Patents Assigned to Enitecnologie S.p.A.
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Patent number: 8262385Abstract: A description follows of an aqueous dispersion of heavy oil residues, suitable for undergoing combustion with a low emission of SOx, comprising: (a) a heavy oil residue; (b) a dispersing agent; (c) a desulfurizing agent selected from CaCO3, MgCO3, dolomite and relative mixtures; (d) a desulfurizing agent with stabilizing and anti-corrosive properties selected from MgO, Mg(OH)2, CaO, Ca(OH)2 and relative mixtures; (e) water; the weight percentage of (e) with respect of the sum of (a)+(e) being at least 15%.Type: GrantFiled: February 22, 2002Date of Patent: September 11, 2012Assignee: Enitecnologie S.p.A.Inventors: Armando Marcotullio, Riccardo Rausa, Alessandro Lezzi
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Patent number: 8236171Abstract: A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, selected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.Type: GrantFiled: July 5, 2006Date of Patent: August 7, 2012Assignees: ENI S.p.A, Enitecnologie S.p.A.Inventors: Roberto Giardino, Vincenzo Calemma, Ugo Cornaro
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Patent number: 7820727Abstract: Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.Type: GrantFiled: February 13, 2009Date of Patent: October 26, 2010Assignees: ENI S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.Inventors: Cristina Maretto, Giovanni Pederzani
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Patent number: 7754637Abstract: The present invention relates to a catalytic composition which comprises a beta zeolite, a metal of group VIII, a metal of group VI B and optionally one or more oxides as carrier. The catalytic system of the present invention can be used for the hydrotreating of hydrocarbon mixtures and more specifically in the upgrading of hydrocarbon mixtures having boiling ranges within the range of 35° to 250° C., containing sulfur impurities, i.e. in hydrodesulfuration with contemporaneous skeleton isomerization and a reduced hydrogenation degree of olefins contained in said hydrocarbon mixtures, the whole process being carried out in a single step.Type: GrantFiled: December 6, 2006Date of Patent: July 13, 2010Assignees: AGIP Petroli S.p.A., Enitecnologie S.p.A.Inventors: Laura Zanibelli, Marco Ferrari, Virginio Arrigoni
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Patent number: 7712489Abstract: A storage tank that stores sulphur with zero emissions uses reinforced EPS panels and an impermeable bottom. The reinforced EPS panels are reinforced with networks of horizontal and/or vertical galvanized or stainless steel wires that are interconnected by galvanized or stainless steel orthogonal wires. Both inner and outer walls of the reinforced EPS panels are plastered before sulphur is placed in the storage tank. Larger storage tanks may be assembled by vertically interconnecting one or more reinforced EPS panels. This interconnection is achieved by corrugating the reinforced EPS panels, or forming their edges in a Greek-key shape. The Greek-key shape prevents sulphur from escaping the storage tank.Type: GrantFiled: November 19, 2004Date of Patent: May 11, 2010Assignees: ENI S.p.A., Snamprogetti S.p.A., Enitecnologie S.p.A.Inventors: Leonardo Zan, Francesco Crescenzi
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Patent number: 7585460Abstract: The invention relates to a method for inhibiting the biological acidification of water which is in contact with materials containing sulfur in reduced form or with elemental sulfur, susceptible to oxidation on the part of Thiobacilli, comprising putting said materials in contact with soluble inorganic salts at concentrations ranging from 0.4 normal to saturation.Type: GrantFiled: April 26, 2004Date of Patent: September 8, 2009Assignees: ENI S.p.A., Enitecnologie S.p.A.Inventors: Francesco Crescenzi, Antonella Crisari, Cesare Achille Piatti
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Patent number: 7579382Abstract: Process for the charging of a catalyst and for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.Type: GrantFiled: September 17, 2004Date of Patent: August 25, 2009Assignees: ENI S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.Inventors: Cristina Maretto, Giovanni Pederzani
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Patent number: 7560408Abstract: Amorphous porous solid of an acidic nature, with a controlled pore size, essentially consisting of a mixed oxide of silicon, aluminum and phosphorous, having a surface area of at least 200 m2/g, which can be used as a catalyst or active carrier of a catalyst for various industrial processes, such as, for example, alkylation, isomerization, hydro-dehydrogenation processes, with an improved activity and selectivity with respect to the traditional amorphous silica-alumina gels.Type: GrantFiled: June 25, 2004Date of Patent: July 14, 2009Assignees: Eni S.p.A., Enitecnologie S.p.A.Inventors: Vincenzo Calemma, Cristina Flego, Luciano Cosimo Carluccio, Roberto Millini, Wallace Parker
