Patents Assigned to DSM Chemie Linz GmbH
  • Patent number: 6046042
    Abstract: A purified (S)-hydroxy-nitrile-lyase is disclosed. Also disclosed is an amino acid sequence for (S)-hydroxy-nitrile-lyase and DNA sequence encoding the same.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: April 4, 2000
    Assignee: DSM Chemie Linz GmbH
    Inventors: Meinhard Hasslacher, Michael Schall, Helmut Schwab, Elfriede Marianne Hayn, Sepp Kohlwein, Herfried Griengl
  • Patent number: 5898076
    Abstract: Process for preparing N-pyruvyl-L-proline by reaction of L-proline with methyl pyruvate dimethyl ketal in the presence of an alkali metal alkoxide, subsequent acid hydrolysis and extraction of 1-pyruvyl-L-proline.
    Type: Grant
    Filed: August 6, 1998
    Date of Patent: April 27, 1999
    Assignee: DSM Chemie Linz GmbH
    Inventors: Karlheinz Giselbrecht, Curt Zimmermann
  • Patent number: 5895815
    Abstract: Process for the purification of 5H-dibenz?b,f!a-zepine, which comprises evaporating 5H-dibenz?b, f!azepine under reduced pressure from a reaction mixture obtained by catalytic dehydrogenation of 10,11-dihydro-5H-dibenz-?b,f!azepine in the 1st step and depositing it as a solid, suspending the deposited product in an aromatic hydrocarbon in the 2nd step and then isolating pure 5H-dibenz?b,f!azepine.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: April 20, 1999
    Assignee: DSM Chemie Linz GmbH
    Inventors: Gunter Eichberger, Walter Raml
  • Patent number: 5874637
    Abstract: Process for the purification of o-phthalaldehyde in which an alcoholic solution containing the crude, unpurified o-phthalaldehyde is adjusted to a pH between 0 and 3 at a temperature between 0.degree. and 60.degree. C., then an alkaline solution is added, and the corresponding dialkoxyphthalan is extracted from the organic phase and purified by distillation and, when required, converted into the purified o-phthalaldehyde by hydrolysis.
    Type: Grant
    Filed: October 29, 1997
    Date of Patent: February 23, 1999
    Assignee: DSM Chemie Linz GmbH
    Inventors: Karl Heinz Giselbrecht, Klaus Reiter, Eduard Perndorfer, Rudolf Hermanseder
  • Patent number: 5872153
    Abstract: A process for preparing an aqueous o-phthalaldehyde-glutaraldehyde solution which comprises converting an acetal of the o-phthalaldehyde in a 10 to 60% strength aqueous glutaraldehyde solution into o-phthalaldehyde at room temperature up to 100.degree. C. by eliminating the corresponding alcohol, and removing the eliminated alcohol to give the aqueous o-phthalaldehyde-glutaraldehyde solution.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: February 16, 1999
    Assignee: DSM Chemie Linz GmbH
    Inventors: Karl Heinz Giselbrecht, Eduard Perndorfer
  • Patent number: 5756812
    Abstract: Process for the preparation of pure (S,S)-N-(1-ethoxycarbonyl-3-phenylpropyl) alanine,in which impure (S,S)-N-(1-ethoxycarbonyl-3-phenylpropyl)alanine is suspended in water, dissolved by heating to the boiling point and separated from insoluble impurities by filtration and the desired end product is then precipitated by cooling, filtered off and dried.
