Patents Assigned to Eni S.p.A.it
  • Publication number: 20060188338
    Abstract: Process for the disposal of sulfur which comprises melting the sulfur, optionally in the presence of hydrogen sulfide, and injecting the molten sulfur into geological structures having a temperature ranging from 90 to 160° C.
    Type: Application
    Filed: July 5, 2004
    Publication date: August 24, 2006
    Applicant: ENI S.P.A.
    Inventors: Alberto Di Lullo, Paul Lockhart
  • Publication number: 20060163115
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), comprising the following steps: • mixing at least part of the heavy feedstock and/or at least most of the stream containing asphaltenes obtained in the deasphalting unit with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; • sending the stream containing the hydrotreatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the different fractions coming from the hydrotreatment reaction are separated; • recyc
    Type: Application
    Filed: December 12, 2003
    Publication date: July 27, 2006
    Applicants: ENI S.P.A., SNAMPROGETTI S.P.A., ENITECNOLGIE S.P.A.
    Inventors: Romolo Montanari, Mario Marchionna, Nicoletta Panariti, Alberto Delbianco, Sergio Rosi
  • Publication number: 20060157245
    Abstract: A process is described for reducing the production of water in oil wells which comprises the injection into the formation around the well of an aqueous solution of one or more polymers selected from those having general formula (1) [] wherein: n ranges from 0.70 to 0.98; m ranges from 0.30 to 0.02; n+m=1; X1 and X2, the same or different, are selected from H an CH3; R1, R2, R3, the same or different, are selected from C1-C10 monofunctional hydrocarbyl groups; x ranges from 2 to 5.
    Type: Application
    Filed: March 14, 2006
    Publication date: July 20, 2006
    Applicants: ENI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Luisa Chiappa, Maria Andrei, Thomas Lockhart, Giovanni Burrafato, Giuseppe Maddinelli
  • Publication number: 20060157385
    Abstract: Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from the
    Type: Application
    Filed: December 20, 2005
    Publication date: July 20, 2006
    Applicants: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
  • Publication number: 20060154814
    Abstract: The present invention concerns a process for oxidative desulphurization of hydrotreated hydrocarbon mixtures which boil within the range of 180° to 360° C., containing less than 350 ppm of sulphur as thiophenic compounds, said process comprising the steps of a) putting these mixtures in contact, in the presence of an organic peroxide, with a catalytic composition comprising a completely amorphous micro and/or mesoporous mixed oxide containing an oxide matrix selected from silica, alumina, ceria, magnesia and mixtures of thereof, wherein one or more oxidative metal oxides selected from transition metal oxides and group IVA metal oxides are uniformly dispersed, and b) separating the obtained corresponding sulphur oxygenated products from the hydrocarbon mixture.
    Type: Application
    Filed: September 26, 2003
    Publication date: July 13, 2006
    Applicants: ENI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Laura Zanibelli, Giuseppe Bellussi, Avelino Corma Canos, Marcelo Domine, Maria Gagliardi
  • Patent number: 7074868
    Abstract: A description follows of random butadiene-isoprene copolymers with a trans-1,4 structure, having a butadiene/isoprene molar composition ranging from 98/2 to 32/68, the above copolymers being crystalline or amorphous depending on the isoprene content. The process for the preparation of the above copolymers is also described, in the present of a catalytic system which comprises: (a) a first component consisting of a vanadium compound selected from: (a1) compounds having general formula (Ia) VO(L)n(X)m wherein n is an integer from 1 to 3 and m ranges from zero to 2, n+m being equal to 2 or 3; (a2) compounds having general formula (Ib) V(L)p(X)q wherein p is an integer from 1 to 4, q ranges from zero to 3, the sum of p+q being equal to 3 or 4; wherein L is a bidentate ligand and X is a halogen, preferably Chlorine; (b) a second component selected from aluminoxanes and relative derivatives.
    Type: Grant
    Filed: August 27, 2002
    Date of Patent: July 11, 2006
    Assignees: ENI S.p.A., Polimeri Europa S.p.A.,
    Inventors: Giovanni Ricci, Francesco Masi, Marco Battistella, Anna Sommazzi, Maria Rivellini, legal representative, Sefano Santi, legal representative, Laura Santi, legal representative, Roberto Santi, deceased
  • Publication number: 20060123695
    Abstract: Fuel for motor vehicles comprising an emulsion between water and a liquid hydrocarbon, and an anti-cavitation additive comprising a copolymer including 20-80% in moles, preferably 35-70% in moles, of units containing at least one carboxylic group and 80-20% in moles, preferably 65-30% in moles, of units deriving from at least one monomer having an ethylene unsaturation, and wherein at least 20% in moles of the carboxylic groups, preferably 30-90% in moles, is in the form of at least one derivative selected from carboxylate salt, ester, amide and imide.
