Patents Assigned to ENI S.p.A.
  • Patent number: 10407628
    Abstract: A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.
    Type: Grant
    Filed: July 4, 2014
    Date of Patent: September 10, 2019
    Assignee: ENI S.p.A.
    Inventors: Giuseppe Bellussi, Vincenzo Piccolo, Alberto Maria Antonio Malandrino, Valentina Fabio, Giacomo Fernando Rispoli
  • Patent number: 10401254
    Abstract: A method and system for continuous remote monitoring of integrity of pressurized pipelines and properties of fluids transported, the method including: installing plural measurement stations along the pipeline, connected to vibroacoustic sensors configured to simultaneously and continuously measure elastic signals propagating in walls of the pipeline, and acoustic signals propagating in the transported fluid; synchronizing the signals measured from different measurement stations, with absolute time reference; continuously transmitting the measured and synchronized signals to a central unit configured to process them in a multichannel mode; calculating, by the central unit, plural transfer functions that can define vibroacoustic propagation in sections of pipeline between consecutive measurement stations; filtering relevant acoustic and elastic signals from the different measurement stations subtracting the contribution relating to the passive sources; creating an equivalent descriptive model of the system incl
    Type: Grant
    Filed: December 18, 2013
    Date of Patent: September 3, 2019
    Assignee: ENI S.p.A.
    Inventors: Giuseppe Giunta, Giancarlo Bernasconi
  • Patent number: 10388899
    Abstract: Inverted polymer solar cell comprising: an electron contact layer; a cathodic buffer layer; an active layer comprising at least one ?-conjugated polymer and at least one organic electron acceptor compound; an anodic buffer layer; a hole contact layer; wherein the cathodic buffer layer comprises zinc oxide and/or titanium dioxide and at least one interfacial agent selected from optionally substituted C7-C21 aromatic carboxylic acids or salts thereof. Such polymer solar cells have improved performance in terms of high charge mobility, high transparency, high efficiency and high chemical stability, which can be produced on a large industrial scale with a high surface area. A process for producing the same is also provided.
    Type: Grant
    Filed: November 4, 2014
    Date of Patent: August 20, 2019
    Assignee: ENI S.p.A.
    Inventors: Chiara Carbonera, Anna Calabrese, Marja Vilkman
  • Patent number: 10370607
    Abstract: A polymeric composition suitable for lowering the Pour Point of paraffinic crude oils comprising a synergic mixture including at least two ethylene-vinyl acetate copolymers respectively having an average molecular weight Mw lower than 130,000 Dalton (measured via GPC), a content of vinyl acetate monomer ranging from 15 to 50% by weight, with the proviso that the content of vinyl acetate monomer in the respective copolymers differs from one copolymer to another, by over 5%, on a weight basis.
    Type: Grant
    Filed: December 5, 2014
    Date of Patent: August 6, 2019
    Assignees: versalis S.p.A., ENI S.p.A.
    Inventors: Paolo Mariani, Michela Agnoli, Alessandro Casalini, Massimo Merlini
  • Publication number: 20190234160
    Abstract: The present invention relates to a device and a method for the implementation of a flexible tubular structure made of reformable composite material, designed for passing from a first folded configuration to a second longitudinally developed operating configuration using a tapered profile slidingly engageable inside the tubular structure.
    Type: Application
    Filed: July 13, 2017
    Publication date: August 1, 2019
    Applicant: ENI S.p.A.
    Inventors: Stefano CARMINATI, Domenico Antonio DI RENZO, Mauro FAVARETTO, Massimo ZAMPATO
  • Publication number: 20190226329
    Abstract: System for cableless bidirectional data transmission in a well (10) for the extraction of formation fluids comprising: a plurality of rods (11, 12) connected to each other in succession so as to form a rod string, which extends from the surface to the bottom of the well (10), the rod string being associable with a plurality of sensors (14) configured for continuously detecting a plurality of parameters relating to the fluids circulating in the well (10) and to the rock formation surrounding the well and/or to safety devices or other remote-controlled well instrumentation; a plurality of communication modules (20) applied at predefined distances along the rod string and configured for the transmission of signals from and towards the bottom of the well (10); each of the communication modules (20) comprising: at least one metal plate selected from: a transmitting metal plate (21); a receiving metal plate (22); a transceiver metal plate (35); an electronic processing and control unit (23) configured for processin
    Type: Application
    Filed: July 14, 2017
    Publication date: July 25, 2019
    Applicant: ENI S.p.A.
