Abstract: A method for high resolution NMR (=nuclear magnetic resonance) measurements using the application of excitation pulses and the acquisition of data points, whereby a dwell time ?t separates the acquisition of two consecutive data points, which is characterized in that one or more tickling rf (=radio frequency) pulses of duration ?p are applied within each dwell time ?t, and that the average rf field amplitude of each of the tickling rf pulses approximately fulfills the condition ?1=?1?p/?t=?J wherein J is the scalar J-coupling constant and ?1=?B1 with ? being the gyromagnetic ratio and B1 being the strength of the magnetic component of each tickling rf pulse. This method is effective in decoupling homonuclear couplings.