Patents Assigned to Enitecnologie S.p.A.
  • Patent number: 8262385
    Abstract: A description follows of an aqueous dispersion of heavy oil residues, suitable for undergoing combustion with a low emission of SOx, comprising: (a) a heavy oil residue; (b) a dispersing agent; (c) a desulfurizing agent selected from CaCO3, MgCO3, dolomite and relative mixtures; (d) a desulfurizing agent with stabilizing and anti-corrosive properties selected from MgO, Mg(OH)2, CaO, Ca(OH)2 and relative mixtures; (e) water; the weight percentage of (e) with respect of the sum of (a)+(e) being at least 15%.
    Type: Grant
    Filed: February 22, 2002
    Date of Patent: September 11, 2012
    Assignee: Enitecnologie S.p.A.
    Inventors: Armando Marcotullio, Riccardo Rausa, Alessandro Lezzi
  • Patent number: 8236171
    Abstract: A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, selected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: August 7, 2012
    Assignees: ENI S.p.A, Enitecnologie S.p.A.
    Inventors: Roberto Giardino, Vincenzo Calemma, Ugo Cornaro
  • Patent number: 8017000
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), and deasphalting (SDA).
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: September 13, 2011
    Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Nicoletta Panariti, Alberto Delbianco, Sergio Rosi
  • Patent number: 7820727
    Abstract: Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: October 26, 2010
    Assignees: ENI S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Cristina Maretto, Giovanni Pederzani
  • Publication number: 20100219104
    Abstract: The present invention relates to an integrated process for the conversion of feedstocks containing coal into liquid products by jointly using at least the following seven process units: coal liquefaction, flash or distillation of the product obtained from the liquefaction, extraction with a solvent to remove the ashes, distillation to separate the solvent, hydroconversion with catalysts in slurry phase, distillation or flash of the production obtained from the hydroconversion, and deasphalting with a solvent.
    Type: Application
    Filed: March 1, 2010
    Publication date: September 2, 2010
    Applicants: ENI S.p.A., SNAMPROGETTI S.p.A, ENITECNOLOGIE S.p.A
    Inventors: Alberto Del Bianco, Romolo Montanari, Nicoletta Panariti, Sergio Rosi
  • Patent number: 7754637
    Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VI B and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: July 13, 2010
    Assignees: AGIP Petroli S.p.A., Enitecnologie S.p.A.
    Inventors: Laura Zanibelli, Marco Ferrari, Virginio Arrigoni
  • Patent number: 7712489
    Abstract: A storage tank that stores sulphur with zero emissions uses reinforced EPS panels and an impermeable bottom. The reinforced EPS panels are reinforced with networks of horizontal and/or vertical galvanized or stainless steel wires that are interconnected by galvanized or stainless steel orthogonal wires. Both inner and outer walls of the reinforced EPS panels are plastered before sulphur is placed in the storage tank. Larger storage tanks may be assembled by vertically interconnecting one or more reinforced EPS panels. This interconnection is achieved by corrugating the reinforced EPS panels, or forming their edges in a Greek-key shape. The Greek-key shape prevents sulphur from escaping the storage tank.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: May 11, 2010
    Assignees: ENI S.p.A., Snamprogetti S.p.A., Enitecnologie S.p.A.
    Inventors: Leonardo Zan, Francesco Crescenzi
  • Patent number: 7691256
    Abstract: Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from the
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: April 6, 2010
    Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
  • Patent number: 7588527
    Abstract: Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H2Sn+1, wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150° C.
    Type: Grant
    Filed: July 6, 2004
    Date of Patent: September 15, 2009
    Assignees: ENI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Alberto De Angelis, Paolo Pollesel, Giuseppe Bellussi, Thomas Paul Lockhart
  • Patent number: 7585460
    Abstract: The invention relates to a method for inhibiting the biological acidification of water which is in contact with materials containing sulfur in reduced form or with elemental sulfur, susceptible to oxidation on the part of Thiobacilli, comprising putting said materials in contact with soluble inorganic salts at concentrations ranging from 0.4 normal to saturation.
    Type: Grant
    Filed: April 26, 2004
    Date of Patent: September 8, 2009
    Assignees: ENI S.p.A., Enitecnologie S.p.A.
    Inventors: Francesco Crescenzi, Antonella Crisari, Cesare Achille Piatti
  • Patent number: 7579382
    Abstract: Process for the charging of a catalyst and for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
    Type: Grant
    Filed: September 17, 2004
    Date of Patent: August 25, 2009
    Assignees: ENI S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Cristina Maretto, Giovanni Pederzani
  • Publication number: 20090197980
    Abstract: Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
    Type: Application
    Filed: February 13, 2009
    Publication date: August 6, 2009
    Applicants: ENI S.P.A., INSTITUT FRANCAIS DU PETROLE, ENITECNOLOGIE S.p.A.
