Abstract: Non-bleeding, non-agglomerated, lustrous colored combination pigments constitute a platy substrate and absorption colorant bound thereto with metal hydroxides and one or more hydrolyzed silane coupling agents.
Abstract: The present invention is directed to an iron-promoted zeolite beta catalyst useful in the selective catalytic reduction of nitrogen oxides with ammonia in which the iron-promoted zeolite beta is treated so as to provide increased amounts of the iron promoter in the form of Fe(OH).
Type:
Application
Filed:
September 7, 2001
Publication date:
March 13, 2003
Applicant:
ENGELHARD CORPORATION
Inventors:
Pascaline H. Tran, Xinsheng Liu, James M. Chen
Abstract: A catalytic trap disposed in an exhaust passage of an internal combustion engine which is operated with periodic alternations between lean and stoichiometric or rich conditions, for abatement of NOx in an exhaust gas stream which is generated by the engine. The trap comprises a catalytic trap material and a refractory carrier member on which the catalytic trap material is disposed. The catalytic trap material comprises: (i) a refractory metal oxide support; (ii) a catalytic component effective for promoting the reduction of NOx under stoichiometric or rich conditions; and (iii) a NOx sorbent effective for adsorbing the NOx under lean conditions and desorbing and reducing the NOx to nitrogen under stoichiometric or rich conditions. The NOx sorbent comprises a metal oxide selected from the group consisting of one or alkali metal oxides, alkaline earth metal oxides and mixtures of one or more alkali metal oxides and alkaline earth metal oxides.
Type:
Application
Filed:
August 21, 2001
Publication date:
March 6, 2003
Applicant:
ENGELHARD CORPORATION
Inventors:
Michel Deeba, Shau-Lin F. Chen, John K. Hochmuth, Patrick L. Burk, Xinyi Wei
Abstract: Composite of at least two metal oxides in the form of Primary Particles and a support having a particle size greater than the Primary Particles used in the formation of a catalyst composition for the treatment of a pollutant containing gas.
Abstract: The present invention relates to an article comprising a catalyst composition and a method useful for the removal of NOx and SOx contaminants from a gaseous stream, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with catalysts of the type generally referred to as “close coupled catalysts” which are designed to reduce pollutants in engine exhaust emissions during engine cold start conditions. The article comprises a lean burn gasoline engine having an exhaust outlet, an upstream section having a close coupled catalyst composite in communication with the exhaust outlet, and a downstream section. The upstream close coupled catalyst composite comprises a first support; a first platinum group component; and a SOx sorbent component selected from the group consisting of oxides and mixed oxides of barium, lanthanum, magnesium, manganese, neodymium, praseodymium, and strontium.
Type:
Application
Filed:
August 24, 2001
Publication date:
February 27, 2003
Applicant:
ENGELHARD CORPORATION
Inventors:
Michel Deeba, John K. Hochmuth, Uwe Dahle, Stefan Brandt
Abstract: A nickel catalyst comprising 0.1 to 12.5 wt. % of at least one structural promoter, selected from the group of oxides of metals and metalloids and combinations thereof, and 87.5 to 99.9 wt. % nickel, calculated on the weight of nickel and the structural promoter together, the catalyst having an nickel surface area, as defined herein, of at least 10 m2/g catalyst and an average pore diameter, as defined herein, of 10 to 60 nm. It has been found that already very small amounts of promoter improves the structure of the catalyst. High amounts still provide a stable, sinter resistant material, but result in a decrease in the pore size to lower levels. Furthermore, properties and sulfur uptake capacity.
Type:
Grant
Filed:
May 1, 2001
Date of Patent:
February 25, 2003
Assignee:
Engelhard Corporation
Inventors:
Bernard Hendrik Reesink, Nico van Gasteren
Abstract: A laminar pigment which has an aluminum- or an aluminum-cerium oxide coating combined with a hydrolyzed silane coupling agent treated surface is used as a pigment for a powder coating composition. By combining the pigment with a powdery film-forming polymer, a film-forming composition which can be applied by electrostatic coating is produced.