    Inventors: Sebastiano BURRAFATO, Alessandro PULITI, Claudio MOLASCHI, Mauro FAVARETTO
  • Patent number: 10336965
    Abstract: Process for the extraction of lipids and sugars from algal biomass, which comprises: —producing an aqueous suspension of algal biomass; —bringing the pH of said aqueous suspension of algal biomass to a value higher than or equal to 10, preferably ranging from 10.2 to 12, obtaining an aqueous suspension of algal biomass at basic pH; —adding at least one anionic flocculant to said aqueous suspension of algal biomass at basic pH obtaining a concentrated algal biomass; —recovering said concentrated algal biomass; —subjecting said concentrated algal biomass to extraction of the lipids obtaining: (i) an organic phase comprising lipids; (ii) a semi-solid phase comprising a residue of said algal biomass; —subjecting said semi-solid phase (ii) to hydrolysis obtaining sugars. The lipids thus obtained can be advantageously used in the production of biodiesel or green diesel which can be used as such, or in a mixture with other fuels for motor vehicles.
    Type: Grant
    Filed: November 18, 2014
    Date of Patent: July 2, 2019
    Assignee: ENI S.p.A.
    Inventors: Felicia Massetti, Federico Capuano, Roberto Medici, Roberta Miglio
  • Patent number: 10330525
    Abstract: A vibration measurement system and relative method to monitor multiphase flows in extraction wells or conduits, by analysis of backscattered multimode fiber light comprising: • a sensing multimode optical fiber; • an optical source, containing a high coherence laser that emits optical pulses to be sent in said sensing fiber; • a photonic lantern with 3 or more single-mode optical fiber ports and one multimode fiber port that is connected to the sensing multimode fiber; • an optical receiver, comprising a number of photodetectors equal to the number of the single-mode optical fiber ports of said photonic lantern minus 1, wherein each photodetector is connected to each of said single-mode ports; • a system for processing output signals from the optical receiver, the optical source being connected to one of the single-mode optical fiber ports and the other single-mode fibers being connected to the optical receiver.
    Type: Grant
    Filed: December 23, 2015
    Date of Patent: June 25, 2019
    Assignee: Eni S.p.A.
    Inventors: Andrea Galtarossa, Luca Palmieri, Massimo Zampato
  • Patent number: 10316258
    Abstract: A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and ¾S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: June 11, 2019
    Assignee: ENI S.P.A.
    Inventors: Giacomo Rispoli, Giuseppe Bellussi
  • Patent number: 10312395
    Abstract: Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoheterodiazole compound of general formula (I), in which: —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group in which R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, which are the same or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxyl groups, optionally substituted phenoxyl groups, or —COOR7 groups or —OCOR7 groups in which R7 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or is a cyano group, provided that when the substituents R1 represents a hydrogen atom, at least one of the substituents R2 and R3 represents an optionally substi
    Type: Grant
    Filed: September 24, 2015
    Date of Patent: June 4, 2019
    Assignee: Eni S.p.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
  • Publication number: 20190161778
    Abstract: The present invention concerns an oleaginous yeast variant of the species Rhodosporidium azoricum characterized by higher biomass yields and intra-cellular lipid accumulation useful for the production of bio-fuels higher, in determined conditions, with respect to the wild type strain of the same species. Furthermore, the invention concerns a method through which said oleaginous yeast variant of the species Rhodosporidium azoricum was obtained. The invention further concerns the lipid production by means of said variant strain of oleaginous yeast of the species Rhodosporidium azoricum.
    Type: Application
    Filed: January 30, 2019
    Publication date: May 30, 2019
    Applicant: ENI S.p.A.
