Abstract: The invention relates to an integrated process for the production of fuel components starting from materials of a biological origin which comprises: (A) transformation of glycerine into an alkoxy-propanediol having formula RO—CH2—CHOH—CH2OH, wherein R is a linear or branched C1-C8 alkyl, (B) transformation of glycerine into 1,2-propanediol CH3—CHOH—CH2OH, (C) dehydration of the 1,2-propanediol obtained in (B) to propionic aldehyde, (D) reaction of part of the propionic aldehyde obtained in (C) with the alkoxy-propanediol having formula RO—CH2—CHOH—CH2OH obtained in (A) to give an acetal having formula (a) wherein R is a linear or branched C1-C8 alkyl, (E) transformation of part of the propionic aldehyde obtained in (C) to a propionate having formula CH3—CH2—COOR?, wherein R? is a linear or branched C1-C8 alkyl. Particular components for gasolines and/or diesel are also described.
Type:
Grant
Filed:
February 11, 2014
Date of Patent:
March 17, 2020
Assignee:
ENI S.p.A.
Inventors:
Giuseppe Bellussi, Alberto Renato De Angelis, Giulio Assanelli, Paolo Pollesel
Abstract: Hydrogenated polymers with a radial structure having a core made up of calixarenes of the general formula (I), to the core of which is linked a number P of hydrogenated linear polymer segments selected from: —hydrogenated homopolymers or copolymers of conjugated dienes; or —hydrogenated copolymers of said conjugated dienes and monoalkenyl arenes, and —mixtures thereof said formula (I) in which: —R1, R2, R3 and R4 are independently selected from hydrogen; a group containing carbon and hydrogen; a group also containing heteroatoms in addition to carbon and hydrogen; a group also containing silicon in addition to carbon, hydrogen and heteroatoms; —one of the two substituents R5 and R6 is hydrogen, while the other may be hydrogen or alkyl, with a number of carbon atoms between 1 and 6, preferably methyl and ethyl; —n is an integer in the range between 4 and 16.
Type:
Grant
Filed:
April 16, 2015
Date of Patent:
March 10, 2020
Assignees:
Eni S.P.A., Versalis S.P.A.
Inventors:
Marcello Notari, Claudio Cavallo, Alberto Roselli, Alessandro Casnati, Francesco Sansone, Alessandro Burlini
Abstract: A pipe for cableless bidirectional data transmission and continuous circulation of a stabilizing fluid in a well for the extraction of formation fluids includes a hollow tubular body which couples with respective drill or completion pipes; a radial valve associated with the tubular body, the radial valve connectable to a pumping system outside the tubular body; an axial valve associated with the tubular body; a communication module associated with the tubular body that includes at least one metal plate selected from a transmitting metal plate, a receiving metal plate, and a transceiver metal plate; an electronic processing and control unit that processes signals to be transmitted by means of the at least one metal plate or signals received by means of the at least one metal plate; and one or more supply batteries for feeding the metal plates and the electronic processing and control unit.
Type:
Application
Filed:
October 20, 2017
Publication date:
February 20, 2020
Applicant:
ENI S.p.A.
Inventors:
Sebastiano BURRAFATO, Alberto MALIARDI, Axel TUROLLA
Abstract: A micellar compositions including oil-soluble surfactants delivered by water-soluble surfactants are disclosed. The micellar compositions demonstrate enhanced crude oil mobilization in porous media. When the porous media was imbued with crude oil, the presence of the surfactant in the oil phase improved the mobilization performance of crude oil. Solutions of SDS were used to solubilize the surfactant, and the formation of SDS/PIBSI micellar composition was confirmed by Cryo-SEM images. High cleaning effectiveness of the micellar compositions on crude oil entrapped in porous media was demonstrated by image binarization.
Type:
Application
Filed:
October 6, 2017
Publication date:
February 6, 2020
Applicants:
THE ADMINISTRATORS OF THE TULANE EDUCATIONAL FUND, ENI S.p.A.
Abstract: A safety valve for extraction wells, configured to be installed on a well head and to enclose a tubular material portion inserted inside the well. The tubular material is internally hollow to contain and transport substances extracted from the well. The safety valve includes: a central hole through which the tubular material passes; a blocking system configured to keep the tubular material to be cut fixed with respect to the safety valve; a cutting and closing group configured to cut and close the well under certain operative conditions; and a sealing mechanism configured to effect watertight closing of the well, after the cutting. The cutting and closing group includes a hole saw housed in a respective chamber of the cutting and closing group, rotated by a motorized actuator, and configured to move in a controlled mode along a substantially orthogonal direction with respect to a development direction of the well.
Type:
Grant
Filed:
October 19, 2015
Date of Patent:
December 31, 2019
Assignee:
ENI S.p.A.
