Patents Assigned to DSM Copolymer, Inc.
  • Patent number: 6127481
    Abstract: A branched polyolefin additive for use in fuel and/or lubricating oil in the form of a comb, star, nanogel and structural combinations thereof in which a plurity of polyolefin arms are attached to a backbone having repeating units containing aliphatic groups, aromatic groups, heteroatom-containing groups and combinations thereof, to provide a branched polymeric additive in which the properties of the additive can be conveniently tailored to a single or multi-functional performance criteria of a fuel and/or lubricating oil composition.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: October 3, 2000
    Assignee: DSM Copolymer, Inc.
    Inventors: Koen Jan Gerarda Janssen, Claude Leo Bostoen
  • Patent number: 6084030
    Abstract: A highly branched polymer in the form of a comb, star, nanogel and structural combinations thereof in which a plurality of polyolefin arms formed of polymers of 1-alkenes are attached to a backbone having repeating units containing aliphatic groups, aromatic groups, heteroatom-containing groups and combinations thereof.
    Type: Grant
    Filed: August 4, 1995
    Date of Patent: July 4, 2000
    Assignee: DSM Copolymer, Inc.
    Inventors: Koen Jan Gerarda Janssen, Gerardus Arnoldus Rademakers, Jacob Renkema, Petronella Danielle Verweij
  • Patent number: 5985953
    Abstract: A compatibilized silica for incorporation into natural and synthetic polymers in latex form or dry blending operations is described. Said compatibilized silica is formed by the reaction of precipitated or fumed silica with organosilicon coupling compounds in aqueous suspension. Polymer-silica reinforced masterbatches are prepared by addition of the compatibilized silica slurry to natural and synthetic polymer latices. Also described is a process for preparing the compatibilized silica.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: November 16, 1999
    Assignee: DSM Copolymer, Inc.
    Inventors: John W. Lightsey, David J. Kneiling, John M. Long, Andrew C. Kolbert
  • Patent number: 5837773
    Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution. The sheared blend of polymers can function as a shear stable dispersant viscosity index improver with improved lower temperature properties or the hydrocarbon base for multifunctional for viscosity index improvers, motor fuel additives or polymeric dispersants.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: November 17, 1998
    Assignee: DSM Copolymer, Inc.
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 5763388
    Abstract: A process for the incorporation of silica into a polymer in latex in which a silica is treated with an organo silicon compound coupling agent in aqueous suspension to form a compatibilized silica and then contacting a polymer latex with the compatibilized silica whereby the silica becomes substantially uniformly distributed throughout the latex and can be recovered when the latex is coagulated to yield little residual silica in the liquid residue from the latex. Also described is a process for preparing the compatibilized silica.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: June 9, 1998
    Assignee: DSM Copolymer, Inc.
    Inventors: John W. Lightsey, David J. Kneiling, John M. Long
  • Patent number: 5728911
    Abstract: A copolymer having an RSV less than 0.6 and a process for its preparation in which ethylene, at least one other 1-alkene and, optionally, an aliphatic or alicyclic polyunsaturated monomer are polymerized in the presence of a catalyst system containing (1) a compound of vanadium, (2) at least one alkyl aluminum halide, (3) an .alpha.-halo, ketoaromatic promoter and (4) a chain transfer agent in which the molar ratio of alkyl groups of the alkyl aluminum halide to halogen atoms is at least 1.5.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: March 17, 1998
    Assignee: DSM Copolymer, Inc.
    Inventor: James R. Hall
  • Patent number: 5721200
    Abstract: An additive compositon comprising a graft and aminederivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha-monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha-monoolefin and from about 0 to 15 mole percent of said polyene, said copolymer having a number average molecular weight ranging from about 5,500 to 50,000 and having grafted thereon at least 1.8 molecules of a carboxylic acid acylating function per molecule of said copolymer and reacting said grafted copolymer with an amino alcohol compound selected from the group consisting of a 2-Anilinoalcohol, a (2-hydroxyalkyl) pyrridine, a 4-(2-hydroxyalkyl) morpholine, a 1-(2-hydroxyalkyl) piperazine, a 1-(2-pyrrolidine and a 1-(2-hydroxyalkyl) 2-pyrrolidine.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: February 24, 1998
    Assignee: DSM Copolymer, Inc.
    Inventors: Shailaja Madhu Shirodkar, Cyril Andrew Migdal
  • Patent number: 5652191
    Abstract: A catalyst precursor is provided that is useful in the selective hydrogenation of olefinic unsaturation in polymers or copolymers. The precursor comprises a palladium salt that is complexed with a complexing agent selected from the gronp consisting of organic phosphates, dialkylidene acetones, and tetraalkyl ammonium hydroxides. The catalyst precursor may be nsed in batch, step-wise addition, or continuous systems.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: July 29, 1997
    Assignee: DSM Copolymer, Inc.
    Inventor: Robert T. Patterson
  • Patent number: 5574118
    Abstract: This invention is addressed to olefin polymers having antioxidant properties which are prepared by Ziegler polymerization of one or more monomers containing ethylenic unsaturation along with a polymerizable antioxidant monomer in the form of a substituted norbornene in which at least one substituent contains one or more groups imparting to the molecule antioxidant properties.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: November 12, 1996
    Assignee: DSM Copolymer, Inc.
