Patents Assigned to Evonik Stockhausen, LLC
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Publication number: 20140155259Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.Type: ApplicationFiled: January 23, 2014Publication date: June 5, 2014Applicant: Evonik Stockhausen, LLCInventors: Gonglu Tian, David L. Bergman, JR., Yaru Shi
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Patent number: 8734948Abstract: The present invention relates to absorbent compositions which exhibit swelling, deswelling, and reswelling behavior. More specifically, absorbent compositions of this invention swell and absorb fluids after exposure to aqueous fluids, deswell and release fluids from the swollen absorbent compositions, and may also reswell and absorb fluids. The swelling-deswelling-reswelling behavior allows enhanced liquid distribution in absorbent composites.Type: GrantFiled: November 21, 2012Date of Patent: May 27, 2014Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Scott J. Smith, Yaru Shi, Richard N. Dodge, Jian Qin
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Patent number: 8647317Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.Type: GrantFiled: February 18, 2013Date of Patent: February 11, 2014Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, David L. Bergman, Jr., Yaru Shi
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Publication number: 20140031498Abstract: The invention relates to absorptive, crosslinked polymeric composition that are based on partly neutralized, monoethylenically unsaturated monomer carrying acid groups wherein the absorptive crosslinked polymer may be coated with a polymeric coating, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which have a high capacity and a high gel bed permeability.Type: ApplicationFiled: July 30, 2013Publication date: January 30, 2014Applicant: Evonik Stockhausen, LLCInventors: Scott J. Smith, Stan McIntosh, David L. Bergman, JR.
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Publication number: 20130310251Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups wherein the absorptive crosslinked polymer may be coated with a thermoplastic polymer, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which has a high gel bed permeability and high centrifuge retention capacity.Type: ApplicationFiled: July 11, 2013Publication date: November 21, 2013Applicant: Evonik Stockhausen, LLCInventors: Scott J. Smith, Stan McIntosh, Heinz Bremus, Frank Loeker
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Patent number: 8519041Abstract: The invention relates to absorptive, crosslinked polymeric composition that are based on partly neutralized, monoethylenically unsaturated monomer carrying acid groups wherein the absorptive crosslinked polymer may be coated with a polymeric coating, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which have a high capacity and a high gel bed permeability.Type: GrantFiled: June 15, 2012Date of Patent: August 27, 2013Assignee: Evonik Stockhausen, LLCInventors: Scott J. Smith, Stan McIntosh, David L. Bergman, Jr.
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Patent number: 8487049Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.Type: GrantFiled: November 9, 2012Date of Patent: July 16, 2013Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
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Patent number: 8486855Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.Type: GrantFiled: October 18, 2012Date of Patent: July 16, 2013Assignee: Evonik Stockhausen LLCInventors: Gonglu Tian, Xinyuan Yang, Scott J. Smith
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Publication number: 20130175472Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.Type: ApplicationFiled: February 18, 2013Publication date: July 11, 2013Applicant: EVONIK STOCKHAUSEN, LLCInventor: Evonik Stockhausen, LLC
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Publication number: 20130172180Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.Type: ApplicationFiled: February 28, 2013Publication date: July 4, 2013Applicant: EVONIK STOCKHAUSEN, LLCInventor: Evonik Stockhausen, LLC
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Patent number: 8476189Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.Type: GrantFiled: February 28, 2013Date of Patent: July 2, 2013Assignee: Evonik Stockhausen LLCInventors: Matthias Naumann, Stanley A. McIntosh, Frank Schubert, Christoph Loick
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Patent number: 8425631Abstract: A fossil-fuel-fired system, which includes an emissions-control-agent dispenser, a furnace, an emissions monitor and, optionally, a controller, is disclosed. The emissions-control-agent dispenser provides a prescribed amount of organic-emissions-control agent, such as, for example, an opacity-control agent to the fossil-fuel-fired system. The furnace includes an exhaust communicating with the atmosphere. The emissions monitor is capable of measuring at least one property of the flue-gas communicated through the exhaust to the atmosphere. For example, when an organic-emissions-control agent is an opacity-control agent, the emissions monitor has the capability of at least measuring opacity. When included, the controller communicates with at least the emissions-control-agent dispenser and the emissions monitor.Type: GrantFiled: October 12, 2009Date of Patent: April 23, 2013Assignee: Evonik Stockhausen, LLCInventors: Gary W. Allen, John T. Joyce, Jr.
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Publication number: 20130096000Abstract: The present invention relates to absorbent compositions which exhibit swelling, deswelling, and reswelling behavior. More specifically, absorbent compositions of this invention swell and absorb fluids after exposure to aqueous fluids, deswell and release fluids from the swollen absorbent compositions, and may also reswell and absorb fluids. The swelling-deswelling-reswelling behavior allows enhanced liquid distribution in absorbent composites.Type: ApplicationFiled: November 21, 2012Publication date: April 18, 2013Applicant: Evonik Stockhausen, LLCInventor: Evonik Stockhausen, LLC
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Patent number: 8420567Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.Type: GrantFiled: December 30, 2011Date of Patent: April 16, 2013Assignee: Evonik Stockhausen, LLCInventors: Matthias Naumann, Stanley A. McIntosh, Frank Schubert, Christoph Loick
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Publication number: 20130079221Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.Type: ApplicationFiled: November 9, 2012Publication date: March 28, 2013Applicant: EVONIK STOCKHAUSEN, LLCInventor: EVONIK STOCKHAUSEN, LLC
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Patent number: 8403904Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.Type: GrantFiled: October 4, 2012Date of Patent: March 26, 2013Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, David L. Bergman, Jr., Yaru Shi
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Publication number: 20130045377Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.Type: ApplicationFiled: October 4, 2012Publication date: February 21, 2013Applicant: Evonik Stockhausen, LLCInventor: Evonik Stockhausen, LLC
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Publication number: 20130040811Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.Type: ApplicationFiled: October 18, 2012Publication date: February 14, 2013Applicant: EVONIK STOCKHAUSEN, LLCInventor: EVONIK STOCKHAUSEN, LLC
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Patent number: 8365963Abstract: A fluid dispenser formed of a bottle for housing the fluid, a discharge mechanism for discharging fluid from the bottle, and a protrusion that is connected to and extends from the bottom of the bottle. The fluid dispenser may have a fastener and a stabilizer. The protrusion has a diameter that is smaller than the diameter of the bottom wall of the bottle. The bottle is capable of standing upward on a horizontal surface without the use of a separate base or mount when the protrusion extends into an aperture in the horizontal surface such that the bottom wall of the bottle rests on the horizontal surface. Further, a method of installing a fluid dispenser.Type: GrantFiled: August 24, 2011Date of Patent: February 5, 2013Assignee: Evonik Stockhausen, LLCInventors: Anthony McCullough, Ron Shuster, Lori Huffman
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Patent number: 8361926Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.Type: GrantFiled: November 25, 2008Date of Patent: January 29, 2013Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Xinyuan Yang, Scott J. Smith