Inventors:
Paolo Ferrara, Giuseppe De Grandis, Andrea Biondi
Abstract: System and corresponding process for the hydroconversion of heavy oils essentially comprising a reactor, a liquid-vapor separator and a section for stripping conversion products outside the reactor comprising an inlet conduit for the stripping gases located at a point on the conduit providing a connection between the head of the reactor and the liquid-vapor separator inclined, at least from the point of entry, upwards with a gradient of between 2% and 20%, preferably between 3% and 12%, with respect to a horizontal plane. The inlet conduit for the stripping gases is inclined with respect to the axis of the conduit providing a connection between the reactor head and the liquid-vapor separator through an angle of between 20° and 65°, more preferably between 30° and 60°, even more preferably between 40° and 50°. The stripping gas delivered to the connection conduit between the head of the reactor and the separator flows in a downward direction.
Type:
Grant
Filed:
December 23, 2015
Date of Patent:
November 19, 2019
Assignee:
Eni S.p.A.
Inventors:
Mario Molinari, Alberto Maria Malandrino, Susi Bonomi
Abstract: An organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one ?-conjugated unit is described. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC).
Type:
Grant
Filed:
November 14, 2014
Date of Patent:
November 5, 2019
Assignees:
ENI S.p.A., CNRS (CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE)
Inventors:
Paolo Biagini, Riccardo Po', Jean Roncali, Dora Demeter
Abstract: A process for the treatment of water contaminated by polar and/or apolar organic compounds, and/or by heavy metal salts, and/or by oil dispersed or in emulsion, comprises sending said contaminated water to a system comprising: at least one adsorption (3) unit including at least one microporous or mesoporous alumina-silicate; at least one nanofiltration unit (7) including at least one hydrophilic nanofiltration membrane; wherein said hydrophilic nanofiltration membrane has a contact angle with water lower than or equal to 45°, preferably ranging from 25° to 40°.
Type:
Grant
Filed:
November 3, 2011
Date of Patent:
October 15, 2019
Assignee:
ENI S.P.A.
Inventors:
Roberto Bagatin, Rodolfo Vignola, Raffaello Sisto, Marco Petrangeli Papini, Riccardo Tuffi, Alessandra De Folley D'Auris
Abstract: It is described a method for detecting and identifying obstructions in a pipeline network for transporting fluids, wherein the network is composed of a plurality of pipeline sections (P) and a plurality of junctions (N). The method comprising the following phases: acquiring the geometrical data of a predefined number of pipeline sections (P) for which the presence of obstructions has to be evaluated; measuring the actual flow-rate values (Q1) of the fluid in one or more pipeline sections (P) and of the actual pressure values (h1) of the fluid at one or more junctions (N) of the network; comparison between the values of the nominal diameters (D1) of said pipeline sections (P) and the corresponding equivalent diameters (Dieq) of said pipeline sections (P); calculating, by means of a specific numerical model, the theoretic flow-rate values (QiT) and pressure values (hiT) of the fluid for said equivalent diameters (Dieq).
Type:
Grant
Filed:
May 14, 2013
Date of Patent:
September 17, 2019
Assignee:
ENI S.p.A.
Inventors:
Tommaso Mantegazza, Alberto Giulio Di Lullo, Paolo Bocchini, Alessandro Marzani
Abstract: A process for the refining of crude oil with at least one atmospheric distillation unit for separating the various fractions, a sub-atmospheric distillation unit, a conversion unit of the heavy fractions obtained, a unit for enhancing the quality of some of the fractions obtained by actions on the chemical composition of their constituents and a unit for the removal of undesired components, where the sub-atmospheric distillation residue is sent to one of the conversion units, the conversion unit includes at least one hydroconversion reactor in slurry phase, into which hydrogen or a mixture of hydrogen and H2S, is fed, in the presence of a suitable dispersed hydrogenation catalyst with dimensions ranging from 1 nanometer to 30 microns.
Type:
Grant
Filed:
July 4, 2014
Date of Patent:
September 10, 2019
Assignee:
ENI S.p.A.
Inventors:
Giuseppe Bellussi, Vincenzo Piccolo, Alberto Maria Antonio Malandrino, Valentina Fabio, Giacomo Fernando Rispoli
Abstract: A method and system for continuous remote monitoring of integrity of pressurized pipelines and properties of fluids transported, the method including: installing plural measurement stations along the pipeline, connected to vibroacoustic sensors configured to simultaneously and continuously measure elastic signals propagating in walls of the pipeline, and acoustic signals propagating in the transported fluid; synchronizing the signals measured from different measurement stations, with absolute time reference; continuously transmitting the measured and synchronized signals to a central unit configured to process them in a multichannel mode; calculating, by the central unit, plural transfer functions that can define vibroacoustic propagation in sections of pipeline between consecutive measurement stations; filtering relevant acoustic and elastic signals from the different measurement stations subtracting the contribution relating to the passive sources; creating an equivalent descriptive model of the system incl
Abstract: Inverted polymer solar cell comprising: an electron contact layer; a cathodic buffer layer; an active layer comprising at least one ?-conjugated polymer and at least one organic electron acceptor compound; an anodic buffer layer; a hole contact layer; wherein the cathodic buffer layer comprises zinc oxide and/or titanium dioxide and at least one interfacial agent selected from optionally substituted C7-C21 aromatic carboxylic acids or salts thereof. Such polymer solar cells have improved performance in terms of high charge mobility, high transparency, high efficiency and high chemical stability, which can be produced on a large industrial scale with a high surface area. A process for producing the same is also provided.
