Patents Assigned to DSM
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Patent number: 7041712Abstract: A radiation-curable composition for an ink base, ink composition, outer primary composition, buffering material or matrix material for fiber optics includes, in the uncured state, a secondary amino or tertiary amino silicone-containing additive.Type: GrantFiled: December 23, 2002Date of Patent: May 9, 2006Assignee: DSM IP Assets B.V.Inventors: Edward J. Murphy, Edward P. Zahora, Nancy L. Coster, Glenn Evans
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Publication number: 20060093779Abstract: Optical disc adhesives and lacquers comprising components that undergo free-radical polymerization when exposed to radiation and a cure-enhancing amount of R—SH, wherein R is a heterocycle; cationic, free-radical, and hybrid adhesives for digital versatile discs (DVD) comprising components that undergo cationic and/or free-radical polymerization when exposed to radiation and a corrosion-inhibiting amount of R—SH, R1-R2 and/or an acyclic thiol, wherein R is a heterocycle, R1 is a substituted or unsubstituted phenyl as a substituent of R2 or forming with R2 a bicyclic structure, and R2 is a heterocycle comprising at least one double bond and at least two N atoms; and optical media, e.g., CD-DA, CD-ROM, CD-R, DVD, and the like, that include one, or a combination, of the foregoing inventive adhesive or lacquer compositions.Type: ApplicationFiled: December 14, 2005Publication date: May 4, 2006Applicant: DSM N.V.Inventors: Chander Chawla, Michael Sullivan, Vadim Krongauz, Christopher Tronche
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Publication number: 20060084756Abstract: Coating compositions are provided that, when cured, provide a coating with low refractive index, surface hardness, scratch resistance, abrasion resistance and good curability at low film thickness. In one embodiment, a composition is provided that comprises reactive nanoparticles free of fluorinated group, reactive nanoparticles having at least one fluorinated group, and an ethylenically unsaturated urethane fluorinated component.Type: ApplicationFiled: April 21, 2005Publication date: April 20, 2006Applicant: DSM IP Assets B.V.Inventors: John Southwell, Chander Chawla
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Patent number: 7029885Abstract: Ampicillin is produced in a batch process by enzymatic acylation of 6-aminopenicillanic acid (6-APA) with the aid of phenylglycine derivative such as D-phenylglycine amide. High conversions of phenylglycine derivative may be achieved by having the total concentration in the reaction mixture of 6-APA and ampicillin greater than 250 mM and the molar ration of total quantity of phenylglycine derivative to total quantity of 6-APA less than 2.5. Higher yields of ampicillin may be achieved when the amount of dissolved 6-APA is kept low, e.g. below 300 mM.Type: GrantFiled: December 10, 1999Date of Patent: April 18, 2006Assignee: DSM IP Assests B.V.Inventors: Harold M. Moody, Wilhelmus H. J. Boesten
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Publication number: 20060076534Abstract: Inner and outer primary and matrix material compositions which, after curing, exhibit a high degree of uniformity after curing even when the coating is applied onto optical fibers at relatively high shear rates, e.g., such as those experienced at high optical fiber coating line speeds. These compositions are provided in significant part by the selective incorporation of at least one radiation-curable oligomer into the compositions. In particular, and with respect to inner primary coatings, the oligomer should be selected so that the value m of an uncured radiation-curable inner primary coating composition in the equation ? = K ? ? ? ? ? ? ? ? 1 + ( ? ? ? ? ? ) m ( I ) is advantageously equal to or greater than about 0.90.Type: ApplicationFiled: November 21, 2005Publication date: April 13, 2006Applicant: DSM N.V.Inventors: David Szum, Robert Johnson