    Type: Application
    Filed: March 22, 2004
    Publication date: June 15, 2006
    Applicant: ENI S.p.A.
    Inventors: Luigi D'Elia, Pietro Scorletti, Riccardo Rausa, Guido Rivolta, Alberto De Amicis, Tiziano Ambrosini
  • Publication number: 20060122445
    Abstract: A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.
    Type: Application
    Filed: January 18, 2006
    Publication date: June 8, 2006
    Applicants: ENICHEM S.p.A, ENI S.p.A., ENITECNOLOGIE S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Giannino Pazzuconi, Carlo Perego, Giuseppe Bellussi
  • Patent number: 7055623
    Abstract: Improved method for the drilling of the initial phase of deep water oil wells with an underwater well head consisting in the positioning and cementation of the conductor pipe and anchorage casing by means of a single drilling phase. A tapered hole (with a double diameter) is drilled using a drill string consisting of a motor driven pilot bit and a reaming bit.
    Type: Grant
    Filed: November 12, 2001
    Date of Patent: June 6, 2006
    Assignee: ENI S.p.A.
    Inventors: Angelo Calderoni, Claudio Maria Molaschi, Guido Brusco
  • Patent number: 7048905
    Abstract: Process for the production of concentrated aqueous solutions of hydrogen peroxide, comprising the following steps: (a) feeding to a reactor containing a catalyst based on palladium and platinum, heterogeneous and maintained in dispersion in a liquid reaction medium: (i) a liquid stream consisting of an alcohol or a mixture of C1–C3 alcohols or a mixture of said alcohols with water containing at least 50% by weight of alcohol, also containing an acid promoter and a halogenated promoter, the alcohol and optionally all or part of the water contained in the stream being recycled from the subsequent phase d); (ii) a gaseous stream containing hydrogen, oxygen and an inert gas, characterized in that the concentration of the hydrogen is less than 4.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: May 23, 2006
    Assignees: Polimeri Europa S.p.A., ENI S.p.A.
    Inventors: Giuseppe Paparatto, Franco Rivetti, Pietro Andrigo, Giordano De Alberti, Ugo Romano
  • Patent number: 7019186
    Abstract: A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: March 28, 2006
    Assignees: Enichem S.p.A., ENI S.p.A., Enitecnologie S.p.A.
    Inventors: Giannino Pazzuconi, Carlo Perego, Giuseppe Bellussi
  • Publication number: 20060042195
    Abstract: A process is described for the zero emission storage of sulphur, using a storage tank made up of one or more levels, characterized in that said storage tank, having an impermeable bottom, essentially consists of reinforced EPS (expanded polystyrene) panels.
    Type: Application
    Filed: November 19, 2004
    Publication date: March 2, 2006
    Applicants: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Leonardo Zan, Francesco Crescenzi
  • Patent number: 7004333
    Abstract: Process for recovering at least 70% of hollow glass microspheres having an average diameter, according to the ASTM D1214-1989, ranging from 5 to 200 ?m contained in a mixture of drilling mud and cuttings which comprises: a) screening, if necessary, the mixture through one or more 5 to 20 mesh sieves; b) feeding the screened mixture to one or more cyclones and/or hydrocyclones arranged in series, each of which is fed with a volume flow-rate from 1.5 to 10 times higher than the maximum nominal operating value.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: February 28, 2006
    Assignees: ENI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Armando Marcotullio, Raffaella Monga, Giuseppe Belmonte, Angelo Calderoni, Giovanni Ferrari
  • Patent number: 7004253
    Abstract: A process is described for reducing the production of water in oil wells, with temperatures of up to (90° C.), which comprises the injection in the formation around the well of an aqueous solution of one or more polymers selected from those having general formula (I) wherein: n ranges from (0.40) to (0.70), preferably from (0.5) to (0.65); m ranges from (0.15) to (0.65), preferably from (0.3) to (0.5); p ranges from (0.02) to (0.20), preferably from (0.05) to (0.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: February 28, 2006
    Assignees: Eni S.p.A., Enitecnologie S.p.A.
