Patents Assigned to EMPA
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Publication number: 20180258232Abstract: The present invention relates to a method for manufacturing hydrophilic biopolymers, particularly hydrophilic cellulosic material, particularly cellulose nanofibers like micro- or nanofibrillated cellulose, as described in claim 1; to novel materials comprising hydrophilic biopolymers and to the use of such hydrophilic biopolymers.Type: ApplicationFiled: December 5, 2014Publication date: September 13, 2018Applicant: EMPA Eidgenossische Materialprufungs- und ForschungsanstaltInventors: Sébastien JOSSET, Philippe TINGAUT, Tanja ZIMMERMANN
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Patent number: 10072212Abstract: The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R1 and R2 are independently hydrogen, C1-C6 alkyl, —P(O)(OR3)2, —P(O)OR3R4, or —P(O)R32, wherein R3 and R4 are independently C1-C4 alkyl, C6-C12 aryl, C7-C15 aralkyl or C7-C15 alkaryl; or R1 and R2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C1-C4 alkylene, C6 arylene, C7-C15 aralkylene, C7-C15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C1-C4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C1-C4 alkylene, C6 arylene, C7-C15 aralkylene or C7-C15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C1-C4 alkylene; t is an integerType: GrantFiled: March 16, 2015Date of Patent: September 11, 2018Assignee: EMPA Eidgenossische Materialprufungs-Und ForschungsanstaltInventors: Timea Stelzig, Lea Bommer, Sabyasachi Gaan, Aleksandra Buczko, Rudolf Hufenus, Giuseppino Fortunato, Benno Wüst, Pierluigi Barbadoro
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Patent number: 10040720Abstract: In order to produce a high performance thermally insulating rendering, a dry blend is provided that consists essentially of: —60 to 90 Vol.-% of a hydrophobized granular silica aerogel; —0.5 to 30 Vol.-% of a purely mineral binder; —0.2 to 20 Vol.-% of an open-porous water-insoluble or slowly water soluble additive having an accessible pore volume from 10 to 90 Vol.-%; —up to 5 Vol.-% reinforcing fibers; and—up to 5 Vol.-% of processing additives. After mixing the dry blend with water, the slurry thus formed can be applied to a surface or shaped to a self-supporting body using an overpressure without adversely affecting the thermal insulation properties.Type: GrantFiled: December 10, 2013Date of Patent: August 7, 2018Assignees: EMPA Eidgenössische Materialprüfungs-Und Forschungsanstalt, FixIt AGInventors: Thomas Stahl, Samuel Brunner, Mark Zimmermann, Matthias Koebel
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Patent number: 9975777Abstract: The present invention relates to a segmented graphene nanoribbon, comprising at least two different graphene segments covalently linked to each other, each graphene segment having a monodisperse segment width, wherein the segment width of at least one of said graphene segments is 4 nm or less and to a method for preparing it by polymerizing at least one polycyclic aromatic monomer compound and/or at least one oligo phenylene aromatic hydrocarbon monomer compound to form at least one polymer and by at least partially cyclodehydrogenating the one or more polymer.Type: GrantFiled: November 13, 2012Date of Patent: May 22, 2018Assignees: BASF SE, EMPA MATERIALS SCIENCE AND TECHNOLOGYInventors: Roman Fasel, Pascal Ruffieux, Klaus Muellen, Stephan Blankenburg, Jinming Cai, Xinliang Feng, Carlo Pignedoli, Daniele Passerone
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Publication number: 20180087224Abstract: An additive for a bituminous binder respectively a bituminous composite material, able to reduce bituminous binder respectively bituminous composite material viscosity when an alternating magnetic field is applied, in particular for healing pavement cracks and in-depth micro-cracks in asphalt, wherein the additive comprises an amount of magnetic iron oxide particles should be improved, in order to reach bituminous composite material respectively a bituminous binder which can be melted in a faster and simplified way, in particular usable for crack healing of asphalt structures on site. This is reached by forming the additive comprising at least a part of magnetic iron oxide nanoparticles with average sizes between 1 nm and 300 nm coated with a fatty acid.Type: ApplicationFiled: April 18, 2016Publication date: March 29, 2018Applicants: EMPA - Eidgenössische Materialprüfungs- und Forschungsanstalt, ETH ZürichInventors: Etienne JEOFFROY, Manfred PARTL, André STUDART
