Abstract: The present invention relates to a transparent lithium aluminosilicate (LAS) glass-ceramic containing a ?-quartz solid solution as the main crystalline phase, the composition of which, expressed in percentages by mass of oxides, contains 60 to 67.5% SiO2, 18 to 22% Al2O3, 2.5 to 3.3% Li2O, 0 to 1.5% MgO, 1 to 3.5% ZnO, 0 to 4% BaO, 0 to 4% SrO, 0 to 2% CaO, 3.1 to 5% TiO2, 0.4 to 1.3% ZrO2, 0 to 1% Na2O, 0 to 1% K2O, 0 to 5% P2O5, 0.02 to 0.1% CoO, 0.05 to 0.25% Fe2O3, with (0.74 MgO + 0.19 BaO + 0.29 SrO + 0.53 CaO + 0.48 Na2O + 0.32 K2O) / Li2O < 0.8, and optionally up to 2% of at least one refining agent, the composition being free of V2O5 with the exception of unavoidable traces. It also relates to an article, consisting at least in part of a glass-ceramic, chosen in particular from a cooking plate and a glazing. It also relates to a lithium aluminosilicate glass, precursor of the glass-ceramic, and the process for producing the article.

Abstract: The present application relates to glass-ceramics that are white, opalescent or opaque, of the lithium aluminosilicate (LAS) type, containing a solid solution of ?-spodumene as the main crystalline phase. The application also provides articles that are constituted, at least in part, of said glass-ceramics, precursor glasses for said glass-ceramics, and a method of preparing said article. Said glass-ceramics have a composition that is free from arsenic oxide and antimony oxide, with the exception of inevitable traces, and that contains the following, expressed as percentages by weight of oxides: 60% to 70% of SiO2, 18% to 23% of Al2O3, 3.0% to 4.3% of Li2O, 0 to 2% of MgO, 1 to 4% of ZnO, 0 to 4% of BaO, 0 to 4% of SrO, 0 to 2% of CaO, 1.3% to 1.75% of TiO2, 1% to 2% of ZrO2, 0.05% to 0.6% of SnO2, 0 to 2% of Na2O, 0 to 2% of K2O, 0 to 2% of P2O5, 0 to 2% of B2O3, with Na2O+K2O+BaO+SrO+CaO?6% and Na2O+K2O?2%, and a maximum of 500 ppm of Fe2O3.

Abstract: The present application provides transparent glass-ceramics of ?-quartz of composition containing a small content of lithium, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics, and also a method of preparing said articles. Said glass-ceramics have a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 62% to 68% of SiO2; 17% to 21% of AI2O3; 1% to <2% of Li2O; 1% to 4% of MgO; 1% to 6% of ZnO; 0 to 4% of BaO; 0 to 4% of SrO; 0 to 1% of CaO; 1% to 5% of TiO2; 0 to 2% of ZrO2; 0 to 1% of Na2O; 0 to 1% of K2O; with Na2O+K2O+BaO+SrO+CaO<6%; optionally up to 2% of at least one fining agent comprising SnO2; and optionally up to 2% of at least one coloring agent.

Abstract: The present application provides LAS type transparent glass-ceramics of ?-quartz of composition containing a high content of zinc, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics (with a low viscosity at high temperature), and also a method of preparing said articles. Said glass-ceramics present a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 64.5% to 66.5% of SiO2; 19.0% to 20.6% of Al2O3; 3.0% to 3.6% of Li2O; 0 to 1% of MgO; 1.7% to 3.4% of ZnO; 2% to 3% of BaO; 0 to 3% of SrO; 0 to 1% of CaO; 2% to 4% of TiO2; 1% to 2% of ZrO2; 0 to 1% of Na2O; 0 to 1% of K2O; with Na2O+K2O+BaO+SrO+CaO?6%; optionally up to 2% of at least one fining agent comprising SnO2; and optionally up to 2% of at least one coloring agent.