    Inventors: Luisa Chiappa, Maria Andrei, Thomas Paul Lockhart, Giovanni Burrafato, Giuseppe Maddinelli
  • Patent number: 7004996
    Abstract: Process for the removal of the hydrogen sulfide contained in natural gas, which comprises: a. absorbing the hydrogen sulfide present in natural gas by means of a virgin naphtha, in an adsorbing device and with a molar ratio virgin naphtha/H2S ranging from 0.85 to 1.5; b. recovering the hydrogen sulfide absorbed by the virgin naphtha as head product of a distillation column operating with a reflux having a temperature of between ?5 and ?20° C.; c. recycling the virgin naphtha discharged as bottom product of the distillation column, to the absorption step (a); d. introducing the hydrogen sulfide back to the production field of natural gas, at the temperature and pressure conditions present at the head of the distillation column.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: February 28, 2006
    Assignee: ENI S.p.A.
    Inventor: Liberato Giampaolo Ciccarelli
  • Patent number: 6977273
    Abstract: A process is described for synthesizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours so that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: December 20, 2005
    Assignees: Institut Francais du Petrole, ENI S.p.A., AGIP Petroli S.p.A.
    Inventors: Magalie Roy-Auberger, Philippe Courty, Renaud Revel, Roberto Zennaro
  • Publication number: 20050232859
    Abstract: Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with said solid fed at its maximum oxidation degree (over-reduced form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with said reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein said solid contains at least on e
    Type: Application
    Filed: March 22, 2005
    Publication date: October 20, 2005
    Applicants: ENI S.p.A., ENITECNOLOGIE S.p.A., SNAMPROGETTI S.p.A.
    Inventors: Domenico Sanfilippo, Franco Mizia, Alberto Malandrino, Stefano Rossini
  • Publication number: 20050222348
    Abstract: A description follows of random butadiene-isoprene copolymers with a trans-1,4 structure, having a butadiene/isoprene molar composition ranging from 98/2 to 32/68, the above copolymers being crystalline or amorphous depending on the isoprene content. The process for the preparation of the above copolymers is also described, in the present of a catalytic system which comprises: (a) a first component consisting of a vanadium compound selected from: (a1) compounds having general formula (Ia) VO(L)n(X)m wherein n is an integer from 1 to 3 and m ranges from zero to 2, n+m being equal to 2 or 3; (a2) compounds having general formula (Ib) V(L)p(X)q wherein p is an integer from 1 to 4, q ranges from zero to 3, the sum of p+q being equal to 3 or 4; wherein L is a bidentate ligand and X is a halogen, preferably Chlorine; (b) a second component selected from aluminoxanes and rclativc dcrivativcs.
    Type: Application
    Filed: August 27, 2002
    Publication date: October 6, 2005
    Applicants: ENI S.p.A., POLIMERI EUROPA S.p.A.
    Inventors: Giovanni Ricci, Francesco Masi, Marco Battistella, Anna Sommazzi, Roberto Santi
  • Patent number: 6936738
    Abstract: A process is described for the preparation of phenol characterized in that the phenol is obtained by means of the hydrodeoxygenation of benzene-diols with hydrogen, operating in continuous, in an aqueous solution, at temperatures ranging from 250 to 500° C., at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or group VIII of the periodic table.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: August 30, 2005
    Assignees: ENI S.p.A., Polimeri Europa S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti
  • Patent number: 6926504
    Abstract: An improved electrical pump is first provided for use in a wellbore. The pump comprises a stator and a stator housing, and an armature and an armature housing. The stator housing and the armature housing define concentrically nested tubular bodies. The armature housing is configured to permit production fluids to flow therethrough. In one aspect, the stator and armature are assembled in connectible and interchangeable sections called “modules” that can be attached in series. In one aspect, the electrical operation of coils within the stator is protected from individual coil short-circuiting or failure by wiring them in parallel, rather than in series. In addition, each module may be wired in parallel. In this way, a failure of one stator module will not result in the failure of another stator module. In an embodiment of the present invention, the valves of the pump are capable of being retrieved by a wireline, without pulling the entire production string.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: August 9, 2005
    Assignees: Total Fiza Elf, Eni S.p.A., Shell International Exploration & Production B.V.
    Inventor: William F. Howard