    Type: Grant
    Filed: February 5, 1997
    Date of Patent: May 26, 1998
    Assignee: DSM Chemie Linz GmbH
    Inventors: Kurt Alfred Hackl, Josef Schaller
  • Patent number: 5734064
    Abstract: A process for the preparation of carboxylic acid succinimidyl esters by reaction of N-hydroxysuccinimide with a carboxylic acid and a halophosphoric acid ester of the formula ##STR1## is desired, in which R.sub.1 and R.sub.2 are identical or different and are a C.sub.2 - to C.sub.6 -alkyl radical or a phenyl radical, or R.sub.1 and R.sub.2 The process is carried out in the presence of a base in a diluent at a temperature of 0.degree. C. up to 100.degree. C. with isolation of the corresponding carboxylic acid succinimidyl ester.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: March 31, 1998
    Assignee: DSM Chemie Linz GmbH
    Inventors: Peter Pochlauer, Wolfram Hendel, Christian Burger, Anita Lamplmayr, Harald Poschko, Antonia Praus, Gerald Summer
  • Patent number: 5723612
    Abstract: Process for the preparation of pure 4,6-dichloropyrimidine by reaction of 4,6-dihydroxypyrimidine with an excess of phosphorus oxychloride at 20.degree. C. up to reflux temperature, in the presence of a trialkylamine as acid scavenger and catalyst.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: March 3, 1998
    Assignee: DSM Chemie Linz GmbH
    Inventors: Wolfgang Huber, Franz Thomas Schwarz, Ferdinand Heu
  • Patent number: 5723661
    Abstract: A process for preparing high-purity calcium pyruvate or its hydrates by reacting an aqueous solution of pyruvic acid with an inorganic calcium compound with the pH being set to 2 to 7, preferably 2.5 to 4, which comprises reacting an up to 10% strength aqueous solution of pyruvic acid with the calcium compound, in the presence or absence of a stabilizer or complexing agent, and mixing the resulting solution with an organic diluent at temperatures of 0.degree. to 30.degree. C. and isolating the resulting precipitate of calcium pyruvate or its hydrate from the solution.
    Type: Grant
    Filed: March 11, 1997
    Date of Patent: March 3, 1998
    Assignee: DSM Chemie Linz GmbH
    Inventors: Curt Zimmermann, Kurt Weissenbock
  • Patent number: 5714356
    Abstract: Process for preparing (S)-cyanohydrins by reacting aldehydes or asymmetrical, aliphatic ketones with hydrocyanic acid in the presence of the (S)-oxynitrilase from Hevea brasiliensis at temperatures of up to at most 10.degree. C.
    Type: Grant
    Filed: June 19, 1995
    Date of Patent: February 3, 1998
    Assignee: DSM Chemie Linz GmbH
    Inventors: Herfried Griengl, Nongyuan Shi, Ulrike Pichler, Norbert Klempier, Peter Pochlauer
  • Patent number: 5710359
    Abstract: Process for the environmentally appropriate degradation of chemical compounds which have one or more heteroatoms X, with X being F, Cl, Br, I, N, O or S, by cleavage of the C--X carbon-heteroatom bonds, characterized in that the chemical compounds or articles which contain the chemical compounds are treated with water vapor in the presence of an aluminum catalyst at 300.degree.-600.degree. C.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: January 20, 1998
    Assignee: DSM Chemie Linz GmbH
    Inventors: Johannes Lercher, Zhan Zhaoqui
  • Patent number: 5686625
    Abstract: Process for the preparation of an N-substituted glycine ester or an N-substituted glycine acid by reaction of a glyoxylic acid ester half-acetal (hemiacetal) or glyoxylic acid half-acetal (hemiacetal) with an amine and hydrogenation of the intermediate product formed by this reaction, and the use of the process in a process for the preparation of indoxyl and indigo derivatives by cyclization of an N-arylglycine ester, prepared by the above process, in a molten alkali metal carbonate or alkaline earth metal carbonate with or without addition of an alkali metal amide, and if appropriate oxidation of the indoxyl derivative formed by this reaction to give the corresponding indigo derivative.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: November 11, 1997
    Assignee: DSM Chemie Linz GmbH
    Inventor: Carlo Kos
  • Patent number: 5686638
    Abstract: Process for the preparation of aliphatic or aromatic mono- or dicarboxylic acids of 4 to 22 carbon atoms by oxidation of the corresponding aldehydes having the same number of carbon atoms in a carboxylic acid from the group consisting of formic acid, acetic acid, and propionic acid or in a carboxylic acid/water mixture at a temperature of 50.degree.-130.degree. C. and at 1 to 25 bar and in the presence of an oxidizing agent.
