Abstract: A fluid fire extinguishing agent shell for throwing is disclosed, comprising a fluid fire extinguishing agent sealed in a thin-walled resin container having such a size that one can throw, which is breakable by a shock, said fluid fire extinguishing agent being a mixture comprising from about 47% to approximately the saturation point of ammonium chloride , from about 4% to about 8% of sodium bicarbonate, from about 25% to about 35% of potassium carbonate, from about 8% to about 14% of ammonium secondary phosphate, and from about 2% to about 6% of sodium tungstate all in terms of by weight, dissolved in a suitable amount of water, is a simple fire extinguishing appliance that anyone can easily use at the time of occurrence of a fire and which is effective even after the storage for a long period of time.