Patents Assigned to ENI S.p.A.
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Patent number: 11891314Abstract: The present invention relates to a device and an apparatus and relative method for removing hydrocarbons from a water body, in particular for the remediation of hydrophobic contaminated hydrocarbons present as a demixed phase. The device of the invention is equipped with at least one sensor which determines its position with respect to the demixed phase in the body of water, allowing automated modification of the position of the device with respect to the demixed phase in optimising its separation and recovery.Type: GrantFiled: December 22, 2017Date of Patent: February 6, 2024Assignee: ENI S.P.A.Inventors: Andrea Chiodini, Stefano Loda
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Patent number: 11884565Abstract: There is a process for the production of a liquid fuel and of a gaseous fuel from biomass. The biomass is sent to a pre-treatment section to form a homogeneous phase that can be moved and/or pumped, wherein inert parts are separated from the biomass and the biomass shredded and/or ground to reduce its size. The homogeneous phase obtained is then subjected to subcritical hydrothermal liquefaction at a temperature between 240° C. and 310° C. to form a liquefied phase. The liquefied phase is separated. After separation, the process continues in two alternative and mutually exclusive modes. In the first mode, the first aqueous phase is subjected to an anaerobic reaction with multiple stages producing biogas; the oily phase is separated into a bio-oil and a solid residue. In the second mode, the separate mixed phase is separated by density or dynamics forming a first aqueous phase, bio-oil and a gaseous phase.Type: GrantFiled: July 31, 2019Date of Patent: January 30, 2024Assignee: ENI S.P.A.Inventors: Roberta Miglio, Roberto Paglino, Cristian Torri, Alisar Kiwan, Daniele Fabbri
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Patent number: 11887747Abstract: Aqueous composition comprising: from 0.5% by weight to 5% by weight, preferably from 1% by weight to 4% by weight, with respect to the total weight of said aqueous composition, of at least one conductive polymer; from 1% by weight to 100% by weight, preferably from 2% by weight to 10% by weight, more preferably from 15% by weight to 50% by weight, with respect to the total weight of said at least one conductive polymer, of at least one cellulose ether. Said aqueous composition may advantageously be used as a printable ink or printable paste in various techniques such as, for example, screen printing, gravure printing, flexographic printing, spray coating, slot die coating, spin-coating, ink-jet printing. Preferably, said aqueous composition may advantageously be used as a printable paste for screen printing.Type: GrantFiled: October 24, 2018Date of Patent: January 30, 2024Assignee: ENI S.P.A.Inventor: Gianni Corso
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Publication number: 20240026210Abstract: A treatment fluid may be suitable for a hydrocarbon fluid extraction well. Such a treatment fluid may include a water-in-oil emulsion. The water-in-oil emulsion may include: an oily continuous phase; and an aqueous discontinuous phase comprising water and a plurality of particles comprising a hydrogel comprising a cationic polymer. The cationic polymer may include, in polymerized form, a monomer with one or more cationic groups. The cationic group may be a —N+—R1R2R3 group, wherein R1, R2, and R3, are independently H or a C1 to C4 alkyl group.Type: ApplicationFiled: September 27, 2023Publication date: January 25, 2024Applicant: ENI S.P.A.Inventors: Davide MOSCATELLI, Lucilla DEL GAUDIO, Paola ALBONICO, Alessandra BELLONI, Alberto CESANA
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Patent number: 11878289Abstract: A process of hydrotreating of a feed containing one or more hydrocarbons by contacting the feed with hydrogen in the presence of a metal sulphide catalyst obtained by sulphidation of a precursor which is in the form of a mixed oxide of formula (I) or of a mixed oxide of formula (I) bound to an inorganic binder B: Mea Nib Moc Wd Ale Of • pC (I).Type: GrantFiled: February 7, 2022Date of Patent: January 23, 2024Assignee: ENI S.p.A.Inventors: Angela Carati, Giuseppe Bellussi, Michela Bellettato
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Patent number: 11860328Abstract: A detection system includes a drill bit where electro-acoustic transducers operate as a transmitter and/or receiver, are integrated; electronic circuits; a control unit associated with a data storage unit and is powered by an electrical supply system, the processing and control unit for generating driving signals sent to the electro-acoustic transducer acting as a transmitter by the analogue driving electronic circuits, for acquiring signals received from the transducer and for processing the received signals to determine discontinuity interfaces and/or anomalies in pore pressures in geological formations; wherein each of the electro-acoustic transducers is in contact with a pressurised fluid and includes: a tubular body with two end portions opposed to each other longitudinally, internally a first chamber ending with the first end portion and a second chamber on one side adjacent and in fluid communication with the first chamber and, on the other side ending with the second end portion.Type: GrantFiled: June 22, 2020Date of Patent: January 2, 2024Assignee: ENI S.P.A.Inventors: Stefano Carminati, Massimo Zampato, Stefano Mauro, Renato Galluzzi