    Inventor: Errol J. Olivier
  • Patent number: 5563118
    Abstract: An additive composition comprising a graft and derivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha- monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha- monoolefin and from about 0 to 15 mole percent of said polyene having an average molecular weight ranging from about 5,000 to 500,000, which has been reacted with at least one olefinic carboxylic acid acylating agent to form one or more acylating reaction intermediates characterized by having a carboxylic acid acylating function within their structure and reacting said reaction intermediate with an amino-aromatic compound to form said graft derivatized copolymer, and a lubricating oil composition containing same are provided.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 8, 1996
    Assignee: DSM Copolymer, Inc.
    Inventors: Munmaya K. Mishra, Isaac D. Rubin
  • Patent number: 5559178
    Abstract: A composition for coating wet rubber particles during extrusion and pelletization prior to drying comprising an inorganic partitioning agent, a thickener and binder reagent, water and a water soluble anionic dispersant, and the process for application to elastomers including those of low viscosity or high resin content to improve their processability during manufacture.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: September 24, 1996
    Assignee: DSM Copolymer, Inc.
    Inventor: Lincoln Widmer
  • Patent number: 5556923
    Abstract: The present invention provides a continuous process for producing an adducted derivatized EPM or EPDM oil solution, in which a grafted ethylene polymer is adducted with an antioxidant diamine for formation of an adduct during holding.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: September 17, 1996
    Assignee: DSM Copolymer, Inc.
    Inventors: Tony L. Caines, Michael L. Junker
  • Patent number: 5534171
    Abstract: A polymeric lubricant additive that behaves as a viscosity index improver and imparts enhanced anti-oxidancy, dispersancy, and anti-wear properties to said lubricant oil has been prepared. The polymeric substrate is a random co- or terpolymer of ethylene propylene and a third monomer; or a block terpolymer of styrene--ethylenebutylene--styrene where hydrogenation has removed aliphatic unsaturation.Ethylenically unsaturated carboxylic acid or acid anhydride is grafted to these aforementioned substrates and imidized with amino-thiadiazole of the formula: ##STR1## wherein R.sub.1 is H.sub.2 or a (C.sub.1 -C.sub.10) alkyl radical selected from the group consisting of a alkyl, alkenyl, alkoxyl, aralkyl, alkaryl, hydroxyalkyl and aminoalkyl, to produce said polymeric lubricant additive.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 9, 1996
    Assignee: DSM Copolymer Inc.
    Inventors: Thomas F. Derosa, Nicholas Benfaremo, Maria M. Kapuscinski, Benjamin J. Kaufman, Rosemary J. Jennejahn
  • Patent number: 5525668
    Abstract: Novel thermoplastic elastomer compositions, made by dispersing a polyolefin elastomer phase containing functionalized EPM or EPDM in a polyamide resin followed by cross-linking of the elastomer phase, are described. The cross-linked phase exists as discreet particles, providing an overall blend which remains thermoplastic. The resulting blend may be used in the fabrication of elastomeric goods without the need for a separate vulcanization step after the desired object is formed.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: June 11, 1996
    Assignee: DSM Copolymer, Inc.
    Inventor: Errol J. Olivier
  • Patent number: 5516849
    Abstract: The present invention provides a continuous process for producing an adducted derivatized EPM or EPDM oil solution in which a grafted ethylene polymer is adducted with an antioxidant diamine for formation of an adduct during holding.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: May 14, 1996
    Assignee: DSM Copolymer, Inc.
    Inventors: Tony L. Caines, Michael L. Junker
  • Patent number: 5475121
    Abstract: A catalyst precursor is provided that is useful in the selective hydrogenation of olefinic unsaturation in polymers or copolymers. The precursor comprises a palladium salt that is complexed with a complexing agent selected from the group consisting of organic phosphates, dialkylidene acetones, and tetraalkyl ammonium hydroxides. The catalyst precursor may be used in batch, step-wise addition, or continuous systems.
    Type: Grant
    Filed: September 22, 1994
    Date of Patent: December 12, 1995
    Assignee: DSM Copolymer,Inc.
    Inventor: Robert T. Patterson
  • Patent number: 5451630
    Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and to yield a product that can be recovered as a solid using conventional plastic processing equipment. The sheared blend of polymers can function as a shear stable viscosity index improver with improved lower temperature properties.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: September 19, 1995
    Assignee: DSM Copolymer, Inc.
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 5451636
    Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and to yield a product that can be recovered as a solid using conventional plastic processing equipment. The sheared blend of polymers can function as a shear stable viscosity index improver with improved lower temperature properties.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: September 19, 1995
    Assignee: DSM Copolymer, Inc.
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 5391617
    Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and to yield a product that can be recovered as a solid using conventional plastic processing equipment. The sheared blend of polymers can function as a shear stable viscosity index improver with improved lower temperature properties.
    Type: Grant
    Filed: August 2, 1993
    Date of Patent: February 21, 1995
    Assignee: DSM Copolymer, Inc.
    Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
  • Patent number: 5384371
    Abstract: The present invention provides a continuous process for producing an adducted derivatized EPM or EPDM oil solution in which a grafted ethylene polymer is adducted with an antioxidant diamine for formation of an adduct during holding.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: January 24, 1995
    Assignee: DSM Copolymer, Inc.
    Inventors: Tony L. Caines, Michael L. Junker