Patents Assigned to DSM Fine Chemicals Austria GmbH
  • Patent number: 6319697
    Abstract: (S)-Hydroxynitrile lyases which have an improved substrate acceptance and which are derived from the Hevea brasiliensis and Manihot esculenta (S)-hydroxynitrile lyases, wherein one or more bulky amino acid residues within the hydrophobic channel leading to the active center have been replaced with less bulky amino acid residues.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: November 20, 2001
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Franz Effenberger, Harald Wajant, Peter Lauble, Siegfried Förster, Holger Buhler, Helmut Schwab, Christoph Kratky, Ulrike Wagner, Ernst Steiner
  • Patent number: 6225095
    Abstract: Process for the preparation of the (S)-enantiomers of optically active cyanohydrins, in which a reaction mixture of a) an aldehyde or ketone dissolved in an organic, water-immiscible or slightly miscible diluent, b) an aqueous (S)-hydroxynitrile lyase solution and c) a cyanide group donor is stirred in such a way that an emulsion is formed which is maintained up to the end of the reaction by stirring.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: May 1, 2001
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Peter Pöchlauer, Michael Schmidt, Irma Wirth, Rudolf Neuhofer, Antonia Zabelinskaja-Mackova, Herfried Griengl, Cor Van den Broek, Raf Reintjens, Herman Jelle Wories
  • Patent number: 6222063
    Abstract: Process for transesterifying &agr;-ketocarboxylic esters in an anhydrous alcohol as reaction medium in the presence of tin catalysts, titanium catalysts, zirconium catalysts or lithium catalysts or of acetylacetonates as catalysts.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: April 24, 2001
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Curt Zimmermann, Johann Friedhuber
  • Patent number: 6090975
    Abstract: Process for the preparation of 2-acetylcarboxylic esters by reacting an acetoacetic ester having 1 to 6 C atoms in the alkyl moiety with an aliphatic aldehyde having 1 to 12 C atoms at 0 to 40.degree. C. in the presence of a condensation catalyst, subsequently removing the water of reaction formed and unreacted starting materials and then hydrogenating the material at 20-160.degree. C., the temperature in the first hydrogenation phase being between 20 and 90.degree. C. and the temperature in the second phase being increased to 50 to 160.degree. C., depending on the starting temperature.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: July 18, 2000
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Wolfgang Huber, Gunter Eichberger, Harald Poschko, Gerhard Burschik
  • Patent number: 6031123
    Abstract: A process for stabilizing enantiomer-enriched cyanohydrins where citric acid and/or boric acid or boric anhydride is added as a stabilizer to the cyanohydrin to be stabilized.
    Type: Grant
    Filed: May 13, 1999
    Date of Patent: February 29, 2000
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Peter Pochlauer, Irma Wirth, Rudolf Neuhofer
  • Patent number: 6031040
    Abstract: Intumescent sealing and cover profiles obtainable by extrusion of a mixture comprising thermoplastic elastomers, expandable graphite, flame retardants, inorganic fillers and inorganic fibers at from 180 to 250.degree. C. and subsequent shaping to form the appropriate profiles, and their use.
    Type: Grant
    Filed: May 21, 1998
    Date of Patent: February 29, 2000
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventor: Heinrich Horacek
  • Patent number: 5993609
    Abstract: A process for the purification of recovered or regenerated phosphorus oxychloride contaminated by reactive organic compounds, by reacting the contaminated phosphorus oxychloride with from 0.1 to 5% by weight of an organic amine, having 1 or 2 tertiary N-atoms and a boiling point above the boiling point of phosphorus oxychloride, at the boiling temperature of the reaction mixture and subsequently carrying out fractional distillation at atmospheric pressure to obtain purified phosphorus oxychloride.
    Type: Grant
    Filed: September 2, 1998
    Date of Patent: November 30, 1999
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Karl Schwendinger, Engelbert Kloimstein
  • Patent number: 5952206
    Abstract: An improved process for preparing L-aspartic acid by enzyme-catalyzed reaction of fumaric acid with ammonia, in which, after reaction has been completed, excess ammonia is removed from the reaction mixture, L-aspartic acid is precipitated by adding acetic acid or formic acid, whereupon formic acid and acetic acid are rereleased from the mother liquor by adding fumaric acid, and the ammonia released and the liberated formic or acetic acid and the ammonium fumarate formed in the liberation are reused for subsequent cycles.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: September 14, 1999
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Karl-Heinz Giselbrecht, Josef Schaller
  • Patent number: 5939580
    Abstract: Process for preparing glyoxylic esters or their hydrates in which a water-soluble salt of a maleic or fumaric monoester or a mixture thereof is reacted with ozone in aqueous solution at temperatures of from 0 to 50.degree. C., and the corresponding glyoxylic ester or its hydrate is isolated from the resulting reaction mixture.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: August 17, 1999
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Engelbert Kloimstein, Wolfram Hendel, Klaus Reiter, Christian Burger, Antonia Praus, Karl Heinz Giselbrecht, Eduard Perndorfer
  • Patent number: 5929251
    Abstract: Process for the preparation of carboxylic acid succinimidyl esters by reaction of N-hydroxysuccinimide with a carboxylic acid and a halophosphoric acid ester of the formula ##STR1## in which R.sub.1 and R.sub.2 are identical or different and are a C.sub.2 - to C.sub.6 -alkyl radical or a phenyl radical, or R.sub.1 and R.sub.2 together form a C.sub.6 -aryl radical, in the presence of a base in a diluent at a temperature of 0.degree. C. up to 100.degree. C. and isolation of the corresponding carboxylic acid succinimidyl ester.
    Type: Grant
    Filed: December 30, 1997
    Date of Patent: July 27, 1999
    Assignee: DSM Fine Chemicals Austria GmbH
    Inventors: Peter Pochlauer, Wolfram Hendel, Christian Burger, Anita Lamplmayr, Harald Poschko, Antonia Praus, Gerald Summer
  • Patent number: 5902737
    Abstract: A process for the preparation of disodium Z-L-aspartate from fumaric acid, in whicha) fumaric acid is reacted with ammonia in an inert diluent in the presence of aspartase or aspartase-producing microorganisms to give ammonium L-aspartate thenb) the ammonium L-aspartate-containing solution is treated with sodium hydroxide, forming, depending on the amount of sodium hydroxide used, the mono- or disodium L-aspartate or a mixture thereof, andc) the eliminated ammonia is returned to a fumaric acid suspension, which is used as starting solution for further enzymatic reactions, and thend) the residual mono and/or disodium L-aspartate-containing solution is reacted with benzyloxycarbonyl chloride at a pH of between 9 and 14, with the simultaneous addition of sodium hydroxide, to form disodium Z-L-aspartate.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 11, 1999
    Assignees: DSM Fine Chemicals Austria GmbH, Holland Sweetener Company V.o.V.
    Inventors: Gerald Kirchner, Erik Salzbrenner, Christian Werenka, Wilhelmus Boesten