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Patent number: 7026028Abstract: Multi-layer moulding, containing a body part and a surface layer which at least partly covers the body part, which body part contains a cross-linked elastomer composition and which surface layer contains a thermoplastic elastomer, in which the surface layer of the multi-layer moulding, in a weather resistance test according to DIN 75202, in which the surface layer is continuously exposed for at most 100 hours to light from a xenon light source, which light source is provided with a borosilicate “S” inner filter and a soda lime outer filter, at a relative humidity of 30%, with an intensity of 1.40 W/m2 at 420 nanometres on the surface of the moulding, a black standard temperature of 100° C., in a space with a temperature of 66° C., develops a colour deviation with a ?E of at most 3.0, measured according to ASTM D 1925.Type: GrantFiled: June 19, 2002Date of Patent: April 11, 2006Assignee: DSM IP Assets B.V.Inventors: Pieter Gijsman, Gerardus L. M. Vroomen, Edwin Willems
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Publication number: 20060073106Abstract: The invention relates to a method of enhancing the photostability of an encapsulated cinnamate derivative in a topical sunscreen composition which comprises introducing into such sunscreen composition an effective amount of at least one additional non-encapsulated sunscreen.Type: ApplicationFiled: September 25, 2003Publication date: April 6, 2006Applicant: DSM IP Assets B.V.Inventors: Katja Berg-Schultz, Volker Schehlmann, Horst Westenfelder
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Publication number: 20060073343Abstract: The present invention provides curable compositions and rapid prototyping processes using the same. In one embodiment, the present compositions include one or more aromatic epoxies and one or more aliphatic epoxies, and, after full cure, exhibit a heat deflection temperature of at least 105° C. and an elongation at break of at least 1.5%.Type: ApplicationFiled: November 21, 2005Publication date: April 6, 2006Applicant: DSM IP Assets B.V.Inventor: Jigeng Xu
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Patent number: 7018817Abstract: Process for the preparation of a compound with enhanced optical purity wherein a mixture of the enantiomers of a chiral compound of formula 1 wherein: R1 represents an alkyl or an aryl group R2 represents H, an alkyl or an aryl group Y represents an alkyl group, an aryl group, (CH2)nCOOH, (CH2)n—COOR, (CH2)n—CONRR?, CH2OH, or C?N wherein R and R? independently represent H, an alkyl or aryl group, and n represents 0 or 1, is brought into contact with an enzyme having peptide deformylase activity with a bivalent metal ion as a cofactor wherein the metal is chosen from the groups 5–11 of the periodic system, or for the preparation of a formylated compound with enhanced optical purity from a mixture of the enantiomers of the corresponding not formulated chiral compound in the presence of a formylation agent. Preferably the peptide deformylase is chosen from the class EC 3.5.2.27 or EC 3.5.1.31, and contains the sequences of (I) HEXXH, (ii) EGCLS and (iii) GXGXAAXQ.Type: GrantFiled: December 17, 1999Date of Patent: March 28, 2006Assignee: DSM IP Assets B.V.Inventors: Peter Jan Leonard Mario Quaedflieg, Theodorus Sonke, Adolf Fritz Volker Wagner
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Patent number: 7019020Abstract: Novel benzoxazolyl benzene derivatives of formula (I): wherein R1 is hydrogen, C1-20-alkyl or C2-20-alkenyl; R2 and R3 are independently a group —C(R4,R5)C(R6)?C(R7,R8) (a) or a group —C(R4?,R5?)CH(R6?)CH(R7?,R8?) (b), wherein R4, R5, R6, R7, R8, R4?, R5?, R6?, R7? and R8? are independently, hydrogen, C1-10-alkyl or C2-10-alkenyl, or C2-10-alkyl or C3-10-alkenyl containing at least one oxygen atom interrupting the hydrocarbon chain; or wherein R4, R5, R6, R4?, R5? and R6? are hydrogen, C1-10-alkyl or C2-10-alkyl containing at least one oxygen atom interrupting the hydrocarbon chain, or alkyl substituted by silane or oligosiloxane moiety, and one of R7 and R8 or R7? and R8? is a silane or oligosiloxane moiety and the other one of R7 and R8 or R7? and R8? is hydrogen; and X is phenylene or naphthylene, or substituted phenylene or naphthylene for use as UV screening agents for protecting human skin or hair against radiation, and in UV screening compositions, particularly topical compositions for cosmentic orType: GrantFiled: January 28, 2002Date of Patent: March 28, 2006Assignee: DSM IP Assets B.V.Inventor: Ulrich Huber
