Abstract: The present invention relates to a microbial cell for producing at least one L-amino acid from at least one C1-C4 alkane, wherein the cell comprises: (i) an increased expression relative to the wild type cell of Enzyme E1 capable of converting the alkane to a corresponding 1-alkanol; (ii) an increased expression relative to the wild type cell of Enzyme E2 capable of converting the 1-alkanol of (i) to a corresponding aldehyde; and either (iii) (A) an increased expression relative to the wild type cell of Enzyme E3 capable of converting the aldehyde of (ii) to a corresponding alkanoic acid; and a wild-type level expression of Enzyme E4 or an increased expression relative to the wild type cell of Enzyme E4 capable of converting the alkanoic acid of (iii) to a corresponding fatty acyl thioester; or ?(B) an increased expression relative to the wild type cell of Enzyme E5 capable of converting the aldehyde of (ii) to a corresponding fatty acyl thioester; ?and (iv) an increased expression relative to the wi

Abstract: Silicon dioxide-containing thermal-insulation sheet hydrophobized throughout with hardened surface, wherein the compressive stress at fracture measured on the sheet surface is higher than the compressive stress at fracture measured on the sectional surface in the middle cross section of the sheet parallel to the sheet surface, at, in each case, the same penetration depths of the measurement probe in the test specimen.

Abstract: Described is a process for producing trifluoromethanesulfonic acid-acidified, end-equilibrated, acetoxy-bearing siloxanes which comprises reacting cyclic siloxanes, in particular comprising D4 and/or D5, and/or cyclic branched siloxanes of the D/T type with acetic anhydride using trifluoromethanesulfonic acid as catalyst and with addition of acetic acid.

Abstract: The production of SiOC-bonded, linear polydimethylsiloxane-polyoxyalkylene block copolymers comprising repeating (AB) units by reaction of polyether diols with trifluoromethanesulfonic acid-acidified, equilibrated ?,?-diacetoxypolydimethylsiloxanes is described, wherein the reaction is undertaken by adding a solid, liquid or gaseous base, optionally using inert solvents.

Abstract: The invention relates to silane mixtures comprising a silane of the formula I (R1)y(R2)3-ySi—R3—(S—R4)n—S—R5??(I) and a silane of the formula II (R1)y(R2)3-ySi—R3—(S—R4)z—S—R3—Si(R1)y(R2)3-y??(II) where the molar ratio of silane of the formula I to silane of the formula II is 20:80-90:10. The silane mixture according to the invention can be prepared by mixing the silanes of the formula I and silanes of the formula II.

Abstract: Robust separator, which has on a substrate and in the intermediate spaces of the substrate, which comprises fibres of an electrically nonconducting material, an electrically nonconductive coating of oxide particles which are adhesively bonded to one another and to the substrate by an inorganic adhesive and comprise at least one oxide, selected from Al2O3, ZrO2 and SiO2, wherein polymer particles are also present in the ceramic coating in addition to the oxide particles of Al2O3, ZrO2 and/or SiO2. These separators are particularly easy to handle, since they are mechanically very stable.

Abstract: Process comprising the following process steps: a) introducing an ethylenically unsaturated compound; b) adding a ligand-metal complex comprising Pd and a bidentate phosphine ligand, or adding a bidentate phosphine ligand and a compound which comprises Pd; c) adding an alcohol; d) supplying CO; e) heating the reaction mixture, the ethylenically unsaturated compound being reacted to form an ester, where the reaction mixture is admixed with less than 0.1 mol %, based on the amount of substance of the ethylenically unsaturated compound, of Brønsted acids having an acid strength of pKa?3, characterized in that the phosphine ligand is substituted on at least one phosphorus atom by at least one heteroaryl radical.

Abstract: The present invention relates to a method for preparing saturated Cn- and C2n-alcohols, wherein the ratio of Cn- to C2n-alcohols is controlled by a distillative separation of the aldehydes used.

Abstract: The present invention provides a process for production of a solid material containing isomaltulose crystals and trehalulose comprising the process steps A) bringing an enzyme complex which is able to catalyse the reaction of sucrose to isomaltulose and trehalulose into contact with a sucrose-containing solution; B) isomerizing at least some of the sucrose to isomaltulose and trehalulose; C) separating off the enzyme complex to give a solution containing isomaltulose, trehalulose and water; D) partial removal of the water by evaporation, while obtaining a concentrated solution with, based on the total solution, a solid content of 75 wt % to 95 wt %, preferably 80 wt % to 93 wt %, particularly preferably 86 wt % to 92 wt %; E) bringing the concentrated solution to a temperature of 30° C. to 63° C., preferably 45° C. to 62° C., even more preferably 55° C. to 60° C.

