Abstract: Process for the preparation of an optically active N-acyl-indoline-2-carboxylic acid in which a mixture of enantiomers of N-acyl-indoline-carboxylic acid is contacted with an optically active resolving agent and the optically active N-acyl-indoline-2-carboxylic acid is liberated from the resulting diastereomeric salt, as resolving agent use being made of a compound of formula 1, where R.sub.1 represents an alkyl group and R.sub.2 a hetero-aryl group or where R.sub.1 and R.sub.2 together with the C atoms to which they are bound form a cycloalkyl group with 5-8 C atoms, fused with a hetero-aryl group.
Abstract: A dual chambered dispensing system allows for application of an aqueous composition containing a biologically effective compound which is adequately stabilized. The system separately contains the stabilized biologically effective compound composition in one chamber and an aqueous basic composition in the other. Both compositions are simultaneously delivered from the dispensing system, whereupon the compositions are mixed to result in a final composition suitable for direct application.
Type:
Grant
Filed:
April 28, 1998
Date of Patent:
September 12, 2000
Assignee:
DSM N.V.
Inventors:
Luppo Edens, Hong Sheng Tan, Johannes Wilhelmus Jacobus Lambers
Abstract: Method for increasing the capacity of an existing urea process, the existing urea process comprising a reactor (R), a pressure-reduction section (SC) and a urea-recovery section (U), characterized in that(i) a stripping column (S) is added, in which ammonium carbamate from the reaction mixture is stripped with carbon dioxide or is thermally stripped at almost the same elevated pressure, resulting in a gaseous mixture (G1) and a liquid mixture (M4), which liquid mixture (M4) is fed to the pressure-reduction section (SC),(ii) a condenser (C) is added, which is fed with the gaseous mixture (G1), ammonia and optionally carbon dioxide, in which the gaseous mixture (G1) is condensed at almost the same elevated reactor pressure (P) and at least 30% of the equilibrium amount of urea obtainable under the condensation conditions is furthermore formed, in which a liquid mixture containing urea, water and ammonium carbamate (MS) is formed, which mixture is fed to the bottom of the existing reactor (R), and a gaseous mixt
Abstract: Polysubstituted cyclopentadiene compound, wherein at least one substituent is of the form --RDR'.sub.n, where R is a bonding group between the cyclopentadiene and the DR'.sub.n group, D is a hetero atom chosen from group 15 or 16 of the Periodic Table of the Elements, R' is a substituent and n is the number of R' groups bonded to D, and in which at least one further substituent is a linear alkyl group comprising at least 2 carbon atoms.
Type:
Grant
Filed:
November 2, 1998
Date of Patent:
September 12, 2000
Assignee:
DSM N.V.
Inventors:
Gerardus J. M. Gruter, Johannes A. M. van Beek, Richard Green, Edwin G. Ijpeij
Abstract: In the present process for the preparation of urea, an off-gas stream released during the synthesis of melamine in a high-pressure melamine process which consists predominantly of ammonia and carbon dioxide, is introduced into at least one high-pressure section of a urea stripping plant and is used in the synthesis of urea. The off-gas stream can be used directly without any further treatment.
Abstract: Process for the preparation of urea, in which the gas stream which is released during the synthesis of melamine and is composed essentially of ammonia and carbon dioxide is used to synthesize urea, in which process the gas stream which originates from a high-pressure melamine process and is composed essentially of ammonia and carbon dioxide is condensed at a pressure virtually equal to the pressure in the melamine reactor, in which process substantially anhydrous ammonium carbamate is formed, after which said ammonium carbamate is fed to a high-pressure section of a urea stripping plant.
Type:
Grant
Filed:
July 28, 1999
Date of Patent:
August 29, 2000
Assignee:
DSM N.V.
Inventors:
Julius G. T. Van Wijck, Jozef H Meessen
Abstract: Optical fiber primary coating systems are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be inner piramry coating composition having a slip enhancing component and a high modulus outer primary coating composition. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.
Type:
Grant
Filed:
May 21, 1998
Date of Patent:
August 29, 2000
Assignee:
DSM N.V.
