Patents Assigned to Engitec Technologies S.p.A.
  • Patent number: 11667990
    Abstract: The present invention concerns a process for the recovery of lead from a lead pastel electrolytically, where the pastel contains lead sulfate. The process provides for the leaching of the non-desulfurised pastel and the subsequent removal of the sulfates by precipitation; the leachate containing the lead ions is then subjected to electrolysis for the recovery of metal lead. The present invention further relates to a process for the recovery of lead accumulator components, wherein the lead contained in the pastel of the accumulators is recovered according to the aforesaid process.
    Type: Grant
    Filed: March 6, 2019
    Date of Patent: June 6, 2023
    Assignee: ENGITEC TECHNOLOGIES S.P.A.
    Inventors: Massimo Giuseppe Maccagni, Edoardo Guerrini
  • Publication number: 20230083759
    Abstract: A method for recovering metal zinc from a solid metallurgical waste containing zinc and manganese, may include: (a) bringing the solid metallurgical waste into contact with an aqueous leaching solution comprising chloride ions and ammonium ions to produce at least one leachate including zinc ions and manganese ions and at least one insoluble solid residue; (b) cementing the leachate, by adding metal zinc as a precipitating agent, to eliminate at least one metal other than zinc and manganese possibly present in the leachate as ions and producing a purified leachate; (c) subjecting the purified leachate to electrolysis in an electrolytic cell including at least one cathode and at least one anode immersed in the purified leachate to deposit metal zinc on the cathode and producing at least one exhausted leachate, and, before the electrolysis, precipitating manganese ions by oxidation with permanganate ions and subsequently separating a precipitate including MnO2.
    Type: Application
    Filed: February 10, 2021
    Publication date: March 16, 2023
    Applicant: ENGITEC TECHNOLOGIES S.P.A.
    Inventors: Massimo Giuseppe MACCAGNI, Edoardo GUERRINI, Andrea GRASSI
  • Publication number: 20220416323
    Abstract: A spent and/or decommissioned accumulator treatment plant and process, wherein a plurality of objects originating from separate waste collection of spent and/or decommissioned accumulators, nominally comprising lead-acid accumulators and accumulators and objects of a different type, are subject to an X-ray scan. If an analysis of the X-ray scan indicates that an object is not a lead-acid accumulator, and in particular is a lithium-ion battery or accumulator, it is deviated out of the treatment workflow, that comprises grinding the objects and separating lead from other materials.
    Type: Application
    Filed: November 17, 2020
    Publication date: December 29, 2022
    Applicant: ENGITEC TECHNOLOGIES S.P.A.
    Inventor: Gianfranco DIEGOLI
  • Publication number: 20210025026
    Abstract: The present invention concerns a process for the recovery of lead from a lead pastel electrolytically, where the pastel contains lead sulfate. The process provides for the leaching of the non-desulfurised pastel and the subsequent removal of the sulfates by precipitation; the leachate containing the lead ions is then subjected to electrolysis for the recovery of metal lead. The present invention further relates to a process for the recovery of lead accumulator components, wherein the lead contained in the pastel of the accumulators is recovered according to the aforesaid process.
    Type: Application
    Filed: March 6, 2019
    Publication date: January 28, 2021
    Applicant: Engitec Technologies S.P.A.
    Inventors: Massimo Giuseppe MACCAGNI, Edoardo GUERRINI
  • Patent number: 8409421
    Abstract: The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis r
    Type: Grant
    Filed: November 27, 2008
    Date of Patent: April 2, 2013
    Assignee: Engitec Technologies S.p.A.
    Inventors: Massimo Maccagni, Silvano Cossali, Carmelita Roncaldier, Carlo Olper, Luigi Olper, Alessandro Olper
  • Publication number: 20110083970
    Abstract: The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis r
    Type: Application
    Filed: November 27, 2008
    Publication date: April 14, 2011
    Applicant: ENGITEC TECHNOLOGIES S.p.A.
    Inventors: Marco Olper, Carmelita Roncaldier, Carlo Olper, Luigi Olper, Alessandro Olper, Massimo Maccagni, Silvano Cossali
  • Patent number: 7604785
    Abstract: The present invention relates to a process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes based on leaching with a solution of sodium sulphide in which the sulphur contained in the residues is selectively leached as sodium polysulphide. The sulphur leaching solution is conveniently regenerated and recycled to the process.
    Type: Grant
    Filed: May 22, 2007
    Date of Patent: October 20, 2009
    Assignee: Engitec Technologies S.p.A.
    Inventors: Marco Olper, Massimo Maccagni, Silvano Cossali
  • Publication number: 20070274902
    Abstract: The present invention relates to a process for the recovery of elemental sulphur from residues produced in hydrometallurgical processes based on leaching with a solution of sodium sulphide in which the sulphur contained in the residues is selectively leached as sodium polysulphide. The sulphur leaching solution is conveniently regenerated and recycled to the process.
    Type: Application
    Filed: May 22, 2007
    Publication date: November 29, 2007
    Applicant: ENGITEC TECHNOLOGIES S.p.A
    Inventors: Marco Olper, Massimo Maccagni, Silvano Cossali