Type:
Grant
Filed:
October 10, 2001
Date of Patent:
February 25, 2003
Assignee:
Engelhard Corporation
Inventors:
Joseph Michael Bagala, Kurt Norman Beale
Abstract: A process for adsorbing hydrocarbons from an acid gas stream includes passing the acid gas stream through an adsorbent which selectively removes hydrocarbons, desorbing the hydrocarbons from the adsorbent and contacting the desorbed hydrocarbons with an acid gas removal solution to remove acid gases which have been coadsorbed with the hydrocarbons. The process is particularly useful in removing hydrocarbons from a hydrogen sulfide-containing stream which is being directed to Claus processing for conversion into elemental sulfur. Useful adsorbents include crystalline titanium silicate molecular sieves containing titania octahedral sites such as ETS-10 and similar materials, as well as high silica aluminosilicate zeolite.
Type:
Grant
Filed:
March 14, 2002
Date of Patent:
February 18, 2003
Assignee:
Engelhard Corporation
Inventors:
Kenneth F. Butwell, William B. Dolan, Steven M. Kuznicki
Abstract: A composition and method for improving the adhesion properties of catalytic and adsorptive compositions to a substrate through the addition of clay and/or silicone binder is disclosed. Preferably, the composition includes manganese dioxide and attapulgite clay and/or a silicone polymer which is adhered to a metal substrate, such as a motor vehicle radiator.
Abstract: Separation of ethylene from ethane is achieved by feeding a mixture of the C2 hydrocarbons in contact with a CTS-1 crystalline titanium silicate molecular sieve which has a controlled pore size to selectively adsorb ethylene and size exclude ethane. The feed stream can also contain acetylene which can be selectively adsorbed from both ethane and ethylene by further controlling the pore size of the CTS-1 molecular sieve. Propane/propylene separation is also disclosed.
Abstract: A silver/gold coated laminar substrate pearlescent product is improved by incorporating rhodium in an amount of up to about 2% into the coating and/or by overcoating with a silane in an amount of up to about 5%.
Type:
Grant
Filed:
September 3, 1999
Date of Patent:
February 11, 2003
Assignee:
Engelhard Corporation
Inventors:
Ahmad Moini, Daniel S. Fuller, Alfred E. Kober, Curtis J. Zimmermann
Abstract: In one embodiment, the present invention relates to a pesticide delivery system, containing a continuous film having a thickness from about 1 &mgr;m to about 1,000 &mgr;m and noncontinuous areas having sizes less than about 100 &mgr;m, the continuous film containing a particulate material wherein at least 90% by weight of the particulate material has a particle size of about 10 microns or less, and a pest control agent at least partially coating the particulate material.
Type:
Grant
Filed:
October 2, 2000
Date of Patent:
February 4, 2003
Assignee:
Engelhard Corporation
Inventors:
Gary J. Puterka, David Michael Glenn, Dennis G. Sekutowski
Abstract: A process for catalytically generating a hydrogen-rich gas from a hydrocarbon feed. A stream comprising the hydrocarbon feed, water and air is preheated to a temperature sufficiently high to initiate catalytic partial oxidation of the hydrocarbon feed. The preheated stream is then introduced into an autothermal reactor containing a layered catalyst member at a temperature sufficient to initiate and sustain both catalytic partial oxidation and catalytic steam reforming. At least part of the hydrocarbon feed is catalytically partially oxidized to produce a hydrogen-rich gas comprising hydrogen and carbon oxides and hydrocarbons remaining in the feed are steam reformed to produce further quantities of the hydrogen-rich gas. The layered catalyst member comprises a monolith substrate containing at least one layer of a steam reforming catalyst in contact with at least one layer of a catalytic partial oxidation catalyst.
