Abstract: The present invention relates to coated metal substrates such as metal piping having improved environmental stress crack resistance and resistance to hydrolytic and/or cathodic disbondment. The coating composition contains a blend of modified and unmodified polyolefins as well as a tackifier. For cathodic disbondment resistance, the preferred tackifiers are rosin esters or hydrogenated versions thereof. The modified polyolefins are grafted versions of metallocene or non-metallocene produced low density or high density polyethylenes.

Abstract: A method for making multilayer polymer films with involves the use of preferably embossed rollers which oscillate oppositely with respect to each along their respective rotational axis. Multilayer film is made by passing two or more molten thermoplastic films through the nip of these rollers, thereby laminating the individual films together. The method is particularly useful for improving the adhesion between film layers, and/or when at least one of the layer is a liquid crystalline polymer. Such films are useful in packaging, multilayer containers and for circuit boards.

Abstract: This invention relates to high temperature, semi-crystalline, semi-aromatic nylon terpolymers with improved shrinkage resistance, made from terephthalic acid (TA), hexamethylene diamine (HMD) and/or 2-methyl pentamethylene diamine (2-MPMD) and another aliphatic dicarboxylic acid as monomers. These polymers display superior % TD (Transverse Direction) annealing shrinkage, as well as very good balance of mechanical performance as high temperature nylons.

Abstract: A multilayer film and a pouch containing a flowable material are disclosed. The multilayer film is made from two layers of a sealant film with an interposed layer of a polyethylene. The sealant film is made from a material comprising 10 to 100 parts by weight of a copolymer of ethylene and at least one C.sub.4 -C.sub.10 alpha-olefin manufactured in a polymerization process using a single-site polymerization catalyst and from 0 to 90 parts by weight of at least one polymer selected from the group consisting of a linear copolymer of ethylene and at least one C.sub.4 -C.sub.10 alpha-olephin having a density of from 0.900 to 0.930 g/cm.sup.3 and a melt index of from 0.3 to 2.0 dg/min, a high-pressure polyethylene having a density of from 0.916 to 0.930 g/cm.sup.3 and a melt index of from about 1 to 10 dg/min, and blends thereof. The polyethylene of the interposed layer is a high density polyethylene with a density of at least 0.930 g/cm.sup.3 and a melt index of less than dg/min.

Abstract: A film for adhering to a molding paste composite during its manufacture, said film being formed from a blend of a film forming polyamide resin and at least one release agent material selected from the group consisting of N, N' ethylene bis amides of the formula R.sub.1 --CO--NH--CH.sub.2 --CH.sub.2 --NH--CO--R.sub.2 wherein R.sub.1 is an aliphatic hydrocarbon chain of about 14 to about 42 carbon atoms, and R.sub.2 is a hydrogen atom or an aliphatic hydrocarbon of about 14 to about 42 carbon atoms, wherein the release agent material is present in an amount such that after the paste composite is formed, substantially all of the film can be removed from the surface of the composite. Also described are processes for making sheet molding and thick molding composites using such films.

Abstract: This invention relates to a method of producing nucleophilic amine functionalized polyolefins by reacting a polymer carrying an electrophilic functional group with a diamine having amino end-groups having different reactivities. The nucleophilic amine functionalized polyolefin has the composition:Polyolefin-X--R.sub.1 --NHR.sub.2where X is selected from the group of imide, amide, sulphonamide or amineR.sub.1 is a bivalent organic radicalR.sub.2 is H or an alkyl groupThe nucleophilic amine functionalized polyolefin has uses as a compatibilizer, adhesive, dyeable material, and dyability improver.

Abstract: A process for the copolymerization of (1) a carboxylic acid comprising terephthalic acid and mixtures thereof with isophthalic acid with (2) a mixture of hexamethylene diamine and 2-methyl pentamethylene diamine. The pressure in the polymerization process is maintained at at least about 2.15 MPa for a period of at least about 40 minutes so that the resultant copolyamide, when annealed, has less than 1% by weight based on the total weight of the copolyamide of fractions having melting points greater than 320.degree. C. Use of lower pressures and times tends to result in formation of a high melting fraction.