    Type: Grant
    Filed: September 5, 1995
    Date of Patent: November 11, 1997
    Assignee: DSM Chemie Linz GmbH
    Inventors: Carlo Kos, Manfred Schoftner, Johann Friedhuber
  • Patent number: 5659076
    Abstract: A process for the transesterification of dimethyl succinylsuccinate with one or more aliphatic alcohols which in each case have at least 2 C atoms, in the presence of an acidic catalyst and in the presence or absence of a diluent which is inert under the reaction conditions, with exclusion of oxygen and under pressure, at least one of the two methoxy groups being replaced by the oxy group corresponding to the alcohol used and use of the process in a process for the preparation of terephthalic acids and of quinacridones.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: August 19, 1997
    Assignee: DSM Chemie Linz GmbH
    Inventors: Franz Thomas Schwarz, Johann Altreiter, Franz Mostl
  • Patent number: 5639662
    Abstract: Process for enhancement of enantioselectivity in the enzymatic separation of (R)- and (S)-enantiomers of an asymmetric alkynol, a lipase and in the presence of at least one vinyl ester, in which the acid component has at least 4 C atoms, an organic solvent and with the addition of water. Also disclosed is a process for enhancement of enantioselectivity in the enzymatic separation of (R)- and (S)-enantiomers of an alcohol with the aid of the abovementioned vinyl ester under addition of a second vinyl ester having at least 2 C atoms less in the alkyl chain than the vinyl ester used as esterifying agent.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: June 17, 1997
    Assignee: DSM Chemie Linz GmbH
    Inventors: Herbert Mayrhofer, Irma Wirth, Peter Pochlauer
  • Patent number: 5629397
    Abstract: 2,6-dimethylphenylmaleimide is used as a comonomer for the preparation of styrene copolymers and vinyl chloride copolymers having an increased glass transition temperature and low intrinsic coloration compared with the prior art.
    Type: Grant
    Filed: February 14, 1996
    Date of Patent: May 13, 1997
    Assignee: DSM Chemie Linz GmbH
    Inventors: Gerhard Steinbauer, Jan Bartus, Heinrich Horacek, Otto Vogl, Gerhard Stern
  • Patent number: 5597917
    Abstract: A process for the dissolution of chemical compounds by use of ureas in which at least one of the urea's two nitrogen atoms is part of a non-aromatic ring which can be broken by an oxygen or sulphur atom as a chemical solvent, and a method of producing tri- or tetraalkylated ureas or bis ureas wherein at least one of the urea's nitrogen atoms is part of a non-aromatic ring which can be broken by an oxygen or sulphur atom by means of dialkylating the --NH.sub.2 group of a urea with an alkene or alkene arylene alkene dihalogenide, disulphonate or dihydrogen sulphonate in the presence of a solid base and a phase-transfer catalyst.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: January 28, 1997
    Assignee: DSM Chemie Linz GmbH
    Inventors: Kurt A. Hackl, Markus R ossler, Martin M ullner, Gerhard Stern
  • Patent number: 5578723
    Abstract: A process for preparing cyanuric acid by cooling an isocyanuric acid/ammonia gas mixture having a temperature of 300.degree. to 480.degree. C. to 200.degree.-300.degree. C., whereupon cyanuric acid is separated off and isolated at this temperature in an apparatus suitable for separating solids from gases, and unreacted isocyanuric acid/ammonia gas mixture is recycled or further processed.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: November 26, 1996
    Assignee: DSM Chemie Linz GmbH
    Inventors: Erich Schulz, Georg H aubl, Martin M ullner
  • Patent number: 5563270
    Abstract: Process for the preparation of 2-amino-4,6-dichloropyrimidine by reaction of 2-amino-4,6-dihydroxypyrimidine with an excess of phosphorus oxychloride at 20 to 80.degree. C. and in the presence of triethylamine as the acid-trapping agent.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: October 8, 1996
    Assignee: DSM Chemie Linz GmbH
    Inventors: Franz-Thomas Schwarz, Johann Altreiter