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Patent number: 7550515Abstract: Process for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.Type: GrantFiled: September 17, 2004Date of Patent: June 23, 2009Assignees: ENI S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.Inventors: Cristina Maretto, Giovanni Pederzani
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Patent number: 7534340Abstract: Process for the contemporaneous production of fuels and lubricating bases from synthetic paraffinic mixtures, which includes a hydrocracking step in the presence of a solid bi-functional catalyst comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm. to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of between 0.05 and 5% by weight with respect to the total weight of the catalyst.Type: GrantFiled: June 28, 2004Date of Patent: May 19, 2009Assignees: ENI S.p.A., Institute Francais du Petrole, Enitecnologie S.p.A.Inventors: Vincenzo Calemma, Cristina Flego, Luciano Cosimo Carluccio, Wallace Parker, Roberto Giardino, Giovanni Faraci
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Patent number: 7442846Abstract: Process for the regeneration of exhausted catalysts, containing one or more calcium aluminates, for steam cracking reactions, comprising treating said exhausted catalysts in a stream of water vapour at a temperature ranging from 700 to 950° C., preferably from 720 to 850° C., and at a pressure ranging from 0.5 to 2 atm.Type: GrantFiled: November 21, 2001Date of Patent: October 28, 2008Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.Inventors: Carlo Perego, Paolo Pollesel, Massimo Soprani, Massimo Romagnoli
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Patent number: 7427348Abstract: A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.Type: GrantFiled: June 26, 2002Date of Patent: September 23, 2008Assignees: ENI S.p.A., Enitecnologie S.p.A., Institut Francais du PetroleInventors: Vincenzo Calemma, Silvia Guanziroli, Silvia Pavoni, Roberto Giardino
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Patent number: 7419930Abstract: The present invention regards a catalytic composition comprising gallium, at least one element chosen in the group of the lanthanides, and a zeolite belonging to the MFI, MEL or MFI/MEL families, the crystal lattice of which is made up of silicon oxide and at least one metal oxide chosen from among aluminum oxide, boron oxide and gallium oxide. Preferably, in the catalytic compositions of the present invention a zeolite is used belonging to the MFI family characterized by crystallites which for at least 90% have diameters smaller than 500 ? and which can form agglomerates of submicron dimensions characterized by possessing at least 30% of the extrazeolitic porosity in the region of the mesopores. The catalytic compositions of the present invention can, in addition, contain rhenium. These catalytic compositions are useful in processes of aromatization of hydrocarbons containing from 3 to 6 carbon atoms, preferably, hydrocarbon mixtures containing olefins.Type: GrantFiled: October 24, 2006Date of Patent: September 2, 2008Assignees: Eni S.p.A., Enichem S.p.A., Enitecnologie S.p.A.Inventors: Angela Carati, Marco Tagliabue, Carlo Perego, Roberto Millini, Stefano Amarilli, Giuseppe Terzoni
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Patent number: 7404942Abstract: Process for the production of hydrogen and the co-production of carbon dioxide in separate streams comprising the following operations: feeding of a solid to a first reaction zone (R1) in which a liquid or gaseous hydrocarbon, preferably natural gas or methane, is also fed, which reacts with the solid fed at its maximum oxidation degree (over-oxidized form), leading to the formation of the combustion products carbon dioxide and water and the solid at its minimum oxidation degree (reduced form); feeding of the solid in reduced form to a second reaction zone (R2) into which water is also fed, which reacts with the reduced form of the solid, producing hydrogen, steam and the solid at an intermediate oxidation degree (oxidized form); feeding of the solid in oxidized form to a third reaction zone (R3) into which air is also fed, obtaining, from the further oxidation of the solid, heat and the solid in over-oxidized form to be recycled to the first reaction zone (R1), wherein the solid contains at least one elementType: GrantFiled: May 29, 2007Date of Patent: July 29, 2008Assignees: ENI S.p.A., Enitecnologie S.p.A., Snamprogetti S.p.A.Inventors: Domenico Sanfilippo, Franco Mizia, Alberto Malandrino, Stefano Rossini
