Abstract: Natural or synthetic wax dissolved in the continuous organic phase of an water-in-oil emulsion retards evaporation of water from a dispersed aqueous phase. An in situ prepared equilibrium mixture of benzyl alcohol, formic acid and benzyl formate emulsified with oleic hydroxyethyl imidazoline or similar oil soluble emulsifying agent is thickened with hydroxypropyl cellulose or hydroxypropyl methylcellulose and contains 0.1 to 1.0% by weight paraffin wax with a melting point of 47.degree. to 65.degree. C. Wax dissolved in the organic phase retards evaporation of water, and formic acid or ammonia which are very volatile in comparison with benzyl alcohol forming the major component of the organic phase. A petroleum distillate is used to pre-wet a hydroxypropyl cellulose thickener and dissolve the wax.

Abstract: A process for the preparation of alkyl halodifluoroacetates comprises reacting a 1,1-difluorotetrahaloethane with an alcohol, e.g., ethanol or isopropanol, in the presence of oxygen and a chemical free-radical initiator, e.g., an azo compound.

Abstract: The invention relates to an impact additive of the core/shell type for thermoplastic polymers.This impact additive comprises a crosslinked elastomeric core based on n-alkyl acrylate and a shell made of poly(alkyl methacrylate) grafted onto the said core.

Abstract: Esters of formula:HS--X--COORin which X denotes a C.sub.1 -C.sub.4 alkylene radical and R a C.sub.1 -C.sub.18 alkyl radical, are prepared by reaction of a hydrosulphide with the corresponding halocarboxylic ester:Y--X--COORwhere Y denotes a chlorine or bromine atom. The reaction is performed under a hydrogen sulphide pressure of at least 10 bars absolute, and preferably in an anhydrous or substantially anhydrous alcoholic medium.

Abstract: Active Rhodium catalyst and impurities are separated from a hydroformylation process stream containing both active and inactive organo-rhodium catalyst by binding active catalyst and impurities to an acidic ion exchange resin containing an acidic group. The purified hydroformylation stream can be returned to the hydroformylation reactor. All or a portion of inactive rhodium can be reactivated before recycling purified hydroformylation process stream to the reactor. During regeneration of the resin, a neutral solvent is used first to remove impurities which are discarded, then an acidic solvent is used to remove active organic rhodium catalyst from the resin. Such active catalyst can be rehydrided and returned to the hydroformylation reactor. An ion exchange resin having at least one acid group disposed on a silica backbone and an active organo-rhodium complex from a hydroformylation process stream bound to the resin can be produced.

Abstract: The present invention comprises a polystannoxane catalyst, a curable composition containing the catalyst and a method of using the catalyst and curing the composition. The curable composition comprises:(i) a blocked isocyanate;(ii) a functional component containing reactive hydrogen;(iii) a polystannoxane catalyst for promoting the reaction of the blocked isocyanate with the functional component.A co-catalyst may also be employed based on Cu, Zn, Ni, Zr, Ce, Fe, Co, V, Sb and Bi and especially oxides, salts or chelates of said metals. The invention also relates to a method for curing a blocked isocyanate at a low reaction temperature which comprises combining the catalyst with the blocked isocyanate and functional component and heating to a temperature less than about 180.degree. C. to obtain a cured urethane.

Abstract: This process is characterized by the fact that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature that can be as low as 0.degree. C., in the presence of an initiation system including: at least one compound generating radicals, other than bromofluorene, and at least one catalyst consisting of a complex of palladium in the 0 oxidation state, denoted by the following formula (I): Pd(0)L.sup.1 L.sup.2 L.sup.3 L.sup.4 in which each of L.sup.1, L.sup.2, L.sup.3 and L.sup.4, which are identical or different, denotes a ligand which may be a chiral ligand, which is chosen from PRR'R", P(OR)(OR')(OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", where each of R, R' and R" independently denotes a C.sub.1 -C.sub.14 alkyl group, optionally substituted, or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined to one another by one or more divalent radicals.

Abstract: Preparation of storage stable, polybutadiene containing, unsaturated polyester resins by heating a mixture containing an unsaturated hydroxyl terminated polybutadiene resin, a saturated anhydride or dibasic acid, an unsaturated anhydride or dibasic acid, a polymerization inhibitor and, optionally, a saturated glycol, while removing water as it is formed, the molar ratio of the saturated anhydride or acid to the unsaturated anhydride or acid being at least equal to 2.

