Abstract: The present invention concerns a process for the recovery of lead from a lead pastel electrolytically, where the pastel contains lead sulfate. The process provides for the leaching of the non-desulfurised pastel and the subsequent removal of the sulfates by precipitation; the leachate containing the lead ions is then subjected to electrolysis for the recovery of metal lead. The present invention further relates to a process for the recovery of lead accumulator components, wherein the lead contained in the pastel of the accumulators is recovered according to the aforesaid process.
Type:
Application
Filed:
March 6, 2019
Publication date:
January 28, 2021
Applicant:
Engitec Technologies S.P.A.
Inventors:
Massimo Giuseppe MACCAGNI, Edoardo GUERRINI
Abstract: The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis r
Type:
Grant
Filed:
November 27, 2008
Date of Patent:
April 2, 2013
Assignee:
Engitec Technologies S.p.A.
Inventors:
Massimo Maccagni, Silvano Cossali, Carmelita Roncaldier, Carlo Olper, Luigi Olper, Alessandro Olper
Abstract: The present invention relates to a process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes based on leaching with a solution of sodium sulphide in which the sulphur contained in the residues is selectively leached as sodium polysulphide. The sulphur leaching solution is conveniently regenerated and recycled to the process.
Type:
Grant
Filed:
May 22, 2007
Date of Patent:
October 20, 2009
Assignee:
Engitec Technologies S.p.A.
Inventors:
Marco Olper, Massimo Maccagni, Silvano Cossali