Abstract: The method of preparing the polycarbonate ether polyol or high molecular weight polyether carbonate using controlled addition of materials during polymerisation includes the steps of: mixing catalyst of formula(I), double metal cyanide (DMC) catalyst and optionally carbon dioxide and/or solvent with epoxide and optionally starter compound and/or carbon dioxide; or mixing DMC catalyst and optionally starter compound, carbon dioxide and/or solvent with epoxide and optionally carbon dioxide and/or solvent; or mixing epoxide, catalyst of formula(I), starter compound and carbon dioxide and optionally solvent; or mixing catalyst of formula (I), DMC catalyst and optionally starter compound, epoxide, carbon dioxide and/or solvent to form in each case a mixture (?); and adding one or more of starter compound, epoxide, carbon dioxide, catalyst of formula(I), DMC catalyst and/or solvent to mixture (?) to form mixture (?) comprising starter compound, epoxide, carbon dioxide, catalyst of formula(I), DMC catalyst and optio
Type:
Grant
Filed:
October 24, 2018
Date of Patent:
April 23, 2024
Assignee:
Econic Technologies LTD.
Inventors:
Michael Kember, James Leeland, Rakibul Kabir, Emmalina Hollis
Abstract: A process for preparing a tetra-substituted aminobiphenol macrocyclic ligand having the structure (I), including the step of treating a precursor compound having the structure (II) with a compound having the structure R6-L where L is a leaving group (hereafter compound (III)) in the presence of a base.
Type:
Grant
Filed:
April 20, 2021
Date of Patent:
February 27, 2024
Assignee:
Econic Technologies Ltd.
Inventors:
Michael Kember, Anthony Chartoire, Anthea Blackburn, Samuel Drane
Abstract: A method for quenching a polymerisation process is described. The reaction of carbon dioxide with an epoxide in the presence of a bimetallic metal complex catalyst to produce a polymer comprises the quenching step of deactivation of the catalyst by contacting the catalyst with an acid effective to deactivate the catalyst. The deactivated catalyst may be removed from the polymer product by contacting the catalyst and polymer product with a solid phase and/or by precipitation; and the catalyst may also be optionally reactivated by contacting the deactivated catalyst with an anion. The acid may contain an anion effective to initiate the polymerisation process and effective to deactivate the catalyst and the molar ratio of acid to catalyst in the deactivation step may be less than or equal to 20:1 of the acid to catalyst mole ratio for the reaction.
Type:
Grant
Filed:
October 24, 2018
Date of Patent:
March 28, 2023
Assignee:
Econic Technologies LTD
Inventors:
Michael Kember, David Muir, Anthony Chartoire, James Leeland, Fernando Valera, Andrew Carruthers, Rakibul Kabir
Abstract: The present invention relates to a method for preparing a polycarbonate ether polyol, by reacting an epoxide and carbon dioxide in the presence of a catalyst of formula (I), a double metal cyanide (DMC) catalyst and a starter compound.
Type:
Application
Filed:
August 6, 2020
Publication date:
November 26, 2020
Applicant:
Econic Technologies Ltd.
Inventors:
Michael Kember, Rakibul Kabir, Charlotte Katherine Williams
Abstract: The present invention relates to a method for preparing a polycarbonate ether polyol, by reacting an epoxide and carbon dioxide in the presence of a catalyst of formula (I), a double metal cyanide (DMC) catalyst and a starter compound.
Type:
Grant
Filed:
November 10, 2017
Date of Patent:
September 15, 2020
Assignee:
Econic Technologies Ltd.
Inventors:
Michael Kember, Rakibul Kabir, Charlotte Katherine Williams
Abstract: The present invention relates to a method for preparing a polycarbonate ether polyol, by reacting an epoxide and carbon dioxide in the presence of a catalyst of formula (I), a double metal cyanide (DMC) catalyst and a starter compound.
Type:
Application
Filed:
November 10, 2017
Publication date:
May 31, 2018
Applicant:
Econic Technologies Ltd.
Inventors:
Michael Kember, Rakibul Kabir, Charlotte Katherine Williams