Patents Assigned to Engitec Technologies S.p.A.
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Patent number: 12191463Abstract: A spent and/or decommissioned accumulator treatment plant and process, wherein a plurality of objects originating from separate waste collection of spent and/or decommissioned accumulators, nominally comprising lead-acid accumulators and accumulators and objects of a different type, are subject to an X-ray scan. If an analysis of the X-ray scan indicates that an object is not a lead-acid accumulator, and in particular is a lithium-ion battery or accumulator, it is deviated out of the treatment workflow, that comprises grinding the objects and separating lead from other materials.Type: GrantFiled: November 17, 2020Date of Patent: January 7, 2025Assignee: ENGITEC TECHNOLOGIES S.P.A.Inventor: Gianfranco Diegoli
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Patent number: 11667990Abstract: The present invention concerns a process for the recovery of lead from a lead pastel electrolytically, where the pastel contains lead sulfate. The process provides for the leaching of the non-desulfurised pastel and the subsequent removal of the sulfates by precipitation; the leachate containing the lead ions is then subjected to electrolysis for the recovery of metal lead. The present invention further relates to a process for the recovery of lead accumulator components, wherein the lead contained in the pastel of the accumulators is recovered according to the aforesaid process.Type: GrantFiled: March 6, 2019Date of Patent: June 6, 2023Assignee: ENGITEC TECHNOLOGIES S.P.A.Inventors: Massimo Giuseppe Maccagni, Edoardo Guerrini
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Publication number: 20230083759Abstract: A method for recovering metal zinc from a solid metallurgical waste containing zinc and manganese, may include: (a) bringing the solid metallurgical waste into contact with an aqueous leaching solution comprising chloride ions and ammonium ions to produce at least one leachate including zinc ions and manganese ions and at least one insoluble solid residue; (b) cementing the leachate, by adding metal zinc as a precipitating agent, to eliminate at least one metal other than zinc and manganese possibly present in the leachate as ions and producing a purified leachate; (c) subjecting the purified leachate to electrolysis in an electrolytic cell including at least one cathode and at least one anode immersed in the purified leachate to deposit metal zinc on the cathode and producing at least one exhausted leachate, and, before the electrolysis, precipitating manganese ions by oxidation with permanganate ions and subsequently separating a precipitate including MnO2.Type: ApplicationFiled: February 10, 2021Publication date: March 16, 2023Applicant: ENGITEC TECHNOLOGIES S.P.A.Inventors: Massimo Giuseppe MACCAGNI, Edoardo GUERRINI, Andrea GRASSI
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Publication number: 20220416323Abstract: A spent and/or decommissioned accumulator treatment plant and process, wherein a plurality of objects originating from separate waste collection of spent and/or decommissioned accumulators, nominally comprising lead-acid accumulators and accumulators and objects of a different type, are subject to an X-ray scan. If an analysis of the X-ray scan indicates that an object is not a lead-acid accumulator, and in particular is a lithium-ion battery or accumulator, it is deviated out of the treatment workflow, that comprises grinding the objects and separating lead from other materials.Type: ApplicationFiled: November 17, 2020Publication date: December 29, 2022Applicant: ENGITEC TECHNOLOGIES S.P.A.Inventor: Gianfranco DIEGOLI
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Publication number: 20210025026Abstract: The present invention concerns a process for the recovery of lead from a lead pastel electrolytically, where the pastel contains lead sulfate. The process provides for the leaching of the non-desulfurised pastel and the subsequent removal of the sulfates by precipitation; the leachate containing the lead ions is then subjected to electrolysis for the recovery of metal lead. The present invention further relates to a process for the recovery of lead accumulator components, wherein the lead contained in the pastel of the accumulators is recovered according to the aforesaid process.Type: ApplicationFiled: March 6, 2019Publication date: January 28, 2021Applicant: Engitec Technologies S.P.A.Inventors: Massimo Giuseppe MACCAGNI, Edoardo GUERRINI
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Patent number: 8409421Abstract: The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis rType: GrantFiled: November 27, 2008Date of Patent: April 2, 2013Assignee: Engitec Technologies S.p.A.Inventors: Massimo Maccagni, Silvano Cossali, Carmelita Roncaldier, Carlo Olper, Luigi Olper, Alessandro Olper
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Publication number: 20110083970Abstract: The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis rType: ApplicationFiled: November 27, 2008Publication date: April 14, 2011Applicant: ENGITEC TECHNOLOGIES S.p.A.Inventors: Marco Olper, Carmelita Roncaldier, Carlo Olper, Luigi Olper, Alessandro Olper, Massimo Maccagni, Silvano Cossali
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Process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes
Patent number: 7604785Abstract: The present invention relates to a process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes based on leaching with a solution of sodium sulphide in which the sulphur contained in the residues is selectively leached as sodium polysulphide. The sulphur leaching solution is conveniently regenerated and recycled to the process.Type: GrantFiled: May 22, 2007Date of Patent: October 20, 2009Assignee: Engitec Technologies S.p.A.Inventors: Marco Olper, Massimo Maccagni, Silvano Cossali -
Process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes
Publication number: 20070274902Abstract: The present invention relates to a process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes based on leaching with a solution of sodium sulphide in which the sulphur contained in the residues is selectively leached as sodium polysulphide. The sulphur leaching solution is conveniently regenerated and recycled to the process.Type: ApplicationFiled: May 22, 2007Publication date: November 29, 2007Applicant: ENGITEC TECHNOLOGIES S.p.AInventors: Marco Olper, Massimo Maccagni, Silvano Cossali