Type:
Grant
Filed:
November 4, 2014
Date of Patent:
August 20, 2019
Assignee:
ENI S.p.A.
Inventors:
Chiara Carbonera, Anna Calabrese, Marja Vilkman
Abstract: A polymeric composition suitable for lowering the Pour Point of paraffinic crude oils comprising a synergic mixture including at least two ethylene-vinyl acetate copolymers respectively having an average molecular weight Mw lower than 130,000 Dalton (measured via GPC), a content of vinyl acetate monomer ranging from 15 to 50% by weight, with the proviso that the content of vinyl acetate monomer in the respective copolymers differs from one copolymer to another, by over 5%, on a weight basis.
Type:
Grant
Filed:
December 5, 2014
Date of Patent:
August 6, 2019
Assignees:
versalis S.p.A., ENI S.p.A.
Inventors:
Paolo Mariani, Michela Agnoli, Alessandro Casalini, Massimo Merlini
Abstract: The present invention relates to a device and a method for the implementation of a flexible tubular structure made of reformable composite material, designed for passing from a first folded configuration to a second longitudinally developed operating configuration using a tapered profile slidingly engageable inside the tubular structure.
Type:
Application
Filed:
July 13, 2017
Publication date:
August 1, 2019
Applicant:
ENI S.p.A.
Inventors:
Stefano CARMINATI, Domenico Antonio DI RENZO, Mauro FAVARETTO, Massimo ZAMPATO
Abstract: System for cableless bidirectional data transmission in a well (10) for the extraction of formation fluids comprising: a plurality of rods (11, 12) connected to each other in succession so as to form a rod string, which extends from the surface to the bottom of the well (10), the rod string being associable with a plurality of sensors (14) configured for continuously detecting a plurality of parameters relating to the fluids circulating in the well (10) and to the rock formation surrounding the well and/or to safety devices or other remote-controlled well instrumentation; a plurality of communication modules (20) applied at predefined distances along the rod string and configured for the transmission of signals from and towards the bottom of the well (10); each of the communication modules (20) comprising: at least one metal plate selected from: a transmitting metal plate (21); a receiving metal plate (22); a transceiver metal plate (35); an electronic processing and control unit (23) configured for processin
Abstract: Process for the extraction of lipids and sugars from algal biomass, which comprises: —producing an aqueous suspension of algal biomass; —bringing the pH of said aqueous suspension of algal biomass to a value higher than or equal to 10, preferably ranging from 10.2 to 12, obtaining an aqueous suspension of algal biomass at basic pH; —adding at least one anionic flocculant to said aqueous suspension of algal biomass at basic pH obtaining a concentrated algal biomass; —recovering said concentrated algal biomass; —subjecting said concentrated algal biomass to extraction of the lipids obtaining: (i) an organic phase comprising lipids; (ii) a semi-solid phase comprising a residue of said algal biomass; —subjecting said semi-solid phase (ii) to hydrolysis obtaining sugars. The lipids thus obtained can be advantageously used in the production of biodiesel or green diesel which can be used as such, or in a mixture with other fuels for motor vehicles.
Type:
Grant
Filed:
November 18, 2014
Date of Patent:
July 2, 2019
Assignee:
ENI S.p.A.
Inventors:
Felicia Massetti, Federico Capuano, Roberto Medici, Roberta Miglio
Abstract: A vibration measurement system and relative method to monitor multiphase flows in extraction wells or conduits, by analysis of backscattered multimode fiber light comprising: • a sensing multimode optical fiber; • an optical source, containing a high coherence laser that emits optical pulses to be sent in said sensing fiber; • a photonic lantern with 3 or more single-mode optical fiber ports and one multimode fiber port that is connected to the sensing multimode fiber; • an optical receiver, comprising a number of photodetectors equal to the number of the single-mode optical fiber ports of said photonic lantern minus 1, wherein each photodetector is connected to each of said single-mode ports; • a system for processing output signals from the optical receiver, the optical source being connected to one of the single-mode optical fiber ports and the other single-mode fibers being connected to the optical receiver.
Type:
Grant
Filed:
December 23, 2015
Date of Patent:
June 25, 2019
Assignee:
Eni S.p.A.
Inventors:
Andrea Galtarossa, Luca Palmieri, Massimo Zampato
Abstract: A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and ¾S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst.
Abstract: Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoheterodiazole compound of general formula (I), in which: —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group in which R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, which are the same or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxyl groups, optionally substituted phenoxyl groups, or —COOR7 groups or —OCOR7 groups in which R7 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or is a cyano group, provided that when the substituents R1 represents a hydrogen atom, at least one of the substituents R2 and R3 represents an optionally substi
Type:
Grant
Filed:
September 24, 2015
Date of Patent:
June 4, 2019
Assignee:
Eni S.p.A.
Inventors:
Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila