Abstract: Ligands for use with catalyst compositions used in hydroformylation reactions are described herein. The ligands are used with various solvents and achieve an increase in isoselectivity with an increase in temperature.

Abstract: Disclosed is a plasticized cellulose ester composition. The plasticized cellulose ester composition of the present invention includes at least one cellulose ester; at least one plasticizer; and an effective amount of a melt- strength enhancing additive. Related calendered articles and flooring articles are also described.

Abstract: Pre-ground plastics of small particle size not more than 2 mm are co-fed into a solid fossil fuel fed entrained flow partial oxidation gasifier. A syngas composition can be made by charging an oxidant and a feedstock composition comprising recycle plastics and a solid fossil fuel to a gasification zone within a gasifier; gasifying the feedstock composition together with the oxidant in said gasification zone to produce said syngas composition; and discharging at least a portion of said syngas composition from said gasifier; wherein the recycled plastics are added to a feed point comprising a solid fossil fuel belt feeding a grinder after the solid fossil fuel is loaded on the belt, a solid fossil fuel belt feeding a grinder before the solid fossil fuel is loaded onto the belt, or a solid fossil fuel slurry storage tank containing a slurry of said solid fossil fuel ground to a size as the size fed to the gasification zone.

Abstract: Disclosed is a multilayer resilient flooring article, The multilayer resilient flooring article of the present invention includes a core layer comprising a first plasticized cellulose ester-based composition and a top layer comprising a second plasticized cellulose ester-based composition, wherein the first plasticized cellulose ester-based composition comprises a combustion suppression system. Compositions useful for example in the manufacture of multilayer resilient flooring articles are also described.

Abstract: The invention provides shrinkable films comprised of polyesters comprising certain combinations of glycols and diacids in particular proportions. These polyesters afford certain advantageous properties in the resulting shrinkable films, and thus are suitable as drop-in replacements for commercially available shrink films made using poly(vinyl chloride).

Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, are provided that integrate a cracker unit with one or more other processing units. For example, in some cases, a fluidized catalytic cracking unit may be used to crack recycle content pyrolysis oil and the effluent from the FCC may be further processed in a conventional cracker unit, including its downstream separation zone, to provide recycle content hydrocarbon product stream. In other cases, a pyrolysis unit and cracking unit may be co-located and may share at least one utility, service group, boundary, conduit, energy exchange zone, and/or geographical area.

Abstract: A process for preparing 5-(alkoxycarbonyl)furan-2-carboxylic acids (ACFC) by oxidizing various furcates in the presence of a catalyst containing cobalt, manganese, and bromine, and a solvent while simultaneously removing water vapor from the reaction chamber. The process can produce ACFC with high purity and low color, and in high yield.

Abstract: Copolyesters made from the direct esterification of terephthalic acid with diols including ethylene glycol, but which contain low diethylene glycol (DEG) content, and processes for making the copolyesters. The copolyesters are characterized by comprising 1.0 wt % or less of DEG without requiring the use of DEG-suppressing additives. The processes are characterized by features including operating at lower pressures and lower EG:TPA feed mole ratios in the first reaction zone, while simultaneously at higher temperatures than typical operation in order to lower incorporation of DEG into the final polymer.

Abstract: The present application discloses a method of reducing acid and ester degradation products during calendering of cellulose ester containing plasticiser using certain additives such as primary antioxidants and metal alkanoate. The compositions comprising the additives exhibit significant reductions in acids and ester degradation products as compared to compositions not comprising the additives.

Abstract: A build material for additive manufacturing applications is disclosed. The build material includes a build composition in powder form. The build composition includes a semi-crystalline polymer having a glass transition temperature of at least 60° C. as measured by DSC and a minimum crystallization half-time of greater than 100 minutes as measured by SALS. A semi-crystalline polymer useful in additive manufacturing applications, an additive manufacturing method for producing a three-dimensional object and an additive-manufactured polymer article are also described.

Abstract: A water dispersible sulfopolyester is provided wherein the sulfopolyester comprises: (a) residues of one or more dicarboxylic acids; (b) at least 10 mole percent of residues of at least one sulfomonomer; and (c) residues of two or more diols, wherein said diols comprise ethylene glycol and diethylene glycol, and wherein the sulfopolyester exhibits a glass transition temperature of at least 58° C., wherein the sulfopolyester comprises a diethylene glycol to ethylene glycol molar ratio of less than 0.65, wherein the sulfopolyester contains substantially equimolar proportions of acid moiety repeating units (100 mole percent) to hydroxy moiety repeating units (100 mole percent), and wherein all stated mole percentages are based on the total of all acid and hydroxy moiety repeating units being equal to 200 mole percent. Woven and nonwoven articles comprising the water dispersible sulfopolyester are also provided.

Abstract: A water dispersible sulfopolyester is provided wherein the sulfopolyester comprises: (a) residues of one or more dicarboxylic acids; (b) at least 4 mole percent and less than 8.5 mole percent of residues of at least one sulfomonomer; and (c) residues of one or more diols, wherein the sulfopolyester comprises a carboxylate ends to acid ends ratio of at least 0.6, wherein the sulfopolyester contains substantially equimolar proportions of acid moiety repeating units (100 mole percent) to hydroxy moiety repeating units (100 mole percent), and wherein all stated mole percentages are based on the total of all acid and hydroxy moiety repeating units being equal to 200 mole percent. Processes for producing the sulfopolyester are also provided as well as articles comprising the sulfopolyester.

Abstract: Transparent, conductive barrier films are disclosed that include a polymeric substrate; an optional planarization layer, atop the polymeric substrate, and at least one dyad, atop the optional planarization layer if present, or atop the polymeric substrate, that comprises an inorganic oxide layer, and a polymethylglutarimide layer. The films of the invention are further provided with a conductive layer, atop the at least one dyad.

Abstract: The present application discloses interlayers comprising half waveplate (“HWP”) films and head-up display systems incorporating the interlayers. The interlayers and head-up display systems are optimized so that the optical axis has an angle phi (?) relative to the axis formed from the p-polarization direction of a display light projected onto the plane of the HWP film. The optimized ? depends on the optical properties of the films.

Abstract: The present application discloses novel polyesteramides comprising cycloalkyl diols and/or cycloalkyl dialkanols with tunable properties based on the monomers and monomerratios used to prepare the polyesteramides and varying the reaction conditions. The present application also discloses compositions and articles.

Abstract: The invention provides a plasticizer for use in plastic materials such as polyvinyl chloride. The plasticizer is a blend of di-(2-ethylhexyl) terephthalate (DOTP) and 2-ethylhexyl methyl terephthalate (MOTP). The blend of di-(2-ethylhexyl) terephthalate and 2-ethylhexyl methyl terephthalate provides a non-ortho-phthalate alternative to plasticizers such as diisononyl phthalate and also produces good fusion temperature, gelation point, plastisol viscosity, efficiency, plasticizer compatibility, and drying time performance.

Abstract: A water dispersible sulfopolyester is provided wherein the sulfopolyester comprises: (a) residues of one or more dicarboxylic acids; (b) at least 10 mole percent of residues of at least one sulfomonomer; and (c) residues of two or more diols, wherein the diols comprise 1,4-cyclohexanedimethanol and diethylene glycol, wherein the sulfopolyester exhibits a glass transition temperature of at least 57° C., wherein the sulfopolyester contains substantially equimolar proportions of acid moiety repeating units (100 mole percent) to hydroxy moiety repeating units (100 mole percent), and wherein all stated mole percentages are based on the total of all acid and hydroxy moiety repeating units being equal to 200 mole percent. Woven articles and nonwoven articles are also provided.

Abstract: Processes are disclosed for preparing at least one aldehyde under hydroformylation temperature and pressure conditions, comprising contacting at least one olefin with hydrogen and carbon monoxide in the presence of at least one hydrocarbon solvent or fluorinated solvent and a transition metal-based catalyst composition comprising a phospholane-phosphite ligand.

Abstract: This invention pertains to a curable composition comprising a first component having ?-ketoester and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of ?-ketoester, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Abstract: Stretchable films are disclosed, that include a coating layer comprising the reaction product of: an oligomeric polyester resin wherein the oligomeric polyester resin has a glass transition temperature (Tg) of ?15 to 10° C., a hydroxyl equivalent weight of 350 to 500 mgKOH/g; and an aliphatic isocyanate, isocyanurate, allophanate, or biuret. The coating of these films has a fingerprint removal haze under 2, a percent haze removal over 70 percent, an initial scratch/mar over 40% gloss retention, and a recovered scratch/mar over 85% gloss retention as measured by both % gloss retention after 24 hours and % gloss retention at 60° C., as defined herein.