Abstract: A mouldable reinforced polyamide composition comprising;(a) a polyamide consisting essentially of between about 0.5 and about 99.5 mol. % of aliphatic diamines having 4-12 carbon atoms and a complementary amount of 2-methyl-pentamethylene diamine copolymerized with aliphatic dicarboxylic acids having 6-12 carbon atoms; and(b) a filler in an amount of 0.5 to 200 parts by weight per 100 parts by weight of said polyamide. The polyamide has an RV greater than about 20. Related polyamides, especially in which the acid is 1,12-dodecanedioic acid, are also disclosed. The polyamides may be used in a wide variety of end-uses, including moulding, and exhibit excellent gloss compared with nylon 6,6.

Abstract: This invention relates to a composition to improve the mechanical properties of blends of polyolefins and polyesters and particularly relates to compatibilizers for polyethylene and polyester blends and the method relating to their production. One particular embodiment of the compatibilizers is a polyolefin with a grafted monomer such as Polyethylene grafted with maleic anhydride and a terpolymer of ethylene such as ethylene, n-Butyl Acrylate and glycidyl methacrylate.

Abstract: An adhesive composition formed by admixing under melt conditions (a) 50-95% by weight of a moisture cross-linkable silane-grafted polyolefin having a melt viscosity of less than 100,000 cps, and (b) 5-50% by weight of a polyolefin grafted with at least one ethylenically-unsaturated carboxylic acid or anhydride, and derivatives thereof. The grafted polyolefin has a melt viscosity of less than 100,000 cps, and contains a catalyst for moisture cross-linking of the silane-grafted polyolefin of (a). The adhesive may be used to bond a variety of substrates.

Abstract: A process for the manufacture of a partially aromatic polyamide is disclosed. The process comprises the polymerization stages of, in sequence, feeding to a reactor a slurry of at least one aromatic dicarboxylic acid and at least one aliphatic diamine, then with the incremental addition of water and in the presence of 0.05 to 2% by weight of a monocarboxylic acid, heating the slurry to a temperature of at least 270.degree. C. while maintaining a pressure of at least 1.2 MPa. The preferred dicarboxylic acid is 2,6 naphthalene dicarboxylic acid. The polyamides may be used in the manufacture of products using melt processing techniques.

Abstract: A reuseable gasketless spout adaptable to conversion to a pump dispenser for fluid contained in a pouch made of inextensible film, comprises a spout-tube and a plunger with a conical tip, the plunger movable coaxially within the spout-tube. The spout is inserted into the pouch, its plunger first puncturing the pouch film, and the edges of the opening produced surround and form a gasketless seal with the outside wall of the spout-tube when the spout is fully inserted. The spout, after full insertion into the pouch, may be converted into a pump dispenser for fluid in the pouch by removing the plunger and replacing it with a pump which has a supply-tube extending coaxially through the spout-tube, into the fluid within the pouch. The dispenser, having the spout-tube in common with the spout is, like the spout, reuseable.

Abstract: An adhesive composition formed by admixing under melt conditions (a) 50-95% by weight of a moisture cross-linkable silane-grafted polyolefin having a melt viscosity of less than 100 000 cps, and (b) 5-50% by weight of a polyolefin grafted with at least one ethylenically-unsaturated carboxylic acid or anhydride, and derivatives thereof. The grafted polyolefin has a melt viscosity of less than 100 000 cps, and contains a catalyst for moisture cross-linking of the silane-grafted polyolefin of (a). The adhesive may be used to bond a variety of substrates.

