Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with water to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: The present invention provides one with an iron electrode employing a binder comprised of polyvinyl alcohol (PVA) binder. In one embodiment, the invention comprises an iron based electrode comprising a single layer of a conductive substrate coated on at least one side with a coating comprising an iron active material and a binder, wherein the binder is PVA. This iron based electrode is useful in alkaline rechargeable batteries, particularly as a negative electrode in a Ni—Fe battery.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with water to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: The present invention provides one with a battery having an iron anode, e.g., a Ni—Fe battery, having improved performance characteristics. The battery uses a particular electrolyte and/or battery separator. The resulting characteristics of efficiency, charge retention and cycle life are much improved over such batteries in the prior art.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, a polyvinyl alcohol binder and sulfur, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is treated prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant solution to thereby create an oxidized surface. The resulting iron electrode is thereby preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a nickel-iron battery. The battery comprises a positive nickel electrode, an iron negative electrode, an electrolyte comprising a surfactant, and a non-polar separator. In one embodiment, the non-polar separator is comprised of a polyolefin, and the surfactant comprises a zwitterionic surfactant.

Abstract: Provided is a nickel-iron battery. The battery comprises a positive nickel electrode, an iron negative electrode, an electrolyte comprising a surfactant, and a non-polar separator. In one embodiment, the non-polar separator is comprised of a polyolefin, and the surfactant comprises an anionic surfactant, a cationic surfactant or a zwitterionic surfactant.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant solution to thereby create an oxidized surface. The resulting iron electrode is thereby preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: The present invention provides one with an iron electrode employing a binder comprised of polyvinyl alcohol (PVA) binder. In one embodiment, the invention comprises an iron based electrode comprising a single layer of a conductive substrate coated on at least one side with a coating comprising an iron active material and a binder, wherein the binder is PVA. This iron based electrode is useful in alkaline rechargeable batteries, particularly as a negative electrode in a Ni—Fe battery.

Abstract: The present invention provides one with a battery having an iron anode, e.g., a Ni—Fe battery, having improved performance characteristics. The battery uses a particular electrolyte and/or battery separator. The resulting characteristics of efficiency, charge retention and cycle life are much improved over such batteries in the prior art.

Abstract: The present invention provides one with a novel coated iron electrode. Provided is an iron based electrode comprising a single layer conductive substrate coated on at least one side with a multilayered coating, with each coating layer comprising an iron active material, and preferably a binder. The coating is comprised of at least two layers. Each layer has at least a different porosity or composition than an adjacent layer. The iron based electrode is useful in alkaline rechargeable batteries, particularly as a negative electrode in a Ni—Fe battery.

Abstract: Provided is a process for activating a battery comprising an iron electrode. The process comprises providing a battery comprising a cathode and an iron anode. The battery further comprises an electrolyte comprising NaOH, LiOH and a sulfide. The battery is then cycled to equalize the state-of-charge of the cathode and iron anode.

Abstract: Provided is an alkaline battery comprising an electrode stack having at least one positive electrode and at least one negative electrode with a separator disposed therebetween and a spacer between the tabs of similarly polarized electrodes of the electrode stack, which is contained in a cell casing that applies greater pressure to the middle of the electrodes and less pressure to the edges of the electrode stack. In one embodiment, the battery is a nickel-iron battery. In one embodiment, the spacers between the tabs of similarly polarized electrodes are the teeth of a comb structure.

Abstract: Provided is an alkaline battery comprising an electrode stack having at least one positive electrode and at least one negative electrode with a separator disposed therebetween and a spacer between the tabs of similarly polarized electrodes of the electrode stack, which battery is contained in a cell casing that applies greater pressure to the electrode towards the bottom of the electrode stack and less pressure towards the top of the electrode stack. In one embodiment, the spacers between the tabs of similarly polarized electrodes are the teeth of a comb structure.

Abstract: Provided is an alkaline battery wherein the cell casing has a concave shape and the middle of the cell casing creates greater pressure on the middle of the electrode stack than at the edges of the electrode stack. In one embodiment, the battery comprises a positive nickel electrode and a negative iron electrode.

Abstract: Provided is an alkaline battery comprising at least one positive electrode and at least one negative electrode with a separator disposed there between, which are contained in a cell casing that applies greater pressure to the electrodes toward the bottom of the electrode stack and less pressure towards the top of the electrode stack. In one embodiment, the battery comprises a positive nickel electrode and a negative iron electrode.

Abstract: Provided is an alkaline battery comprising at least one positive electrode and at least one negative electrode with a separator disposed therebetween, with at least one of the electrodes having alternating areas that are raised and lowered to create gaps between the electrode and the separator. In one embodiment, the battery comprises a positive nickel electrode and a negative iron electrode.