    Inventors: Cristina Maretto, Giovanni Pederzani
  • Patent number: 7560408
    Abstract: Amorphous porous solid of an acidic nature, with a controlled pore size, essentially consisting of a mixed oxide of silicon, aluminum and phosphorous, having a surface area of at least 200 m2/g, which can be used as a catalyst or active carrier of a catalyst for various industrial processes, such as, for example, alkylation, isomerization, hydro-dehydrogenation processes, with an improved activity and selectivity with respect to the traditional amorphous silica-alumina gels.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: July 14, 2009
    Assignees: Eni S.p.A., Enitecnologie S.p.A.
    Inventors: Vincenzo Calemma, Cristina Flego, Luciano Cosimo Carluccio, Roberto Millini, Wallace Parker
  • Publication number: 20090159530
    Abstract: A process is described for the treatment of water contaminated by apolar compounds consisting of halogenated solvents, aliphatic compounds, aromatic compounds or their mixtures which consists in treating the water with one or more apolar zeolites characterized by a silica/alumina ration >50 and by the presence of structural channels having dimensions similar to those of the molecules of the contaminating compounds.
    Type: Application
    Filed: December 16, 2008
    Publication date: June 25, 2009
    Applicant: ENITECNOLOGIE S.p.A.
    Inventors: Rodolfo Vignola, Adriano Bernardi, Giovanni Grillo, Raffaello Sisto
  • Patent number: 7550515
    Abstract: Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
    Type: Grant
    Filed: September 17, 2004
    Date of Patent: June 23, 2009
    Assignees: ENI S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Cristina Maretto, Giovanni Pederzani
  • Patent number: 7534340
    Abstract: Process for the contemporaneous production of fuels and lubricating bases from synthetic paraffinic mixtures, which includes a hydrocracking step in the presence of a solid bi-functional catalyst comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm. to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of between 0.05 and 5% by weight with respect to the total weight of the catalyst.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: May 19, 2009
    Assignees: ENI S.p.A., Institute Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Vincenzo Calemma, Cristina Flego, Luciano Cosimo Carluccio, Wallace Parker, Roberto Giardino, Giovanni Faraci
  • Publication number: 20090101540
    Abstract: Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), characterized in that the three units operate on mixed streams consisting of fresh charge and recycled streams, by the use of the following steps: sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one consisting of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and optionally with the remaining fraction of heavy charge not sent to the deasphalting section and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase t
    Type: Application
    Filed: October 9, 2008
    Publication date: April 23, 2009
    Applicants: ENI S.P. A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Mario MARCHIONNA, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Patent number: 7442846
    Abstract: Process for the regeneration of exhausted catalysts, containing one or more calcium aluminates, for steam cracking reactions, comprising treating said exhausted catalysts in a stream of water vapour at a temperature ranging from 700 to 950° C., preferably from 720 to 850° C., and at a pressure ranging from 0.5 to 2 atm.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: October 28, 2008
    Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.
    Inventors: Carlo Perego, Paolo Pollesel, Massimo Soprani, Massimo Romagnoli
  • Patent number: 7427348
    Abstract: A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: September 23, 2008
    Assignees: ENI S.p.A., Enitecnologie S.p.A., Institut Francais du Petrole
    Inventors: Vincenzo Calemma, Silvia Guanziroli, Silvia Pavoni, Roberto Giardino
  • Patent number: 7419930
    Abstract: The present invention regards a catalytic composition comprising gallium, at least one element chosen in the group of the lanthanides, and a zeolite belonging to the MFI, MEL or MFI/MEL families, the crystal lattice of which is made up of silicon oxide and at least one metal oxide chosen from among aluminum oxide, boron oxide and gallium oxide. Preferably, in the catalytic compositions of the present invention a zeolite is used belonging to the MFI family characterized by crystallites which for at least 90% have diameters smaller than 500 ? and which can form agglomerates of submicron dimensions characterized by possessing at least 30% of the extrazeolitic porosity in the region of the mesopores. The catalytic compositions of the present invention can, in addition, contain rhenium. These catalytic compositions are useful in processes of aromatization of hydrocarbons containing from 3 to 6 carbon atoms, preferably, hydrocarbon mixtures containing olefins.
    Type: Grant
    Filed: October 24, 2006
    Date of Patent: September 2, 2008
    Assignees: Eni S.p.A., Enichem S.p.A., Enitecnologie S.p.A.
    Inventors: Angela Carati, Marco Tagliabue, Carlo Perego, Roberto Millini, Stefano Amarilli, Giuseppe Terzoni