Inventors:
David M. Szum, Chander P. Chawla, James R. Petisce, George Pasternack, Timothy E. Bishop, Paul E. Snowwhite, Edward P. Zahora
Abstract: A process for depolymerizing nylon 6 and recovering caprolactam from the depolymerized products by extraction with alkyl phenolic compounds. Process steps include (a) treating a first mixture comprising nylon 6 with water at a temperature between about 200.degree. C. and about 400.degree. C. to yield a second mixture comprising depolymerized nylon 6 components, wherein the second mixture contains caprolactam at a concentration between about 5 wt. % and about 35 wt. %; (b) optionally, separating insoluble material from the second mixture; (c) extracting the second mixture with an extraction agent to yield an aqueous raffinate third mixture and an organic phase fourth mixture comprising caprolactam and the extraction agent, wherein the extraction agent is an alkyl phenol having a boiling point higher than that of the caprolactam; (d) recovering caprolactam from the organic phase fourth mixture by distillation; (e) recycling the aqueous raffinate third mixture to step (a).
Type:
Grant
Filed:
January 12, 1998
Date of Patent:
August 29, 2000
Assignee:
DSM N.V.
Inventors:
Yvonne H Frentzen, Marcellinus P. G. Thijert, Rudolf L. Zwart
Abstract: The invention relates to a solvent-free radiation curable, optical glass fiber coating composition containing:a) a urethane oligomer having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1.2, having a vinyl addition polymer as backbone.b) a urethane compound having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1, containing an organic moiety having about 5 or more carbon atoms as backbone.c) a reactive diluent.Furthermore, the invention relates to a solvent-free method for producing a solvent-free, radiation curable urethane oligomer composition.
Type:
Grant
Filed:
October 8, 1998
Date of Patent:
August 22, 2000
Assignee:
DSM N.V.
Inventors:
Anthony J. Tortorello, Edward J. Murphy
Abstract: This invention relates to a novel multi-functional fuel and lubricant additive that provides dispersancy properties as well as viscosity index improved credit, improved fuel economy and low temperature viscometric properties. The invention further relates to concentrates, fuel and lubricating oil compositions containing said additive.
Type:
Grant
Filed:
October 15, 1997
Date of Patent:
August 22, 2000
Assignees:
Ethyl Corporation, DSM N.V.
Inventors:
Carl Kurt Esche, Jr., Anthony J. Rollin, Mark Thomas Devlin
Abstract: A process to prepare the E isomer of a 3-substituted (6R,7R)-7-phenyl-acetamido-ceph-3-em-4-carboxylic acid from a mixture of the E and Z-isomer of either the corresponding tert-butyl or the corresponding 4-methoxybenzyl ester of a 3-substituted (6R,7R)-7-phenylacetamido-ceph-3-em-4-carboxylate, characterized by the application of a compound selected from the group titanium tetrachloride, tin tetrachloride and tellurium tetrachloride.
Abstract: The present invention relates to diagnostic assays whereby the detection means is based on electrochemical reactions. This means that the label to be detected provides an electric signal. Preferred labels are enzymes giving such a signal. Provided is a flow cell whereby a solid phase is provided in a flow stream of the sample, in close proximity to a working electrode to detect any electrical signal. In a typical embodiment, a sample is mixed with molecule having specific binding affinity for an analyte of which the presence in the sample is to be detected, whereby said specific binding molecule is provided with a label. The conjugate of labelled specific binding molecule and analyte is then immobilized on the solid phase in the vicinity of the working electrode, the flow cell is rinsed with a solution and afterwards a substrate solution for the label (an enzyme) is provided upon which an electrical signal is generated and can be detected by the working electrode.
Abstract: A photo-curable resin composition capable of providing a three-dimensional object having excellent mechanical strength and high dimensional accuracy when used in a photo-fabrication process. The resin composition is also capable of providing a three-dimensional object with excellent stability in shape and properties in a photo-fabrication process. The photo-curable composition includes:(A) a compound represented by the formula (1) ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom or a methyl group;(B) a compound having a cyclohexene oxide structure;(C) a cationic photo-initiator;(D) an ethylenically unsaturated monomer;(E) a radical photo-initiator; and(F) a polyol having three or more hydroxyl groups.