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Patent number: 9914240Abstract: The invention relates to a mineralized wood material comprising at least one metal salt MA in the lumina of the mineralized wood material, in particular in the lumina and the cell walls of the mineralized wood material and methods for providing said mineralized wood material.Type: GrantFiled: April 17, 2015Date of Patent: March 13, 2018Assignees: ETH ZURICH, SWISS FEDERAL AL LABORATORIES FOR MATERIALS SCIENCE AND TECHNOLOGY (EMPA)Inventors: Ingo Burgert, Munish Chanana, Vivian Merk
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Publication number: 20180043303Abstract: A porous adsorbent structure that is capable of a reversible adsorption and desorption cycle for capturing CO2 from a gas mixture comprises a support matrix formed by a web of surface modified cellulose nanofibers. The support matrix has a porosity of at least 20%. The surface modified cellulose nanofibers consist of cellulose nanofibers having a diameter of about 4 nm to about 1000 nm and a length of 100 nm to 1 mm that are covered with a coupling agent being covalently bound to the surface thereof. The coupling agent comprises at least one monoalkyldialkoxyaminosilane.Type: ApplicationFiled: October 13, 2017Publication date: February 15, 2018Applicant: EMPA Eidgenossische Materialprufungs-Und ForschungsanstaltInventors: Christoph Gebald, Tanja Zimmermann, Philippe Tingaut
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Patent number: 9869015Abstract: A hard material layer system with a multilayer structure, comprising alternating layers A and B, with A layers having the composition MeApAOnANmA in atomic percent and B layers having the composition MeBpBOnBNmB in atomic percent, where the thermal conductivity of the A layers is greater than the thermal conductivity of the B layers. MeA and MeB each comprise at least one metal of the group Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al, pA indicates the atomic percentage of MeA and pB indicates the atomic percentage of MeB and the following is true: PA=PB, nA indicates the oxygen concentration in the A layers in atomic percent and nB indicates the oxygen concentration in the B layers in atomic percent and the following is true: nA<nB, and mA indicates the nitrogen concentration in the A layers in atomic percent and mB indicates the nitrogen concentration in the B layers in atomic percent and the following is true: pA/(nA+mA)=pB/(nB+mB).Type: GrantFiled: March 26, 2014Date of Patent: January 16, 2018Assignees: Oerlikon Surface Solutions AG, Pfäffikon, ETH ZÜRICH, EMPAInventors: Matthias Lukas Sobiech, Sebastian Stein, Paul Heinrich Böttger, Valery Shklover, Jörg Patscheider
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Publication number: 20180001576Abstract: The invention relates to a method for producing an aerogel material with a porosity of at least 0.55 and an average pore size of 10 nm to 500 nm, having the following steps: a) preparing and optionally activating a sol; b) filling the sol into a casting mold (10); c) gelling the sol, whereby a gel is produced, and subsequently aging the gel; at least one of the following steps d) and e), d) substituting the pore liquid with a solvent; e) chemically modifying the aged and optionally solvent-substituted gel (6) using a reaction agent; followed by f) drying the gel, whereby the aerogel material is formed. The casting mold used in step b) is provided with a plurality of channel-forming elements (2) which are designed such that the sol filled into the casting mold lies overall at a maximum distance X from a channel-forming element over a specified minimum length L defined in the channel direction of the elements, with the proviso that X<15 mm and L/X>3.Type: ApplicationFiled: February 4, 2016Publication date: January 4, 2018Applicant: EMPA EIDGENOSSISCHE MATERIALPRUFUNGS- UND FORSCHUNGSANSTALTInventors: MATTHIAS KOEBEL, LUKAS HUBER
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Patent number: 9837565Abstract: A method (200) and deposition zone apparatus (300) for fabricating thin-film optoelectronic devices (100), the method comprising: providing a potassium-nondiffusing substrate (110), forming a back-contact layer (120); forming at least one absorber layer (130) made of an ABC chalcogenide material, adding at least two different alkali metals, and forming at least one front-contact layer (150) wherein one of said at least two different alkali metals is potassium and where, following forming said front-contact layer, in the interval of layers (470) from back-contact layer (120), exclusive, to front-contact layer (150), inclusive, the comprised amounts resulting from adding at least two different alkali metals are, for potassium, in the range of 500 to 10000 ppm and, for the other of said at least two different alkali metals, in the range of 5 to 2000 ppm and at most ½ and at least 1/2000 of the comprised amount of potassium.Type: GrantFiled: December 16, 2013Date of Patent: December 5, 2017Assignees: FLISON AG, EMPAInventors: Adrian Chirila, Stephan Buecheler, Fabian Pianezzi, Patrick Reinhard, Ayodhya Nath Tiwari