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Patent number: 7368482Abstract: Partial oxidation process of liquid fuels, selected from hydrocarbon and/or oxygenated compounds, together with gaseous fuels, selected from hydrocarbon compounds, natural gas and LPG, by means of a suitable catalytic system comprising the following steps: premixing the reagents and possibly heating them to temperatures ranging from 25 to 400° C., said reagents consisting of said liquid fuels, said gaseous fuels and oxygen or air or oxygen enriched air, optionally in the presence of vapor and/or CO2; reacting the mixture of reagents in the catalytic zone, at inlet temperatures ranging from 50 to 500° C. and space velocities ranging from 1,000 to 1,000,000 Nl reagents/L cat×h, reaching temperatures ranging from 450 to 1350° C.Type: GrantFiled: September 9, 2004Date of Patent: May 6, 2008Assignees: ENI S.p.A., Enitecnologie S.p.A.Inventors: Luca Basini, Andrea Bartolini, Giancarlo Lupi, Gabriele Carlo Ettore Clerici
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Patent number: 7341665Abstract: A process is described for the treatment of water contaminated by apolar organic compounds and/or by heavy metals, which consists in circulating the water through a system comprising at least two types of zeolites having a silica/alumina ratio >50, placed in succession, wherein the first zeolite through which the water is passed is characterized by a high absorption capacity and structural channel dimensions ranging from 7 to 50 ?, whereas the second is characterized by a high removal capacity of molecules with a molecular diameter comparable with structural channel dimensions ranging from 5 to 7 ?.Type: GrantFiled: December 6, 2004Date of Patent: March 11, 2008Assignee: Enitecnologie S.p.A.Inventors: Rodolfo Vignola, Umberto Cova, Gino Della Penna, Raffaello Sisto
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Patent number: 7341973Abstract: The present invention relates to solid base catalysts consisting of an amorphous material obtained from a silica or alumina gel containing an alkaline, earth-alkaline or transition metal (M), characterized by a molar ratio between metal (M) and Si or Al ranging from 30:1 to 0.0001:1, a surface area ranging from 100 to 600 m2/g, an overall pore volume ranging from 0.1 to 1.1 ml/g, an average channel diameter ranging from 30 to 150 ? and a density of the base sites ranging from 10 to 900 ?mol/g. Said catalysts can be conveniently used in base catalysis reactions.Type: GrantFiled: May 15, 2001Date of Patent: March 11, 2008Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.Inventors: Cristina Flego, Mauro Palazzina, Ugo Romano
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Patent number: 7311468Abstract: Process for the disposal of sulfur which comprises melting the sulfur, optionally in the presence of hydrogen sulfide, and injecting the molten sulfur into geological structures having a temperature ranging from 90 to 160° C.Type: GrantFiled: July 5, 2004Date of Patent: December 25, 2007Assignees: ENI S.p.A., Enitecnologie S.p.A.Inventors: Alberto Di Lullo, Paul Thomas Lockhart
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Patent number: 7287933Abstract: An improved process is described for the removal of organic pollutants from soil by extraction with a lipophylic solvent, wherein the improvement consists in the fact that the purified soil is treated with water to remove the residual solvent. This process allows the residual solvent to be completely removed from the purified soil enabling it to be re-inserted into the environment, with a low energy consumption and a greater guarante of safety in the running of the plant.Type: GrantFiled: July 4, 2002Date of Patent: October 30, 2007Assignees: Ecotec S.r.l., Enitecnologie S.p.A.Inventors: Rosario Pappa, Felicia Massetti, Edoardo D'Angeli, Aldo Imerito
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Patent number: 7255795Abstract: Process for selectively removing molybdenum from liquid mixtures containing it, in a quantity greater than (200) mg/l, together with vanadium characterized in that it comprises the following steps: bringing the liquid mixture to a pH of less than (3); adding a solution of an alkaline xanthate to the solution so that the molar ratio molybdenum/alkaline xanthate ranges from (¼) to (?), maintaining the pH constant by means of the addition of an inorganic acid; stirring the mixture causing the precipitation of the molybdenum present in the mixture.Type: GrantFiled: May 14, 2002Date of Patent: August 14, 2007Assignees: ENI S.p.A., Snamprogetti S.p.A., Enitecnologie S.p.A.Inventors: Emilio Sentimenti, Nicoletta Panariti