Abstract: Direct catalytic process for the production of hydroxylamine by means of the oxidation of ammonia with H.sub.2 O.sub.2, wherein the catalyst is composed of silicon, titanium and oxygen and has a crystalline (as in the case of titanium-silicalites, for example) or amorphous structure.
Type:
Grant
Filed:
July 2, 1992
Date of Patent:
June 14, 1994
Assignee:
Enichem Anic S.r.l.
Inventors:
Maria A. Mantegazza, Mario Padovan, Guido Petrini, Paolo Roffia
Abstract: Two-step process in the liquid phase for producing oximes at 60.degree.-100.degree. C. and 1.5-5 bars, which comprises:(a) in a primary step, ammoximating a carbonylic compound with H.sub.2 O.sub.2 and NH.sub.3 in the presence of a silicon, titanium and oxygen based catalyst;(b) oximating the residual carbonylic compound with a solution of hydroxylamine, obtained in its turn by oxidizing ammonia with H.sub.2 O.sub.2, having a concentration comprised within the range of from 0.01 to 3%, preferably of from 0.5 to 2% by weight, in such a way as to have a molar ratio of hydroxylamine to the carbonylic compound comprised within the range of from 0.9 to 3, preferably of from 1 to 2.
Type:
Grant
Filed:
March 30, 1993
Date of Patent:
May 17, 1994
Assignee:
Enichem Anic S.r.l.
Inventors:
Maria A. Mantegazza, Guido Petrini, Alberto Cesana
Abstract: A procedure is described for the preparation of colorless hydrocarbon resins having a higher thermal stability than similar products in the known art. The procedure involves the treatment of polymeric mixtures deriving from the (co)polymerization by means of Friedel-Crafts catalysts of hydrocarbons or mixtures of ethylenically unsaturated hydrocarbons, with an organometallic compound of Magnesium and/or Lithium, the separation of the inorganic residues and the final removal of the volatile organic products.
Type:
Grant
Filed:
February 11, 1992
Date of Patent:
March 15, 1994
Assignee:
Enichem Anic S.R.L.
Inventors:
Ambrogio Magni, Attilio Sioli, Claudia Andena, Mario Ponzinibbi
Abstract: A selective procedure is described for the removal of catalytic residues based on AlCl.sub.3 or its complex compounds deriving from the (co) polymerization of olefinic and diolefinic cuts, allowing the production of almost colourless hydrocarbon resins. This procedure involves putting the polymerized mass in contact with organometallic compounds, treating the resulting mixture with water or aqueous solutions, either acidic or basic, and separating the organic phase, which at this point is without inorganic residues.
Type:
Grant
Filed:
March 23, 1992
Date of Patent:
December 14, 1993
Assignee:
Enichem Anic S.R.L.
Inventors:
Ambrogio Magni, Attilio Sioli, Claudia Andena, Mario Ponzinibbi
Abstract: A multistep process for the liquid phase ammoximation of carbonyl compounds with H.sub.2 O.sub.2 and NH.sub.3, at 60.degree.-100.degree. C., at 1.5-5 bar and in the presence of a catalyst based on silicon, titanium and oxygen, characterized in that:a) in one or more primary steps, the H.sub.2 O.sub.2 : carbonyl compound molar ratio ranges from 0.9 to 1.15 by mols and the carbonyl component conversion is carried out up to at least 95%;b) in a last (exhaustion) step the H.sub.2 O.sub.2 : carbonyl compound ratio is in a higher range, i.e. from 1.5 to 3.0 by mols.
Type:
Grant
Filed:
January 21, 1992
Date of Patent:
July 13, 1993
Assignee:
Enichem Anic s.r.l.
Inventors:
Sergio Tonti, Paolo Roffia, Vittorio Gervasutti