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Publication number: 20170314277Abstract: The method includes a tension element, for example in the form of flat steel, that is placed on the structure or structural part and can be guided around a corner. The flat steel can also wrap as a band around the structure, in which the two ends of the flat steel are either connected to one another or are separately connected to the structure by the end anchors or intersect to produce a clamping connection. The flat steel contracts as a result of a subsequent active and controlled input of heat using a heating element and generates a permanent tensile stress and, correspondingly, a permanent prestress on the structure.Type: ApplicationFiled: December 14, 2015Publication date: November 2, 2017Applicants: RE-FER AG, EIDGENOESSISCHE MATERIALPRUEFUNGS-UND FORSCHUNGSANSTALT EMPAInventors: Masoud Motavalli, Benedikt Weber, Wookijn Lee, Rolf Broennimann, Christoph Czaderski, Christian Leinenbach
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Patent number: 9786807Abstract: A method to fabricate thin-film photovoltaic devices including a photovoltaic Cu(In,Ga)Se2 or equivalent ABC absorber layer, such as an ABC2 layer, deposited onto a back-contact layer characterized in that the method includes at least five deposition steps, during which the pair of third and fourth steps are sequentially repeatable, in the presence of at least one C element over one or more steps. In the first step at least one B element is deposited, followed in the second by deposition of A and B elements at a deposition rate ratio Ar/Br, in the third at a ratio Ar/Br lower than the previous, in the fourth at a ratio Ar/Br higher than the previous, and in the fifth depositing only B elements to achieve a final ratio A/B of total deposited elements.Type: GrantFiled: April 17, 2012Date of Patent: October 10, 2017Assignees: EMPA, FLISOM AGInventors: Adrian Chirila, Ayodhya Nath Tiwari, Patrick Bloesch, Shiro Nishiwaki, David Bremaud
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Publication number: 20170267816Abstract: The present invention relates to water-soluble modified lignins preparable by enzymatic reaction of at least one water-insoluble lignin with at least one organic compound which possesses at least one group selected from primary or secondary amino group, hydroxyl group and phenyl group and has an average molecular weight in the range from 75 to 2500 g/mol. The water-soluble modified lignins are preparable under mild conditions in a simple process. They can be used as dispersants for mineral binder compositions, where they act as plasticizers and in so doing prolong the setting time to much less of an extent than the water-insoluble lignins used in their preparation.Type: ApplicationFiled: March 15, 2017Publication date: September 21, 2017Applicants: SIKA TECHNOLOGY AG, EMPAInventors: Irene SCHOBER, Michael RICHTER, Tobias HECK, Dagmara JANKOWSKA
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Patent number: 9758968Abstract: The invention relates to a method according to which a profile consisting of a shape-memory alloy is placed into concrete, or a concrete to be reinforced is roughened on the outside, then profiles (2) consisting of a shape-memory alloy are fastened to the roughened outside (9) of the structure (6) and a cementitious matrix is applied to the roughened outside (9) to cover the profiles (2). After the cementitious matrix has set, said profiles (2) produce a contraction force and thus a tension as a result of the input of heat. The mortar covering layer (16) thereby acts as a reinforcement layer owing to the interlocking of the mortar covering layer (16) with the roughened outside (9) of the structure (6). The profiles (2) run in an outer mortar as a reinforcement layer (16) of the outside of a structure along the outside of the structure inside the mortar or reinforcement layer (16).Type: GrantFiled: March 17, 2014Date of Patent: September 12, 2017Assignees: re-Fer AG, EMPAInventors: Christian Leinenbach, Masoud Motavalli, Benedikt Weber, Wookjin Lee, Rolf Brönnimann, Christoph Czaderski
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Publication number: 20170248125Abstract: A flying apparatus is provided that comprises a airfoil (1) with a streamlined profile for generating an aerodynamic lift force vector (L) acting on the flying apparatus when being exposed to an apparent air flow. The flying apparatus also comprises at least three drive units (4, 42; 5, 51; 6, 61) being adapted to generate a resulting thrust force vector acting on the flying apparatus, the thrust force vector being alignable essentially in parallel with the aerodynamic lift force vector (L). For controlling the aerodynamic pitch of the flying apparatus, the flying apparatus comprises at least one control surface (31, 11). Furthermore, the flying apparatus has an aerodynamic neutral point (NP) that lies, along the longitudinal centre axis (10) and in the direction from the leading edge (17) to the trailing edge (18) of the airfoil (1), behind the centre of gravity (CG) of the flying apparatus.Type: ApplicationFiled: October 13, 2015Publication date: August 31, 2017Applicants: TwingTec AG, EMPA Eidg. Materialprüfungsund ForschungsanstaltInventors: Rolf LUCHSINGER, Flavio GOHL