Abstract: The present invention provides an aluminoborosilicate glass of composition, expressed as percentages by weight of oxides, containing: 60% to 70% of SiO2, 13% to 20% of Al2O3, 1% to 9% of B2O3, 0 to 3% of P2O5, 0.5% to 4% of MgO, 1% to 4% of BaO, 0 to 3% of CaO, 0 to 3% of SrO, 2% to 10% of ZnO, 0 to 2% of Li2O, 0 to 2% of Na2O, 0 to 2% of K2O, 0.1% to 3% of CuO, optionally up to 1% of at least one fining agent; and optionally up to 2% of at least one coloring agent other than CuO, with MgO+BaO+CaO+SrO<6%, 0.2%<Li2O+Na2O+K2O<2%, and B2O3+MgO+Li2O?(BaO+CaO+SrO+CuO)<6.4%. The invention also provides an article constituted at least in part of an aluminoborosilicate glass, the article being selected from glazing and a cooktop for associating with induction heater means with infrared sensors.

Abstract: A method for preparing an article, the structure of which comprises a substrate of a glass or a glass-ceramic and a coating fixed to at least one portion of the surface of the substrate. In a characteristic way, the coating is generated from at least one loaded polysilsesquioxane resin; the at least one polysilsesquioxane resin not containing any aryl radical in its structure.

Abstract: The object of the present application is ?-quartz glass-ceramics (having very interesting optical, thermal expansion and feasibility properties), the articles including said glass-ceramics; the precursor glasses of said glass-ceramics, as well as the methods for elaborating said glass-ceramics and said articles. Said glass-ceramics having a composition, free, except for inevitable trace amounts, of arsenic oxide, antimony oxide and rare earth oxide, which contains, expressed in percentages by weight of oxides: 64 to 70% of SiO2, 18 to 24% of Al2O3, 4 to 5% of Li2O, 0 to 0.6% of SnO2, >1.9 to 4% of TiO2, 1 to 2.5% of ZrO2, 0 to 1.5% of MgO, 0 to 3% of ZnO, >0.3 to 1 of CaO, 0 to 3% of BaO, 0 to 3% of SrO, with BaO+SrO?3%, 0 to 1.5% of Na2O, 0 to 2% of K2O, with 0.

Abstract: The present application provides transparent glass-ceramics of ?-quartz of composition containing a small content of lithium, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics, and also a method of preparing said articles. Said glass-ceramics have a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 62% to 68% of SiO2; 17% to 21% of AI2O3; 1% to <2% of Li20; 1% to 4% of MgO; 1% to 6% of ZnO; 0 to 4% of BaO; 0 to 4% of SrO; 0 to 1% of CaO; 1% to 5% of TiO2; 0 to 2% of ZrO2; 0 to 1% of Na2O; 0 to 1% of K2O; with Na2O+K2O+BaO+SrO+CaO <6%; optionally up to 2% of at least one fining agent comprising SnO2; and optionally up to 2% of at least one coloring agent.

Abstract: The present application provides LAS type transparent glass-ceramics of ?-quartz of composition containing a high content of zinc, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics (with a low viscosity at high temperature), and also a method of preparing said articles. Said glass-ceramics present a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 64.5% to 66.5% of SiO2; 19.0% to 20.6% of Al2O3; 3.0% to 3.6% of Li2O; 0 to 1% of MgO; 1.7% to 3.4% of ZnO; 2% to 3% of BaO; 0 to 3% of SrO; 0 to 1% of CaO; 2% to 4% of TiO2; 1% to 2% of ZrO2; 0 to 1% of Na2O; 0 to 1% of K2O; with Na2O+K2O+BaO+SrO+CaO?6%; optionally up to 2% of at least one fining agent comprising SnO2; and optionally up to 2% of at least one coloring agent.

Abstract: Methods, compositions, and articles provide for LAS-type glass-ceramics having specific thermo-mechanical, optical and coloration characteristics to yield generally brown-grey products. The glass-ceramic materials may include as colorants iron oxide, vanadium oxide, chromium oxide, cobalt oxide, nickel oxide and/or cerium oxide.

Abstract: A method for preparing an article, the structure of which comprises a substrate of a glass or a glass-ceramic and a coating fixed to at least one portion of the surface of said substrate. In a characteristic way, said coating is generated from at least one loaded polysilsesquioxane resin; said at least one polysilsesquioxane resin not containing any aryl radical in its structure.