Abstract: The invention relates to benzothiazole-containing silanes of the formula I which are prepared by reacting benzothiazole-containing silanes of the formula II with a compound of formula III R2—H??(III). The benzothiazole-containing silanes of the formula I can be used in rubber mixtures.

Abstract: The present invention relates to a process for purifying acrolein. The process includes the steps of a) splitting a liquid feed stream containing acrolein into at least a first liquid stream and a second liquid stream, b) introducing the first liquid stream with a temperature T1 into a distillation column at a point between the top and the bottom of the distillation column, c) introducing the second liquid stream with a temperature T2 into the distillation column at the top of the distillation column, d) withdrawing an overhead vapor stream enriched in acrolein from the distillation column, and e) withdrawing a bottom stream depleted in acrolein. The temperature T2 of the second liquid stream in step c) is lower than the temperature T1 of the first liquid stream in step b).

Abstract: Process for the direct conversion of alkenes to carboxylic acids.

Abstract: The invention provides a process for oligomerization of n-butenes using a nickel-containing aluminosilicate catalyst to produce a product mixture whose ratio of 4,4-dimethylhexene to 3,4-dimethylhexene is determined and monitored. The invention further relates to a process for determining the ratio of the amount of the formed 4,4-dimethylhexene or of the formed 3-ethyl-2-methylpentene to the amount of the formed 3,4-dimethylhexene.

Abstract: The present invention relates to a granular thermal insulation material comprising hydrophobized silicon dioxide and at least one IR opacifier, having a tamped density of up to 250 g/l and a compressive strength according to DIN EN 826:2013 at 50% compression of 150 to 300 kPa or greater than 300 kPa, to processes for production thereof and to the use thereof for thermal insulation.

Abstract: A novel method is used for the fermentative production of L-lysine using bacteria of the species Corynebacterium glutamicum, having the ability to excrete L-lysine, containing in their chromosome a variant of a polynucleotide encoding a polypeptide having hydrolase activity. The bacteria are cultivated in a suitable medium under suitable conditions, and then L-lysine is accumulated in the medium to form an L-lysine containing fermentation broth.

Abstract: The present invention relates to a process for purifying acrolein. The process includes the steps of a) splitting a liquid feed stream containing acrolein into at least a first liquid stream and a second liquid stream, b) introducing the first liquid stream with a temperature T1 into a distillation column at a point between the top and the bottom of the distillation column, c) introducing the second liquid stream with a temperature T2 into the distillation column at the top of the distillation column, d) withdrawing an overhead vapor stream enriched in acrolein from the distillation column, and e) withdrawing a bottom stream depleted in acrolein. The temperature T2 of the second liquid stream in step c) is lower than the temperature T1 of the first liquid stream in step b).

Abstract: The invention provides compositions comprising at least one rhamnolipid and at least one siloxane, characterized in that the weight ratio of rhamnolipid to siloxane is from 5,000,000:1 to 100:1, preferably from 500,000:1 to 1000:1, particularly preferably from 25,000:1 to 2500:1. In another embodiment, the invention provides compositions include rhamnolipid in an amount of from 0.5% by weight to 70% by weight, preferably from 2% by weight to 60% by weight, particularly preferably from 3% by weight to 50% by weight, where the percentages by weight refer to the total composition.

Abstract: Process for the direct conversion of diisobutene to a carboxylic acid.

Abstract: The invention relates to a process comprising the following process steps: a) introducing an ethylenically unsaturated compound; b) adding a monophosphine ligand and a compound which comprises Pd, or adding a complex comprising Pd and a monophosphine ligand; c) adding an aliphatic alcohol; d) supplying CO; e) heating the reaction mixture, the ethylenically unsaturated compound being reacted to form an ester; where the monophosphine ligand is a compound of formula (I) where R1 is selected from —(C1-C12)-alkyl, —O—(C1-C12)-alkyl, —O—(C6-C20)-aryl, —(C6-C20)-aryl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C3-C20)-heteroaryl; R2 is selected from —(C6-C20)-aryl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —(C3-C20)-heteroaryl; R3 is —(C3-C20)-heteroaryl; and R1, R2 and R3 may each independently be substituted by one or more substituents selected from —(C1-C12)-alkyl, —(C3-C12)-cycloalkyl, —(C3-C12)-heterocycloalkyl, —O—(C1-C12)-alkyl, —O—(C1-C12)-alkyl-(C6-C20)-aryl, —O—(C3-C12)-cyclo

Abstract: The invention relates to a method for producing siloxanes that have glycerin modifications and, at the same time, hydrophobic substituents. The invention further relates to a siloxane that has glycerin modifications and also hydrophobic side chains, wherein at least some of the glycerin modifications bear ketal groups, and to the use of said new siloxanes.