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Patent number: 11859125Abstract: A method for inhibiting water permeation in an extraction well of a hydrocarbon fluid from an underground reservoir may include: supplying a water-in-oil emulsion including an oily continuous phase and an aqueous discontinuous phase containing a plurality of particles of at least one hydrogel containing a cationic polymer; and positioning the water-in-oil emulsion in contact with the underground reservoir. A treatment fluid for hydrocarbon fluid extraction wells may contain a water-in-oil emulsion including an oily continuous phase and an aqueous discontinuous phase containing a plurality of particles of at least one hydrogel containing a cationic polymer.Type: GrantFiled: March 19, 2020Date of Patent: January 2, 2024Assignee: ENI S.P.A.Inventors: Davide Moscatelli, Lucilla Del Gaudio, Paola Albonico, Alessandra Belloni, Alberto Cesana
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Patent number: 11856806Abstract: There is a disubstituted diaryloxybenzoheterodiazole compound having general formula (I): This disubstituted diaryloxybenzoheterodiazole compound having general formula (I) may advantageously be used as a spectrum converter in luminescent solar concentrators (“Luminescent Solar Concentrators”—LSCs) which, in turn, are capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on either a rigid or flexible support.Type: GrantFiled: October 18, 2019Date of Patent: December 26, 2023Assignee: ENI S.P.A.Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
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Patent number: 11851524Abstract: There is a benzodithiophene conjugated polymer of general formula (1): There are also photovoltaic devices having the polymer. There are also organic devices having the polymer.Type: GrantFiled: March 6, 2020Date of Patent: December 26, 2023Assignee: ENI S.P.A.Inventor: Gabriele Bianchi
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Patent number: 11852010Abstract: A method for estimating an anomalous pore pressure value at depth level of a first discontinuous interface between a first geological formation and a second geological formation to be drilled by means of a drilling apparatus comprising at least one bit, where said method is implemented by means of a system comprising at least one electro-acoustic transducer (20) mounted with said bit, at least one memory for containing observable data and at least one control processor for processing observable data contained in said at least one memory, where said at least one processor controls transmitting a signal transmitted at a given frequency, said at least one electro-acoustic transducer receives a received signal that said at least one processor records in said at least one memory, comparing it with pre-loaded observable data in said at least one memory and estimating the value of the anomalous pore pressure of the first discontinuous interface.Type: GrantFiled: September 13, 2019Date of Patent: December 26, 2023Assignee: ENI S.P.A.Inventors: Axel Turolla, Paolo Ferrara
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Patent number: 11845909Abstract: There is a method for extracting bio-oil from algal biomass, in particular oily microalgae, using solvents of a Deep Eutectic Solvents (DES) capable of producing a bio-oil with a low content of phospholipids and inorganic salts, mainly sodium chloride.Type: GrantFiled: September 9, 2019Date of Patent: December 19, 2023Assignee: ENI S.P.A.Inventors: Alberto Renato De Angelis, Filomena Castaldo
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Patent number: 11840678Abstract: There are mixtures containing calixarenes of formula (I) with a reduced alkyl phenol and linear oligomer content and a preparation process thereof: wherein: a. R is selected between a linear or branched alkyl having a number of carbon atoms comprised between 4 and 40, more preferably between 4 and 24, even more preferably comprised between 8 and 18; b. n is the number of units of the calixarene cycle and is comprised in the range from 4 to 16, preferably between 4 and 12. Furthermore, there are detergent compositions containing overbased metal salts of calixarenes, a preparation process thereof, and a use thereof in lubricant compositions.Type: GrantFiled: June 26, 2020Date of Patent: December 12, 2023Assignee: ENI S.P.A.Inventors: Marcello Notari, Giulio Assanelli, Alessandro Casnati, Francesco Sansone, Andrea Magini
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Publication number: 20230392064Abstract: A new class of multifunctional tracers has been synthesised for use in the oil industry, specifically during waterflooding operations. They are used either in a traditional way (i.e., mapping the connections of oilfield selections) or to provide information on important physical-chemical parameters (such as oil content, temperature and rock permeability) useful for optimizing the oilfield management and subsequent improvement/increase in oil extraction. The multifunctional tracers have a polymer chain having a plurality of units different from one another and recurring along the chain and having respective specific functionalities.Type: ApplicationFiled: October 21, 2021Publication date: December 7, 2023Applicant: ENI S.P.A.Inventors: Giuseppe MADDINELLI, Stefano CARMINATI, Davide MOSCATELLI, Matteo MARALDI
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Patent number: 11834394Abstract: A system having a catalytic partial oxidation (CPO) reactor operable to produce a CPO reactor effluent characterized by a hydrogen to carbon monoxide (H2/CO) molar ratio and an M ratio (H2—CO2)/(CO+CO2); a steam methane reforming (SMR) reactor operable to produce an SMR reactor effluent characterized by a H2/CO molar ratio greater than that of the CPO reactor effluent, and an M ratio greater than that of the CPO reactor effluent. The system includes a flow line(s) configured to combine at least a portion of the CPO reactor effluent with at least a portion of the SMR reactor effluent to provide a combined syngas stream upstream or downstream of a heat exchanger operable to transfer heat from at least a portion of the CPO reactor effluent, at least a portion of the SMR reactor effluent, or the combined syngas stream to the first portion and/or the second portion of hydrocarbons.Type: GrantFiled: February 6, 2020Date of Patent: December 5, 2023Assignee: ENI S.P.A.Inventors: Faisal Alahmadi, Marwan Alamro, Aspi Kolah