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Publication number: 20060062539Abstract: The invention relates to coated optical fibers comprising soft primary coatings and to such primary coatings for protecting glass optical fibers having a sufficient high resistance against cavitation. In particular, the primary coatings have a cavitation strength at which a tenth cavitation appears (?10cav) of at least about 1.0 MPa as measured at a deformation rate of 0.20% min?1 and of at least about 1.4 times their storage modulus at 23° C. The coating preferably shows strain hardening in a relative Mooney plot, preferably has a strain energy release rate Go of about 20 J/m2 or more, and preferably has a low volumetric thermal expansion coefficient. The invention furthermore provides a method and apparatus for measuring the cavitation strength of a primary coating.Type: ApplicationFiled: November 9, 2005Publication date: March 23, 2006Applicant: DSM IP Assets B.V.Inventors: Markus Bulters, Gerrit Rekers, Philippe Bleiman, Jozef Linsen, Alexander Stroeks, Johannes Van Eekelen, Adrianus Abel, Marko Dorschu, Paulus Steeman
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Patent number: 7015014Abstract: The present invention relates to a crystalline carotenoid compound, such as ?-carotene, with a purity of at least 95% and with substantially no solvent enclosed in the crystal lattice. The present invention further describes a process to prepare such a highly pure crystalline carotenoid compound from microbial biomass, without the use of a solvent extraction and/or an anti-solvent crystallization process.Type: GrantFiled: January 29, 2001Date of Patent: March 21, 2006Assignee: DSM IP Assets B.V.Inventors: Albert Schaap, Mieke Sibeijn, Johannes Hendrik Wolf
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Patent number: 7012149Abstract: A process is provided for making (?)-epigallocatechin gallate (EGCG) by subjecting a green tea extract to chromatography on a macroporous polar resin, eluting EGCG from the resin with a polar elution solvent, optionally concentrating the eluate, optionally regenerating the resin by desorbing the remaining catechins, and optionally concentrating the desorbed catechins.Type: GrantFiled: September 18, 2002Date of Patent: March 14, 2006Assignee: DSM IP Assets B.V.Inventors: David Carl Burdick, Heinz Egger, Andrew George Gum, Ingo Koschinski, Elena Muelchi, Isabelle Prevot-Halter
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Publication number: 20060051564Abstract: The invention relates to a process for the manufacture of a ballistic-resistant moulded article in which a stack of monolayers is formed, each monolayer containing unidirectionally oriented reinforcing fibres and at most 30 mass % of a plastic matrix material, the reinforcing fibres being highly-drawn polyethylene fibres, and with the fibre direction in each monolayer being rotated with respect to the fibre direction in an adjacent monolayer, the stack then being compressed at a pressure of more than 25 MPa and a temperature between 125 and 150° C., and the plastic matrix material having a 100% modulus of at least 3 MPa.Type: ApplicationFiled: October 31, 2003Publication date: March 9, 2006Applicant: DSM IP Assets B.V.Inventors: Martinus Jacobs, Jean Beugels, Marc Blaauw
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Publication number: 20060048494Abstract: The invention relates to a method to make a splice in a laid rope construction comprising at least two strands, wherein: a) one end of a first rope end is split in a first and a second part comprising respectively a first and a second number of strands, the first number of strands being at most one more than the second number of strands; b) the first part is tucked from one side into an opening in a second rope, such that the opening has a first number of strands of the second rope on one side and a second number of strands on the other side, where the first and second number differ at most by one; c) the second part is tucked from the other side into the opening in the second rope; and d) step b) and c) are repeated at least 3 respectively at least 3+1 times, whereby the respective openings in the second rope are separated such that the first and the second part have crossed over at least all the strands of the second rope once and the first and second part leave the second rope at respective last openings.Type: ApplicationFiled: October 31, 2003Publication date: March 9, 2006Applicant: DSM IP Assets B.V.Inventors: Karel Wetzels, Christiaan Dirks
