Abstract: The invention generally relates to a method of substantially homogeneously mixing ingredients comprising solid thermoplastic particulates and a viscous material in a container and apparatus useful therein. The invention also generally relates to a non-clogging device and mixing apparatus comprising same.
Abstract: A polycondensation reaction mixture is disclosed which includes a catalyst, acyclic esters, ethylene glycol, and water. The catalyst is a titanium atrane. The polycondensation reaction mixture is prepared by the steps of (a) contacting a solution comprising a titanium (IV) alkoxide compound and a first solvent with an organic acid; (b) contacting the solution formed in step (a) with a substituted or unsubstituted trialkanolamine to form an impure catalyst; (c) purifying the impure catalyst to form the titanium atrane catalyst; and (d) bringing the catalyst into contact with the acyclic esters under conditions that produce the ethylene glycol and water.
Abstract: The invention generally relates to a method of substantially homogeneously mixing ingredients comprising solid thermoplastic particulates and a viscous material in a container and apparatus useful therein. The invention also generally relates to a non-clogging device and mixing apparatus comprising same.
Abstract: Method for producing polyesters using titanium atrane catalysts is disclosed. Also disclosed are methods for making the titanium atrane catalysts. The titanium atrane catalysts are useful as esterification and/or polycondensation catalysts, have similar activity, color and byproduct formation as conventional catalyst systems, but with reduced toxicity and regulatory concerns.
Abstract: Method for producing polyesters using titanium atrane catalysts is disclosed. Also disclosed are methods for making the titanium atrane catalysts. The titanium atrane catalysts are useful as esterification and/or polycondensation catalysts, have similar activity, color and byproduct formation as conventional catalyst systems, but with reduced toxicity and regulatory concerns.
Abstract: The invention pertains to new catalyst systems for polycondensation reactions, for example for producing polyethylene terephthalate. In accordance with the invention, complex compounds with hydrotalcite-analogous structures of general formula [M(II)1−xM(III)x(OH)2]x+(An−x/n).mH2O are used, wherein M(II) represents divalent metals, preferably Mg or Zn or NI or Cu or Fe(II) or Co, and M(III) represents trivalent metals, for example Al or Fe(III), and A represents anions, preferably carbonates or borates. These catalysts can be calcinated and can be used in combination with phosphorus compounds that contain at least one hydrolyzable phosphorus-oxygen bond.