    Inventors: Giuliana Franzosi, Daniela Cucchetti, Daniele Bianchi, Silvia Galafassi, Concetta Compagno
  • Patent number: 10301656
    Abstract: The present invention concerns an oleaginous yeast variant of the species Rhodosporidium azoricum characterized by higher biomass yields and intra-cellular lipid accumulation useful for the production of bio-fuels higher, in determined conditions, with respect to the wild type strain of the same species. Furthermore, the invention concerns a method through which said oleaginous yeast variant of the species Rhodosporidium azoricum was obtained. The invention further concerns the lipid production by means of said variant strain of oleaginous yeast of the species Rhodosporidium azoricum.
    Type: Grant
    Filed: December 29, 2015
    Date of Patent: May 28, 2019
    Assignee: ENI S.p.A.
    Inventors: Giuliana Franzosi, Daniela Cucchetti, Daniele Bianchi, Silvia Galafassi, Concetta Compagno
  • Publication number: 20190114552
    Abstract: Simulation method (100) for simulating the thermo-fluid dynamic behavior of multiphase fluids in a hydrocarbons production and transport system, said method comprising the following steps: outlining (110) the hydrocarbons production and transport system as a plurality of interconnected component blocks, thus creating a schematic representation; modeling (120) each component block with a simplified analytical mathematical model selected from the group of models comprising at least one conduit model, a valve model, a reservoir model and a separator model, each simplified analytical mathematical model comprising a plurality of constitutive equations adapted to describe the thermo-fluid dynamic behavior of the corresponding component block; generating (130) an oriented graph on the basis of the schematic representation; determining (140) a plurality of topological equations on the basis of the oriented graph; determining (150) a plurality of output variables adapted to describe the thermo-fluid dynamic behavior o
    Type: Application
    Filed: April 3, 2017
    Publication date: April 18, 2019
    Applicant: ENI S.p.A.
    Inventors: Alberto Giulio DI LULLO, Axel TUROLLA, Massimo ZAMPATO
  • Patent number: 10208950
    Abstract: The present invention relates to reaction equipment for the treatment of organic and/or inorganic waste of refineries or petrochemical plants comprising: •—a drying and pyrolysis device (4) which rotates around its longitudinal, tilted rotation axis (A), •—a gasification device (6) which rotates around its longitudinal, horizontal rotation axis (B), •—a combustion device (14) comprising a burner (13) having a longitudinal horizontal axis (C), •—at least one settling chamber (15) for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products, •—at least one outlet duct of the gaseous end-products (16), at least one outlet duct of the solid end-products (7), and at least one inlet duct of the feedstock (2) •—said combustion device (14), drying and pyrolysis device (4), gasification device (6) are physically separated and positioned on three different levels, •—the longitudinal rotation axis (A) of the drying and pyrolysis device (4) is tilted with respect to bot
    Type: Grant
    Filed: October 2, 2014
    Date of Patent: February 19, 2019
    Assignee: ENI S.p.A.
    Inventors: Felicia Massetti, Maria Ilaria Pistelli, Medardo Pinti
  • Patent number: 10132823
    Abstract: A method and system are described for the continuous remote monitoring of the position and advance speed of a pig device inside a pipeline suitable for transporting a pressurized fluid, wherein the pipeline consists of a plurality of pipe sections joined to each other by welding.
    Type: Grant
    Filed: May 14, 2015
    Date of Patent: November 20, 2018
    Assignee: ENI S.p.A.
    Inventors: Giuseppe Giunta, Giancarlo Bernasconi, Silvio Del Giudice
  • Patent number: 10125322
    Abstract: The invention relates to a method for revamping a conventional refinery of mineral oils into a biorefinery, characterized by a production scheme which allows the treatment of raw materials of a biological origin (vegetable oils, animal fats, exhausted cooking oils) for the production of biofuels, prevalently high-quality biodiesel.
    Type: Grant
    Filed: November 28, 2017
    Date of Patent: November 13, 2018
    Assignee: ENI S.p.A.