Type:
Grant
Filed:
December 10, 1997
Date of Patent:
August 1, 2000
Assignees:
DSM N.V., JSR Corporation, Japan Fine Coatings Co., Ltd.
Abstract: A method of cleaning a substrate by covering the substrate with a composition in a sufficient amount to clean the substrate. The composition includes a substantial amount of at least one low viscosity organic compound which includes a radiation curable group. The compound is reclaimed for further use. The reclaimed compound may be used as a reactive diluent in a radiation curable coating composition.
Abstract: Process for the preparation of 2-acetylcarboxylic esters by reacting an acetoacetic ester having 1 to 6 C atoms in the alkyl moiety with an aliphatic aldehyde having 1 to 12 C atoms at 0 to 40.degree. C. in the presence of a condensation catalyst, subsequently removing the water of reaction formed and unreacted starting materials and then hydrogenating the material at 20-160.degree. C., the temperature in the first hydrogenation phase being between 20 and 90.degree. C. and the temperature in the second phase being increased to 50 to 160.degree. C., depending on the starting temperature.
Type:
Grant
Filed:
December 29, 1998
Date of Patent:
July 18, 2000
Assignee:
DSM Fine Chemicals Austria GmbH
Inventors:
Wolfgang Huber, Gunter Eichberger, Harald Poschko, Gerhard Burschik
Abstract: A process for the carbonylation of allylic butenol or butenyl ester of a carboxylic acid (e.g., crotyl acetate, 3-acetoxybutene-1 and mixtures thereof) in an anhydrous carboxylic acid solvent and production of beta-gamma unsaturated carboxylic acid anhydride (e.g., 3-pentenoic acid anhydride) utilizing a rhodium-containing catalyst (e.g., dicarbonylacetylacetonate rhodium(I)) promoted with a metal iodide (e.g., dicarbonylacetylacetonate rhodium(I), or the like). The following representative reaction showing a crotyl ester (i.e., a carboxylic acid ester of 2-buten-1-ol) as the reactant producing a corresponding pentenoic acid anhydride is illustrative of the overall carbonylation. ##STR1## Suitable allylic compounds are of the form ##STR2## where one of the groups R.sup.1, R.sup.2, and R.sup.3 is methyl and the other two groups are H and wherein R.sub.4 is selected from the group consisting of H and ##STR3## wherein R.sup.5 is selected from the group consisting of a C.sub.1 to C.sub.10 alkyl.
Type:
Grant
Filed:
December 18, 1998
Date of Patent:
July 11, 2000
Assignees:
E I. du Pont de Nemours and Company, DSM Desotech Inc.
Abstract: Process for the depolymerization of one or more polyamides into its monomeric components in the presence of water by means of at least one alkali metal compound, at least one alkaline-earth metal compound or a combination thereof. The depolymerization takes place at a pressure of between 0.2 and 2.0 MPa, so that high conversions are achieved and the depolymerization reaction proceeds faster, even in the presence of a high content of cyclic oligomers.
Abstract: The present invention discloses a method for obtaining feed pellets. The method includes the addition of active ingredients to feed pellets after the pellets have been extruded. The method further includes the addition of a solution or suspension of the desired feed or ingredient in a water or oil phase to the pellets under reduced pressure and subsequently increasing the pressure. The method results in pellets with a high degree of loading and in which the active ingredients are homogeneously distributed.
Type:
Grant
Filed:
February 9, 1998
Date of Patent:
July 4, 2000
Assignee:
DSM N.V.
Inventors:
Reinder Sietze Hamstra, Augustinus Franciscus Tromp
Abstract: Provided is a ribbon assembly having the functional capability of providing mid-span access without the use of additives, monomers or oligomers containing fluorine or silicone. The ribbon assembly is formulated from an oligomer which reduces the surface energy of the ink coating and/or the matrix material.
Type:
Grant
Filed:
August 5, 1998
Date of Patent:
July 4, 2000
Assignee:
DSM N.V.
Inventors:
Edward P. Zahora, Edward J. Murphy, David M. Szum, John T. Vandeberg, Gerry K. Noren, Eva Montgomery