Abstract: Disclosed is a process to produce a purified vapor comprising dialkyl-furan-2,5-dicarboxylate (DAFD). Furan-2,5-dicarboxylic acid (FDCA) and an alcohol in an esterification zone to generate a crude diester stream containing dialkyl furan dicarboxylate (DAFD), unreacted alcohol, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), and alkyl furan-2-carboxylate (AFC). The esterification zone comprises at least one reactor that has been previously used in an DMT process.

Abstract: The present invention relates to a method for the manufacture of cyclododecasulfur, a cyclic sulfur allotrope wherein the number of sulfur (S) atoms in the allotrope's homocyclic ring is 12. The method includes reacting a metallasulfur derivative with an oxidizing agent in a reaction zone to form a cyclododecasulfur-containing reaction mixture.

Abstract: Disclosed is a process to produce a purified vapor comprising dialkyl-furan-2,5-dicarboxylate (DAFD). Furan-2,5-dicarboxylic acid (FDCA) and an alcohol in an esterification zone to generate a crude diester stream containing dialkyl furan dicarboxylate (DAFD), unreacted alcohol, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), and alkyl furan-2-carboxylate (AFC). The esterification zone comprises at least one reactor that has been previously used in an DMT process.

Abstract: The present application discloses low cost plastisols with high filler loading and gel points below 77° C.

Abstract: Filament comprising a polymeric material that includes a diacid component comprising from about 40 to 60 mole % of units derived from terephthalic acid and from about 40 to 60 mole % of units derived from a diacid chosen from isophthalic acid, a cyclohexanedicarboxylic acid, a naphthalenedicarboxylic acid, a stilbenedicarboxylic acid, or a combination thereof; a glycol component comprising at least 75 mole % of units derived from cyclohexanedimethanol; wherein the polymeric material has an inherent viscosity loss of 3% or less after being extruded; and method of using this filament in production of different articles by 3D printing are disclosed.

Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.

Abstract: A cellulose ester composition is provided comprising at least one cellulose ester and at least one ethylene vinyl acetate copolymer and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided.

Abstract: Provided is a resin composition containing: cellulose acylate (A); at least a polymer (B) selected from a group consisting of: a polymer (b1) having a core-shell structure including a core layer containing a butadiene polymer, and a shell layer located on an surface of the core layer and containing a polymer selected from a styrene polymer and an acrylonitrile-styrene polymer; a styrene-ethylene-butadiene-styrene copolymer (b2); polyurethane (b3); and aromatic polyester (b4); and a plasticizer (C). A resin molded article obtained by molding the resin composition satisfies at least one of the following conditions (1) and (2): (1) a heat distortion temperature measured in accordance with an ASTM D648-07 B method is 95° C. or less; and (2) a heat distortion temperature measured in accordance with an ISO 75-2 A method (2013) is 80° C. or less.

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Abstract: Vulcanizable elastomeric formulation are disclosed. The formulations comprise at least one elastomer; a vulcanizing agent comprising cyclododecasulfur; and a prevulcanization inhibitor, present in an amount, for example, from about 0.01 phr to about 10 phr. The formulations, when vulcanized, provide articles that exhibit improved durability.

Abstract: Disclosed are polymeric compositions that exhibit improved weathering and ultraviolet radiation resistance. The compositions comprise a polymer, at least one ultra-violet light (UV) absorber, at least one primary antioxidant, at least one secondary antioxidant, at least one hindered amine light stabilizer and at least one chain extending agent. In some embodiments the invention comprises a polyester; at least one triazine UV absorber; at least one hindered phenol primary antioxidant; at least one phosphite secondary antioxidant; at least one hindered amine light stabilizer and at least one styrene-acrylate copolymer.

Abstract: This invention pertains to polyester compositions and their use in low shear manufacturing processes. More particularly, this invention pertains to polyester compositions that have a sharp transition from solid to flowable melt, a steep viscosity curve with temperature resulting in minimal heating above the melting temperature for good flow and having minimal cooling requirements. The polyesters have particular utility in low shear polymer melt processes such as rotational molding, powder slush molding, powder coating and 3D printing processes. The polyesters are comprised of at least one dicarboxylic acid, at least one dihydroxy alcohol, at least one polyol, and optionally a multi-functionalized acid, alcohol or anhydride branching agent. The polyesters have a puddling curve slope of ?2 to ?20.

Abstract: This invention pertains to polyester compositions. More particularly, this invention pertains to polyester compositions that have particular utility as component of medical adhesive tapes, topical and transdermal drug delivery patches and cosmetic patches. The polyester is comprised of a diacid selected from the group consisting of a cyclohexane dicarboxylic acid, a dimethylcyclohexane dicarboxylic acid, and combinations thereof and polytetramethylene ether glycol and optionally a branching agent.

Abstract: The present invention is generally related to various types of compositions that comprise a polyindane resin. In particular, the polyindane resins may be utilized in various polymer-based and elastomer-based formulations in order to enhance several properties and characteristics of those formulations. More specifically, elastomeric compositions are provided that comprise at least one polyindane resin, which may be used to replace or enhance the functionality of existing hydrocarbon resins used in elastomeric formulations. The elastomeric compositions may be used to produce various tire components.

Abstract: A recycle content polystyrene and method of making a recycle content polystyrene wherein the recycle content is derived directly or indirectly from the cracking of recycle content pyrolysis oil and/or gas. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.

Abstract: Disclosed are a variety of amphoteric ester sulfonates, including 3-(N, N-dimethyl-cocoylpropylammonio-1-yl)-2-hydroxypropanesulfonate. These amphoteric ester sulfonates can be advantageously prepared in high yield and purity by a two-step chemoenzymatic process, and have excellent surfactant properties.

Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). In some cases, the pyrolysis and cracking may be carried out in different sections of the same furnace, or in different furnaces in the same cracker facility. Pyrolysis conducted in a furnace may or may not require retrofitting a furnace previously used to crack alkanes to form olefins.

Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, are provided that integrate a cracker unit with one or more other processing units. For example, in some cases, a fluidized catalytic cracking unit may be used to crack recycle content pyrolysis oil and the effluent from the FCC may be further processed in a conventional cracker unit, including its downstream separation zone, to provide recycle content hydrocarbon product stream. In other cases, a pyrolysis unit and cracking unit may be co-located and may share at least one utility, service group, boundary, conduit, energy exchange zone, and/or geographical area.

Abstract: A pyrolysis method and system are provided that enhances the production of alkanes and minimizes the production of aromatics in the resulting pyrolysis oil. More particularly, the disclosed pyrolysis method and system may be configured to enhance the production of alkanes due to the use of certain pyrolysis catalysts and more intense pyrolysis conditions.