Abstract: The invention relates to reinforcing compositions for thermoplastic polymers which have improved anticaking and flow properties, which include an impact additive and a precipitated silica.These compositions are very particularly suitable for the reinforcement of PVC.

Abstract: The invention relates to binders for self-crosslinkable varnishes and paints comprising one or a number of hydroxylated and/or carboxylated fluorinated copolymers and one or a number of epoxidized and/or alkoxylated acrylic copolymers.

Abstract: Poly(monoperoxycarbonates) of the structure: ##STR1## where R, R.sup.1 and n are defined in the summary of the invention such as 1,1,1-tris(t-butylperoxycarbonyloxymethyl)ethane, intermediates for their preparation as well as processes for their preparation and use are disclosed. The monoperoxycarbonate compounds are useful in initiating the polymerization of ethylenically unsaturated monomers, particularly styrene, curing of unsaturated polyester resins, and in modifying the molecular weight of polymers such as by crosslinking or controlled chain degradation.

Abstract: Compounds of the formula?P!(ACH.sub.2 NH.sub.2).sub.xin which P denotes a partially hydrogenated 1,3-diene oligomer residue, x is practically equal to 2 and A denotes a divalent residue such as ##STR1## are obtained by selective hydrogenation of compounds of formula ?P.sub.1 !(ACN)x in which P.sub.1 denotes a 1,3-diene oligomer residue.

Abstract: The invention relates to a composition based on ethylene copolymers for manufacturing floor coverings and comprising: a) a copolymer having at least one epoxide functional group, b) a copolymer of ethylene and of at least one unsaturated monomer having functional groups which are reactive with the epoxide functional group of a), c) fillers, and optionally d) ethylene-vinyl acetate or ethylene-alkyl (meth)acrylate copolymers. The floor coverings obtained have an abrasion according to DIN 53516 of less than 300 mm.sup.3, a resistance to scratching which is greater than 150 g, and an oxygen index which is greater than 30.

Abstract: An improved process for removing phosphate from waste water comprising simultaneously injecting a coagulating agent upstream and downstream of a stage of biological oxidation in aerobic medium.

Abstract: Inexpensive paint stripper compositions containing neither chlorinated nor alkaline solvents and well adapted for removing paints such as glycerophtalic, alkyd-urethane or acrylic urethane paints on a variety of substrates, e.g. wood and metal substrates comprise (a) 1 to 99% by volume of an aprotic polar solvent chosen from the group comprising: dimethyl sulfoxide, dimethyl formamide, N-methylpyrrolidone, N-methylmorpholine, .gamma.-butyrolactone, acetonitrile and mixtures thereof; and (b) 99 to 1% by volume of an ether selected from the family of ethers having a flash point higher than 0.degree. C. a molar volume less than 160 and a molecule that includes one or several methoxy groups.

Abstract: This process for the manufacture of sec-butyl acrylate by reaction of acrylic acid and at least one butene in the presence of a macroporous cationic resin containing sulphonic acid groups is characterized in that the reaction is carried out using a molar ratio of the acrylic acid to the butene(s) used which is greater than 1, the crude reaction product comprising residual acrylic acid, dissolved butene isomers, the desired sec-butyl acrylate, octenes, 2-butanol and heavy addition products, and in that the desired sec-butyl acrylate is separated from the crude reaction product.

Abstract: For degreasing the surface of an object, applying thereto a composition containing at least 25% by weight of an amphiphilic compound of the formula A--B, wherein A is a lipophilic and hydrophobic radical and B is a hydrophilic radical, e.g., an alkyleneglycol ether oxide having a terminal group of at least 10 carbon atoms, then rinsing the surface with water.

Abstract: This invention relates to a plastic composite material which comprises:a thermoplastic plastic sheet and, bonded to one side thereof,a thermoplastic spun felt comprising a hot-melt adhesive, to a method of producing it and to its use.

Abstract: The present invention relates to the simultaneous manufacture of difluoromethane (F32) and 1,1,1,2-tetrafluoroethane (F134a) by pyrolysis of chlorodifluoromethane in the presence of hydrogen, working at a temperature above 500.degree. C. in the absence of any catalyst or metal surface. Depending on the operating conditions chosen, this process also makes it possible predominantly to manufacture either F134a or F32.

Abstract: To replace compositions based on CFC or CFHC in applications for cleaning solid surfaces (in particular defluxing), the invention proposes azeotropic or quasi-azeotropic compositions based on 1,1,1,2,2,4,4-heptafluorobutane and a C.sub.1 -C.sub.3 alcohol.