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Patent number: 7005547Abstract: The invention relates to a process for the production of cyclohexanone oxime in which a phosphate-containing aqueous reaction medium is cycled from a hydroxylammonium synthesis zone to a cyclohexanone oxime synthesis zone and back to the hydroxylammonium synthesis zone, in which hydroxylammonium synthesis zone hydroxylammonium is formed by catalytic reduction of nitrate with hydrogen, and in which cyclohexanone oxime synthesis zone hydroxylammonium is reacted with cyclohexanone to form cyclohexanone oxime, the cyclohexanone and an organic solvent being fed into the cyclohexanone oxime synthesis zone, an organic medium comprising the organic solvent and cyclohexanone oxime being withdrawn from the cyclohexanone oxime synthesis zone, characterized in that the ratio fh/fc<1.Type: GrantFiled: May 31, 2001Date of Patent: February 28, 2006Assignee: DSM IP Assets B.V.Inventors: Marc Blaauw, Antonius Jacobus Franciscus Simons, Henk Oevering
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Publication number: 20060035321Abstract: The invention relates to isolated polypeptides with hydantoin recemase activity, that do not suffer from substrate inhibition. Such polypeptides arc for instance isolated polypeptides with at least 87% idcntity with SEQ ID: NO. 2 or SEQ ED: NO. 4. The invention also relates to nucleic acid sequences encoding these polypeptides. The invention also relates to processes for the racemisation of enantiomerically enriched hydantoin compounds and to processes for the preparation of enantiomarically enriched I)-or I-? amino acids.Type: ApplicationFiled: May 23, 2003Publication date: February 16, 2006Applicant: DSM IP Assets B.V.Inventors: Wilhelmus Hubertus Boesten, Joannes Kierkels, Bernard Assema, Luis Fuiz Perez, Dolores Gonzalez Pacanowska, Jesus Gonzalez Lopez, Santiago De La Escal Era Hueso
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Patent number: 6995003Abstract: The invention provides DNA, heterologous host cells capable of transcribing, translating or expressing said DNA and methods employing such host cells and cultures thereof for an improved in vivo production of acylated cephalosporins with higher yield. According to the invention, a host cell is provided comprising an enzyme having expandase activity which is predominantly localized in the cytosol (as opposed to localized mainly in or with the peroxisomes or microbodies) of the host cell.Type: GrantFiled: May 19, 1999Date of Patent: February 7, 2006Assignee: DSM IP Assets B.V.Inventors: Maarten Nieboer, Roelof Ary Lans Bovenberg
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Publication number: 20060024010Abstract: A coated optical fiber can have a primary coating and a secondary coating, where the primary coating can have good microbending resistance and is obtained by curing a composition having a high cure speed. In one example, a coated optical fiber can include as optical fiber, a primary coating and a secondary coating. The optical fiber can have an attenuation increase of less than 0.650 dB/km at 1550 nm, with the primary coating having a modulus retention ratio of at least 0.5, a glass transition temperature of ?35° C., and where the primary coating is obtained by curing a primary coating composition having a cure dose to attain 95% of the maximum attainable modulus of less than 0.65 J/cm2.Type: ApplicationFiled: October 3, 2005Publication date: February 2, 2006Applicant: DSM IP Assets B.V.Inventors: Jan van Eekelen, Joanna Nagelvoort, Duurt Alkema, Paul Buijsen, Huimin Cao, Robert Johnson, David Szum
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Patent number: 6992121Abstract: Aqueous emulsion of a polymodal multistage polymeric material, wherein: (i) at least 50% of the polymodal multistage polymeric material comprises the polymers of at least two polymerisation stages having a Tg difference of ?20° C., more preferably ?40° C., and most preferably ?60° C.; (ii) at least 50% of the polymodal multistage polymeric material comprises the polymers of at least two polymerisation stages having a Dw differing by ?50 nm, preferably ?80 nm and more preferably ?100 nm; and (iii) the means to form at least one of the differing Tg's in (i) and at least one of the differing Dw's in (ii) are carried out in different stages of the multistage polymerisation to form the polymeric material. The polymer emulsion is useful for protective coatings, printing inks, overprint lacquer formulations, polishes, varnishes, sealants, paint formulations and adhesives.Type: GrantFiled: November 16, 2000Date of Patent: January 31, 2006Assignee: DSM IP Assets B.V.Inventors: Antonius Carolus Ida Adrianus Peters, Gerardus Cornelis Overbeek