Abstract: The present invention relates to a layered catalyst composite useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved catalysts of the type generally referred to as “three-way conversion” catalysts. The layered catalysts trap sulfur oxide contaminants which tend to poison three-way conversion catalysts used to abate other pollutants in the stream. The layered catalyst composites of the present invention have a sulfur oxide absorbing layer before or above a nitrogen oxide absorbing layer. The layered catalyst composite comprises a first layer and a second layer. The first layer comprises a first support and at least one first platinum component. The second layer comprises a second support and a SOX sorbent component having a free energy of formation from about 0 to about −90 Kcal/mole at 350° C.
Abstract: The present invention relates to a method for recovering and/or removing organic compounds from gas flows, wherein the method comprises the step of:
removing the organic compounds from the gas flow using an adsorber and
desorbing the organic compounds using microwaves, characterized in that the adsorber is a finely dispersed mixture of a hydrophilic and a hydrophobic adsorbent.
Type:
Grant
Filed:
October 23, 2000
Date of Patent:
January 28, 2003
Assignee:
Engelhard Corporation
Inventors:
Henner Schmidt-Traub, Dieter Bathen, Thomas Schulz, Michael Hoffmeister
Abstract: A process for adsorbing hydrocarbons from an acid gas stream includes passing the acid gas stream through an adsorbent that selectively removes hydrocarbons, desorbing the hydrocarbons from the adsorbent and contacting the desorbed hydrocarbons with an acid gas removal solution to remove acid gases which have been coadsorbed with the hydrocarbons. The process is particularly useful in removing hydrocarbons from a hydrogen sulfide-containing stream that is being directed to Claus processing for conversion into elemental sulfur. Useful adsorbents include Y-type zeolites having a silica to alumina mole ratio of less than 15 and a reduced sodium content.
Type:
Grant
Filed:
October 11, 2001
Date of Patent:
January 21, 2003
Assignee:
Engelhard Corporation
Inventors:
John W. Byrne, William B. Dolan, Kenneth F. Butwell
Abstract: An OBD system is provided for monitoring an ozone depletion system that includes a catalyst coating containing MnO2 applied to a heat exchange surface on a moving vehicle over which atmospheric air passes. A physical characteristic of the catalyst coating or a material containing a physical characteristic within the catalyst coating is sensed to determine the presence or absence of the catalyst coating for detecting catastrophic failure of the ozone depleting system and/or degradation or wear of the catalyst coating to ascertain the efficiency of the catalyst coating.
Type:
Grant
Filed:
May 26, 2000
Date of Patent:
January 14, 2003
Assignee:
Engelhard Corporation
Inventors:
Fred Mitchell Allen, Xiaolin David Yang, Ronald Marshall Heck, Jeffrey B. Hoke, Earl Marvin Waterman, Xinsheng Liu, Dennis Ray Anderson, Arthur Bruce Robertson, Terence Christopher Poles
Abstract: The invention is directed to a process for the hydrogenation of a hydrocarbon feed containing thiophenic sulfur contaminants, wherein the entire feed is contacted with a nickel catalyst, the improvement comprising contacting the said feed additionally with a platinum group metal prior to or simultaneously with contacting the nickel.
Abstract: One aspect of the present invention relates to a catalyst system for use in olefinic polymerization, containing a solid titanium catalyst component prepared by contacting a titanium compound and a magnesium compound; an organoaluminum compound having at least one aluminum-carbon bond; and an organosilicon compound comprising at least one of cyclobutyl group. Another aspect of the present invention relates to a method of making a catalyst for use in olefinic polymerization, involving the steps of reacting a Grignard reagent having a cyclobutyl group with an orthosilicate to provide an organosilicon compound having a cyclobutyl moiety; and combining the organosilicon compound with an organoaluminum compound having at least one aluminum-carbon bond and a solid titanium catalyst component prepared by contacting a titanium compound and a magnesium compound.