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Patent number: 9676755Abstract: The present invention relates to a graphene nanoribbon, comprising a repeating unit which comprises at least one modification, wherein the modification is selected from a heteroatomic substitution, a vacancy, a sp3 hybridization, a Stone-Wales defect, an inverse Stone-Wales defect, a hexagonal sp2 hybridized carbon network ring size modification, and any combination thereof.Type: GrantFiled: May 13, 2013Date of Patent: June 13, 2017Assignees: BASF SE, EMPA-EIDGENOESSISCHE MATERIALPRUEFUNGS-UND FORSCHUNGSANSTALT, MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFEN E.V.Inventors: Roman Fasel, Pascal Ruffieux, Klaus Muellen, Jinming Cai, Xinliang Feng, Reinhard Berger
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Patent number: 9650497Abstract: A group of novel compounds containing one or more amino substituted DOPO (9,10-dihydro-9-oxa-phosphaphenthren-10-oxide) moieties. The compounds were found to have good flame retardant properties and also good thermal stability, which makes them particularly suitable as flame retardant additives for various thermoplastic polymers. In particular, they can be incorporated in a polyurethane foam.Type: GrantFiled: August 6, 2012Date of Patent: May 16, 2017Assignees: EMPA EIDGENOSSISCHE MATERIALPRUFUNGS- UND FORSCHUNGSANSTALT, FRITZ NAUER AGInventors: Sabyasachi Gaan, Matthias Neisius, Primo Mercoli, Shuyu Liang, Henri Mispreuve, Reinold Näscher
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Patent number: 9638624Abstract: A Multi-pass optical cell (1) with an internal space (11) for laser spectroscopy is described, which is able to reduce or eliminate interference fringes appearing by performing laser absorption spectroscopy in the multi-pass optical cells (1) leading to improved absorption spectra. This is achieved by using a multi-pass optical cell (1) comprising an absorption mask (3) which is permanently or removable mountable in the internal space (11) in a rotatably fixed manner, where in a mask wall (30) a plurality of m apertures (300) is formed, in which the position of each aperture (300) is adapted to a predefinable propagation path of a main optical beam and/or the resulting reflection spot pattern (211) defined by the geometry of the multi-pass optical cell (1) and the used angle of incidence of an initial beam (20), so that each aperture (300) is traversable by the main optical beam from a first side (301) to a second side (302).Type: GrantFiled: October 7, 2013Date of Patent: May 2, 2017Assignee: EMPA EIDGENÖSSISCHE MATERIALPRÜFUNGS- UND FORSCHUNGSANSTALTInventors: Markus Mangold, Bela Tuzson, Lukas Emmenegger
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Publication number: 20170081590Abstract: The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R1 and R2 are independently hydrogen, C1-C6 alkyl, —P(O)(OR3)2, —P(O)OR3R4, or —P(O)R32, wherein R3 and R4 are independently C1-C4 alkyl, C6-C12 aryl, C7-C15 aralkyl or C7-C15 alkaryl; or R1 and R2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C1-C4 alkylene, C6 arylene, C7-C15 aralkylene, C7-C15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C1-C4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C1-C4 alkylene, C6 arylene, C7-C15 aralkylene or C7-C15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C1-C4 alkylene; t is an integerType: ApplicationFiled: March 16, 2015Publication date: March 23, 2017Applicant: EMPA EIDGENOSSISCHE MATERIAL-PRUFUNGS- UND FORSCHUNGSANSTALTInventors: Timea STELZIG, Lea BOMMER, Sabyasachi GAAN, Aleksandra BUCZKO
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Publication number: 20170051101Abstract: Provided are graphene nanoribbons with controlled zig-zag edge and cove edge configuration and methods for preparing such graphene nanoribbons. The nanoribbons are selected from the following formulae.Type: ApplicationFiled: February 9, 2015Publication date: February 23, 2017Applicants: BASF SE, EMPA-Eidgenoessische Materialpruefungs- Und Forschngsanstalt, Max-Planck-Geselischaft zur Foerderung der Wissenschaften e.V.Inventors: Matthias Georg SCHWAB, Klaus MUELLEN, Xinliang FENG, Bo YANG, Tim DUMSLAFF, Roman FASEL, Pascal RUFFIEUX, Jia LIU, Jinming CAI, Carlos SANCHEZ-SANCHEZ, Junzhi LIU