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Patent number: 11807645Abstract: Polymer comprising an indacen-4-one derivative, said polymer having general formula (IX), (X) or (XI): in which: W and W1, Z and Y, R1 and R2, are as described; D represents an electron-donor group; A represents an electron-acceptor group; n is an integer ranging from 10 to 500.Type: GrantFiled: August 10, 2020Date of Patent: November 7, 2023Assignee: Eni S.P.A.Inventors: Riccardo Po, Gabriele Bianchi
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Patent number: 11802639Abstract: Tubular structures for use in a subsea environment and a method of manufacturing the same are provided. These composite tubular structures can be used in the oil and gas industry, for example, as production risers.Type: GrantFiled: December 18, 2019Date of Patent: October 31, 2023Assignee: ENI S.P.A.Inventors: Stefano Carminati, Massimo Zampato, Mariangela Lombardi, Matteo Pavese
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Patent number: 11802715Abstract: The invention relates to a method for exchanging heat contained at a fluid. A gas which is heated indirectly and emits infrared radiation is used as the fluid, said fluid being guided to the heat exchanger via an inlet and through art absorber chamber in the heat exchanger, and at least one surface, which absorbs the infrared radiation of the gas in order to use the heat of the gas, is provided in the absorber chamber. The mass flow and the temperature of she gas are additionally adjusted and the at least one surface which is absorbent for the heat exchange is designed such that the ratio ? of the heat flowing through the surface as a result of absorption to the total heat flowing through the surface is ?0.6 during operation. Thus, a simpler and less expensive heat exchanger can be implemented.Type: GrantFiled: June 28, 2018Date of Patent: October 31, 2023Assignees: Synhelion SA, ENI S.P.A.Inventors: Gianluca Ambrosetti, Philipp Good
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Patent number: 11800728Abstract: Luminescent solar concentrator (L8C) of neutral coloration comprising: —at least one first sheet comprising a matrix of a transparent material and at least one first photoluminescent organic compound having an absorption interval within the range 400 nm to 550 nm, preferably within the range 420 nm to 500 mrs, and an emission interval within the range 500 nm to 650 nm, preferably within the range 520 mn to 620 nm; —at least one second sheet comprising a matrix of a transparent material and at least one second photoluminescent organic compound having an absorption interval within the range 420 nm to 650 nm, preferably within the range 480 nm to 600 nm, and an emission interval within the range 580 mn and 750 nm, preferably within the range 600 nm and 700 nm; —at least one third sheet comprising a matrix of a transparent material and at least one third, optionally photoluminescent, organic compound having an absorption interval within the range 550 nm to 750 nm, preferably within the range 570 nrn to 700 nm, anType: GrantFiled: April 17, 2019Date of Patent: October 24, 2023Assignee: ENI S.P.A.Inventors: Roberto Fusco, Liliana Gila, Luciano Caccianotti, Antonio Alfonso Proto
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Patent number: 11713314Abstract: A process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (XII): wherein: Z represents a sulfur atom, an oxygen atom, a selenium atom; or a group NR6 wherein R6 is selected from linear or branched C1-C20 alkyl groups, or from optionally substituted aryl groups; R2 and R3, identical or different, represent a hydrogen atom, provided that R1 does not represent a hydrogen atom; or R1, R2 and R3 are selected from linear or branched C1-C20 alkyl groups optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted, linear or branched C1-C20 alkoxy groups, optionally substituted phenoxy groups, or a cyano group; or R1 and R2, may optionally be bound together so as to form, together with carbon atoms to which R1 and R2 are bound, a saturated, unsaturated, or aromatic, cyclic or a polycyclic system containing from 3 to 14 carbon atoms, optionally containing one or more heteroatoms selectedType: GrantFiled: October 20, 2021Date of Patent: August 1, 2023Assignee: Eni S.P.A.Inventors: Giuliana Schimperna, Antonio Alfonso Proto
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Patent number: 11708539Abstract: There is an absorbent mixture usable for the removal of sour gases from gas mixtures. The mixture has at least one organic base having a pKb (in water) less than or equal to 3.2; at least one alcoholic solvent of general formula R(OH)n having a boiling temperature above or equal to 100° C. at ambient pressure, wherein R is a linear or branched saturated alkyl group having a number of carbon atoms between 2 and 20 and n is a whole number varying between 1 and 20; an aprotic polar solvent having a dielectric constant ? at 25° C. greater than or equal to 30, a viscosity ? at 25° C. less than or equal to 14 cP, preferably less than or equal to 12 cP; and a boiling temperature at normal pressure equal to or above 130° C. There is also a process for the removal of sour gases using the absorbent mixture.Type: GrantFiled: September 9, 2019Date of Patent: July 25, 2023Assignee: ENI S.P.A.Inventors: Alberto Renato De Angelis, Giuseppe Bellussi