Nakao, Yukihiro Matuda, Tomokazu Mouri
  • Patent number: 8580381
    Abstract: An oxygen absorber for blending in a resin, comprising a mixed powder containing an iron powder, a metal halide and an alkaline substance, and having a half-peak width on a plane (110) of 0.20°/2? (Co—K?) or less as measured by a powder X-ray diffraction method, a specific surface area of 0.5 m2/g or more, and an average particle size of 1 to 40 ?m. The oxygen absorber effectively suppresses the generation of hydrogen, features excellent safety, exhibits excellent oxygen-absorbing capability and offers an advantage of high productivity due to the suppressed occurrence of coarse particles in the step of producing the oxygen absorber.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: November 12, 2013
    Assignees: Toyo Seikan Kaisha, Ltd, Dowa Electronics Materials Co., Ltd, Dowa IP Creation Co., Ltd
    Inventors: Youichi Ishizaki, Keiji Fukue, Kazuhiro Seno