Patents Assigned to ECP-Enichem Polymeres France S.A.
  • Patent number: 5591410
    Abstract: (I) The (co)polymerisation of ethylene is carried out in at least one reaction zone (R) under high pressure, at 150.degree.-320.degree. C.; (II) the reaction product is routed into a zone (S), under an intermediate pressure P, for separation of the (co)polymer, in the molten state, from the unreacted (co)monomer(s), or the reaction product is routed into a first separation zone (S1), under an intermediate pressure (P1); the (co)polymer issuing from (S1) is then routed into a second separation zone (S2), under a pressure P2<P1; (III) the (co)polymer is routed into a zone (SF), under low pressure, for final separation of the (co)polymer from the residual gases. Let-down zones (D), (D1) and (D2) are provided along the path of the (co)polymer between the zones (S) and (SF), (S1) and (S2), and (S2) and (SF) respectively, the grafting monomer or monomers being introduced on-line, in the path of the (co)polymer, at at least one point located at the level of the zone (D) or at at least one zone (D1, D2).
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 7, 1997
    Assignee: ECP-Enichem Polymeres France S.A.
    Inventors: Joel Audureau, Hacene Mehalla, Thierry Pellerin
  • Patent number: 5585447
    Abstract: This catalyst has the general formula VX.sub.3, mAIX.sub.3, nZ, wherein X is a halogen atom, Z is at least one at least partially halogenated, branched or unbranched, saturated hydrocarbon, m is between 0.1 and 10, and n is between 1 and 300. To prepare it, a vanadium halide VX.sub.2 and/or VX.sub.3 is coground with an aluminum halide AlX.sub.3, and then at least one halogenated hydrocarbon Z is added to the mixture obtained in proportions corresponding to the chosen values of m and n. The invention also relates to the (co)polymerization of alpha-olefins at 20.degree.-350.degree. C. in the presence of a catalyst system comprising at least one catalyst as defined above and at least one organometallic activator.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: December 17, 1996
    Assignee: ECP-Enichem Polymeres France S.A.
    Inventors: Emmanuel Adisson, Karel Bujadoux, Michel Fontanille, Alain Deffieux
  • Patent number: 5583181
    Abstract: (I) The (co)polymerisation of ethylene is carried out in at least one reaction zone (R) under high pressure, at 150.degree.-320.degree. C.; (II) the reaction product is routed into a zone (S), under an intermediate pressure P, for separation of the (co)polymer, in the molten state, from the unreacted (co)monomer(s), or the reaction product is routed into a first separation zone (S1), under an intermediate pressure (P1); the (co)polymer issuing from (S1) is then routed into a second separation zone (S2), under a pressure P2<P1; (III) the (co)polymer is routed into a zone (SF), under low pressure, for final separation of the (co)polymer from the residual gases. Let-down zones (D), (D1) and (D2) are provided along the path of the (co)polymer between the zones (S) and (SF), (S1) and (S2), and (S2) and (SF) respectively, the grafting monomer or monomers being introduced on-line, in the path of the (co)polymer, at at least one point located at the level of the zone (D) or at at least one zone (D1, D2).
    Type: Grant
    Filed: January 12, 1995
    Date of Patent: December 10, 1996
    Assignee: ECP-Enichem Polymeres France S.A.
    Inventors: Jo el Audureau, Hacene Mehalla, Thierry Pellerin
  • Patent number: 5334663
    Abstract: The compositions contain a) less than 90% and at least 2% by weight of at least one ethylene polymer (A), and optionally, at least one .alpha.-olefin having from 3 to 12 carbon atoms, said polymer containing at least 70% in moles of patterns derived from ethylene, and b) more than 10% and up to 98% by weight of at least one polymer (B) containing at least 85% in moles of patterns derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms and at the most 15% in moles of patterns derived from ethylene, and are characterized in that the polymer (A) is a modified polymer of which the measured limit viscosity is comprised between 1.3 and 100 times its limit viscosity calculated from the distribution of molecular masses. The compositions are obtained by a process consisting in providing a polymer of ethylene and, optionally, of at least one .alpha.-olefin having from 3 to 12 carbon atoms in the presence, on the one hand, of at least one initiator of free radicals in a quantity comprised between 0.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: August 2, 1994
    Assignee: ECP-Enichem Polymeres France S.A.
    Inventors: Joel Audureau, Vincent Crenna