    Inventors: Giacomo Fernando Rispoli, Claudia Prati, Andrea Amoroso, Paolo Pollesel
  • Patent number: 10087163
    Abstract: The present invention relates to a process for preparing cyclic acetals having general formula (I) wherein Y and Y?, equal to or different from each other, are selected from H and a group OR, R being a linear or branched alkyl containing from 1 to 8 carbon atoms, comprising at least the following phases: (i) providing a reaction mixture comprising at least one vicinal diol having formula (II) Z—CH2—CHOH—CH2OH wherein Z is selected from H and a group OR?, R? being a linear or branched alkyl containing from 1 to 8 carbon atoms, said mixture being substantially free of aldehydes having general formula RI—CHO, wherein RI is a linear or branched alkyl containing from 1 to 6 carbon atoms, possibly substituted by an alkoxide group OR111, wherein RIII is an alkyl containing from 1 to 4 carbon atoms; (ii) thermally treating said reaction mixture at a temperature within the range of 100° C.-300° C. in the presence of at least one acid catalyst, obtaining said compound having formula (I).
    Type: Grant
    Filed: April 3, 2015
    Date of Patent: October 2, 2018
    Assignee: ENI S.p.A.
    Inventors: Giulio Assanelli, Alberto Renato De Angelis
  • Publication number: 20180273856
    Abstract: The present invention relates to a process for the treatment of refinery purge streams, containing a hydrocarbon component in slurry phase having a boiling point higher than or equal to 140° C., characterized by the presence of quantities of asphaltenes higher than or equal to 5% by weight and characterized by the presence of a solid content higher than or equal to 5% by weight. The process provides that said purge be mixed with a suitable fluxing agent according to appropriate ratios and under certain conditions, forming a suspension with a content higher than or equal to 10% by weight of compounds having a boiling point TbP lower than or equal to 350° C. After mixing, the suspension is sent to a liquid/solid separation step which operates under suitable conditions, separating a solid phase containing a residual organic component and a solid component, called cake, and a liquid phase containing residual solids. The solid phase obtained is cooled to below 60° C.
    Type: Application
    Filed: December 21, 2016
    Publication date: September 27, 2018
    Applicant: ENI S.p.A.
    Inventor: Andrea BARTOLINI
  • Publication number: 20180223248
    Abstract: A method for concentrating, in order to favour the subsequent extraction process of intracellular lipids, a cell suspension containing a biomass of oleaginous yeasts fermented in fermentation broth under conditions that allow the intracellular accumulation of lipids, where the biomass contains significant quantities of mucilaginous material. The method includes: a) cultivating the oleaginous yeasts in a fermentation broth to obtain a cell suspension containing the mucilaginous biomass; b) subjecting the cell suspension obtained from a) to heat treatment, at a temperature between 95° C. and 120° C. and to acid treatment, to obtain a treated cell suspension containing the mucilaginous biomass containing intact oleaginous yeast cells; and c) concentrating the treated cell suspension obtained from b), by removing at least part of the fermentation broth to obtain a concentrated cell suspension.
    Type: Application
    Filed: August 5, 2016
    Publication date: August 9, 2018
    Applicant: ENI S.p.A.
    Inventors: Rossella BORTOLO, Daniele BIANCHI
  • Patent number: 10011776
    Abstract: A multi-structured tubular element for producing a reactor for effecting exothermic/endothermic chemical reactions, comprises two or more monolithic thermoconductive bodies, assembled together so that each has a part of the side surface interfaced with the side surface of one or more monolithic thermoconductive bodies adjacent thereto, so as to form as a whole, a honeycomb structure containing a plurality of longitudinal channels extending from one end to the other of said tubular element, suitable for being filled with a granular catalytic solid.
    Type: Grant
    Filed: December 27, 2013
    Date of Patent: July 3, 2018
    Assignee: Eni S.p.A.
    Inventors: Marco Paturzo, Mauro Favaretto, Marzio Piazza, Pio Forzatti, Gianpiero Groppi, Luca Lietti, Enrico Tronconi, Carlo Giorgio Visconti