Abstract: Aluminosilicate glasses whose composition is free of alkali metals and contain, as a weight percentage of oxides, 60 to 70% SiO2, 13 to 22% Al2O3, 0 to 9% B2O3, 1 to 6% MgO, 0 to 5% CaO, 1 to 5% BaO, 2 to 12% ZnO, and 0 to 3% SrO, wherein Al2O3+B2O3+ZnO>23% and B2O3+MgO?CaO?BaO?SrO<6%. The glasses exhibit a low coefficient of thermal expansion (CTE) and strong acid and alkali durabilities, and may be used in substrates for induction cooktops.

Abstract: Methods, compositions, and articles provide for LAS-type glass-ceramics having specific thermo-mechanical, optical and coloration characteristics to yield generally brown-grey products. The glass-ceramic materials may include as colorants iron oxide, vanadium oxide, chromium oxide, cobalt oxide, nickel oxide and/or cerium oxide.

Abstract: A method for preparing an article, the structure of which comprises a substrate of a glass or a glass-ceramic and a coating fixed to at least one portion of the surface of the substrate. In a characteristic way, the coating is generated from at least one loaded polysilsequioxane resin not containing any aryl radical in its structure.

Abstract: The object of the present application is ?-quartz glass-ceramics (having very interesting optical, thermal expansion and feasibility properties), the articles including said glass-ceramics; the precursor glasses of said glass-ceramics, as well as the methods for elaborating said glass-ceramics and said articles. Said glass-ceramics having a composition, free, except for inevitable trace amounts, of arsenic oxide, antimony oxide and rare earth oxide, which contains, expressed in percentages by weight of oxides: 64 to 70% of SiO2, 18 to 24% of Al2O3, 4 to 5% of Li2O, 0 to 0.6% of SnO2, >1.9 to 4% of TiO2, 1 to 2.5% of ZrO2, 0 to 1.5% of MgO, 0 to 3% of ZnO, >0.3 to 1 of CaO, 0 to 3% of BaO, 0 to 3% of SrO, with BaO+SrO?3%, 0 to 1.5% of Na2O, 0 to 2% of K2O, with 0.

Abstract: The invention relates to a process for manufacturing a flat ribbon of precursor glass for a glass-ceramic, comprising the continuous floating of the molten glass on a bath of molten metal in a float chamber, said glass being poured in the molten state at a temperature above its devitrification onset temperature onto the molten metal upstream of the chamber, said glass progressively forming a ribbon that runs along said metal bath, the cooling rate of the glass being at least 18° C./min between, on the one hand, the moment when the glass is at the theoretical temperature for which the devitrification rate is a maximum and, on the other hand, the later moment when the glass is at the theoretical temperature at which the devitrification crystal growth rate becomes less than 1 micron per minute. The glass thus floated does not undergo any devitrification.

Abstract: Beta-quartz glass-ceramics containing in their composition neither arsenic oxide nor antimony oxide and having a controlled transmission curve, articles made using the glass-ceramics, including cooktops, and precursor glasses of such glass-ceramics.

Abstract: Methods, compositions, and articles provide for LAS-type glass-ceramics having specific thermo-mechanical, optical and coloration characteristics to yield generally brown-grey products. The glass-ceramic materials may include as colorants iron oxide, vanadium oxide, chromium oxide, cobalt oxide, nickel oxide and/or cerium oxide.

Abstract: Beta-quartz glass-ceramics containing in their composition neither arsenic oxide nor antimony oxide and having a controlled transmission curve, articles made using the glass-ceramics, including cooktops, and precursor glasses of such glass-ceramics.

Abstract: Transparent, essentially colorless and non-diffusing ?-quartz glass-ceramics and glass compositions for forming the same have a composition, free of arsenic oxide, antimony oxide and rare earth oxides except for inevitable trace amounts, which contains, expressed as percentages by weight of oxides 62-72% of SiO2, 20-23% of Al2O3, 2.8-5% of Li2O, 0.1-0.6% of SnO2, 1.9-4% of TiO2, 1.6-3% of ZrO2, less than 0.4% of MgO, 2.5-6% of ZnO and/or BaO and/or SrO, less than 250 ppm of Fe2O3; and their crystallites present in the ?-quartz solid solution have an average size of less than 35 nm. The glass-ceramics exhibit low thermal expansion and are easily obtained at an industrial scale.