Abstract: A structure is disclosed comprising a layer of polyurethane foam bonded to at least one layer of another material, especially a layer of fibreglass matte, a layer of cellulosic material e.g. cardboard, and/or a layer of polyurethane foam. The layers are bonded together with an adhesive of polyethylene or polypropylene that has been grafted with an ethylenically unsaturated dicarboxylic acid or anhydride thereof, the adhesive containing at least 0.03% by weight of said acid or anhydride. The structure exhibits a temperature for heat-fail resistance in shear of at least 90.degree. C. In embodiments, the polyurethane foam is a rigid polyurethane foam, and the polyethylene and polypropylene have been grafted with fumaric acid, maleic acid or maleic anhydride. As an example, the structure is comprised of a layer of fibreglass matte, at least one layer of polyurethane foam and a layer of fibreglass matte, the layers being bonded together with the adhesive.

Abstract: A dispenser of flowable materials from a pouch is disclosed. The pouch has an ear (55) at each of the ends of a transverse seal (53) located at one end of the pouch (57). The dispenser comprises i) a cylindrical container (33) having sides and an open top having a rim, the container being adapted to contain the pouch, and ii) a lid (35) attachable to the rim such that the lid is adapted to trap the ears of the pouch between the lid and the rim and to keep said end of the pouch taut between the ears when the lid is attached to the rim. The lid is also being adapted to allow a spout (41) to pierce the pouch at the taut portion.

Abstract: A method of partitioning a pre-selected phase of a sample of liquid having a plurality of phases of differing densities, a separation device and a tube containing the separation device. The sample of liquid is placed in a first chamber of a linear tube that is separated from a second chamber by a separation device. The separation device slidably engages the interior surface of the tube in an essentially fluid-tight manner and has an axial orifice on the longitudinal axis of the tube that is in fluid flow communication with a flow-restriction channel. The phases are ordered concentrically by rotating the tube around its longitudinal axis e.g. in an axial centrifuge. The volume of the first chamber is reduced by movement of the separation device within the tube, that phase of the liquid located axially within the first chamber flowing into the axial orifice and passing through the flow-restriction channel into the second chamber.

Abstract: A heat sealing element and related self aligning support jaw, for sealing at least two layers of thermoplastic film is disclosed. It may be used with a vertical form, fill and seal machine for packaging flowable materials, e.g. chocolate fudge, sundae topping, in pouches. The heat sealing element has a spade end which extends from the electrical connection essentially to the edge of the thermoplastic film.

Abstract: The process of this invention for making strong, discontinuous fibers from a polyolefin includes feeding a solution of polyolefin dissolved in an organic solvent at a pressure that is at least autogenous pressure to a spinneret. Plexifilamentary film-fibril strands are formed by flash spinning, by passing said solution through the exit of the spinneret and into a tunnel at a lower pressure and temperature than the solution, the temperature being greater than the boiling point of the organic solvent. At or subsequent to the exit from the spinneret but inside the tunnel, the strands and solvent are contacted in the tunnel with an inert fluid that has a liquid and a vapor phase, the amount of inert fluid being such that the ratio of the total volumetric flow rate of solvent vapor plus inert fluid vapor to the mass flow rate of the polymer is greater than 4.5 m.sup.3 /kg in the tunnel. The temperature of the inert fluid in the tunnel is 2.degree.-40.degree. C. lower than the melting point of the polymer.

Abstract: A partially crystalline copolyamide formed from an aromatic carboxylic acid that is terephthalic acid or a mixture of terephthalic acid and isophthalic acid containing less than 40% of isophthalic acid, and an aliphatic diamine that is a mixture of hexamethylene diamine and 2-methyl pentamethylene diamine. The aliphatic diamine is at least 40%, molar basis, of hexamethylene diamine and the amount of isophthalic acid plus 2-methyl pentamethylene diamine is in the range of 15-35%, molar basis, of the total amount of aromatic carboxylic acid and aliphatic diamine. The copolyamides have a melting point of 280.degree.-330.degree. C. The copolyamide preferably has a heat of fusion of greater than 17 J/g. The copolyamide may be moulded into articles, spun into fibres or formed into films, and used in a wide variety of end-uses especially where high temperature properties are required.