Patents Assigned to Evonik Stockhausen, LLC
  • Publication number: 20140155259
    Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.
    Type: Application
    Filed: January 23, 2014
    Publication date: June 5, 2014
    Applicant: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, David L. Bergman, JR., Yaru Shi
  • Patent number: 8734948
    Abstract: The present invention relates to absorbent compositions which exhibit swelling, deswelling, and reswelling behavior. More specifically, absorbent compositions of this invention swell and absorb fluids after exposure to aqueous fluids, deswell and release fluids from the swollen absorbent compositions, and may also reswell and absorb fluids. The swelling-deswelling-reswelling behavior allows enhanced liquid distribution in absorbent composites.
    Type: Grant
    Filed: November 21, 2012
    Date of Patent: May 27, 2014
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Yaru Shi, Richard N. Dodge, Jian Qin
  • Patent number: 8647317
    Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.
    Type: Grant
    Filed: February 18, 2013
    Date of Patent: February 11, 2014
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, David L. Bergman, Jr., Yaru Shi
  • Publication number: 20140031498
    Abstract: The invention relates to absorptive, crosslinked polymeric composition that are based on partly neutralized, monoethylenically unsaturated monomer carrying acid groups wherein the absorptive crosslinked polymer may be coated with a polymeric coating, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which have a high capacity and a high gel bed permeability.
    Type: Application
    Filed: July 30, 2013
    Publication date: January 30, 2014
    Applicant: Evonik Stockhausen, LLC
    Inventors: Scott J. Smith, Stan McIntosh, David L. Bergman, JR.
  • Publication number: 20130310251
    Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups wherein the absorptive crosslinked polymer may be coated with a thermoplastic polymer, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which has a high gel bed permeability and high centrifuge retention capacity.
    Type: Application
    Filed: July 11, 2013
    Publication date: November 21, 2013
    Applicant: Evonik Stockhausen, LLC
    Inventors: Scott J. Smith, Stan McIntosh, Heinz Bremus, Frank Loeker
  • Patent number: 8519041
    Abstract: The invention relates to absorptive, crosslinked polymeric composition that are based on partly neutralized, monoethylenically unsaturated monomer carrying acid groups wherein the absorptive crosslinked polymer may be coated with a polymeric coating, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which have a high capacity and a high gel bed permeability.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: August 27, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Scott J. Smith, Stan McIntosh, David L. Bergman, Jr.
  • Patent number: 8487049
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: July 16, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 8486855
    Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.
    Type: Grant
    Filed: October 18, 2012
    Date of Patent: July 16, 2013
    Assignee: Evonik Stockhausen LLC
    Inventors: Gonglu Tian, Xinyuan Yang, Scott J. Smith
  • Publication number: 20130175472
    Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.
    Type: Application
    Filed: February 18, 2013
    Publication date: July 11, 2013
    Applicant: EVONIK STOCKHAUSEN, LLC
    Inventor: Evonik Stockhausen, LLC
  • Publication number: 20130172180
    Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.
    Type: Application
    Filed: February 28, 2013
    Publication date: July 4, 2013
    Applicant: EVONIK STOCKHAUSEN, LLC
    Inventor: Evonik Stockhausen, LLC
  • Patent number: 8476189
    Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: July 2, 2013
    Assignee: Evonik Stockhausen LLC
    Inventors: Matthias Naumann, Stanley A. McIntosh, Frank Schubert, Christoph Loick
  • Patent number: 8425631
    Abstract: A fossil-fuel-fired system, which includes an emissions-control-agent dispenser, a furnace, an emissions monitor and, optionally, a controller, is disclosed. The emissions-control-agent dispenser provides a prescribed amount of organic-emissions-control agent, such as, for example, an opacity-control agent to the fossil-fuel-fired system. The furnace includes an exhaust communicating with the atmosphere. The emissions monitor is capable of measuring at least one property of the flue-gas communicated through the exhaust to the atmosphere. For example, when an organic-emissions-control agent is an opacity-control agent, the emissions monitor has the capability of at least measuring opacity. When included, the controller communicates with at least the emissions-control-agent dispenser and the emissions monitor.
    Type: Grant
    Filed: October 12, 2009
    Date of Patent: April 23, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gary W. Allen, John T. Joyce, Jr.
  • Publication number: 20130096000
    Abstract: The present invention relates to absorbent compositions which exhibit swelling, deswelling, and reswelling behavior. More specifically, absorbent compositions of this invention swell and absorb fluids after exposure to aqueous fluids, deswell and release fluids from the swollen absorbent compositions, and may also reswell and absorb fluids. The swelling-deswelling-reswelling behavior allows enhanced liquid distribution in absorbent composites.
    Type: Application
    Filed: November 21, 2012
    Publication date: April 18, 2013
    Applicant: Evonik Stockhausen, LLC
    Inventor: Evonik Stockhausen, LLC
  • Patent number: 8420567
    Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.
    Type: Grant
    Filed: December 30, 2011
    Date of Patent: April 16, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Matthias Naumann, Stanley A. McIntosh, Frank Schubert, Christoph Loick
  • Publication number: 20130079221
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Application
    Filed: November 9, 2012
    Publication date: March 28, 2013
    Applicant: EVONIK STOCKHAUSEN, LLC
    Inventor: EVONIK STOCKHAUSEN, LLC
  • Patent number: 8403904
    Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.
    Type: Grant
    Filed: October 4, 2012
    Date of Patent: March 26, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, David L. Bergman, Jr., Yaru Shi
  • Publication number: 20130045377
    Abstract: The present invention relates to a particulate superabsorbent polymer comprising a monomer and an internal crosslinker agent wherein the particulate superabsorbent polymer has a Centrifuge Retention Capacity Increase of 2 g/g or more as set forth herein in the Centrifuge Retention Capacity Increase Test. The present invention further relates to a superabsorbent polymer comprising an internal crosslinker agent comprising a silane compound comprising at least one vinyl group or one allyl group attached to a silicon atom, and at least one Si—O bond. The present invention further relates to an absorbent article that includes such particulate superabsorbent polymers.
    Type: Application
    Filed: October 4, 2012
    Publication date: February 21, 2013
    Applicant: Evonik Stockhausen, LLC
    Inventor: Evonik Stockhausen, LLC
  • Publication number: 20130040811
    Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.
    Type: Application
    Filed: October 18, 2012
    Publication date: February 14, 2013
    Applicant: EVONIK STOCKHAUSEN, LLC
    Inventor: EVONIK STOCKHAUSEN, LLC
  • Patent number: 8365963
    Abstract: A fluid dispenser formed of a bottle for housing the fluid, a discharge mechanism for discharging fluid from the bottle, and a protrusion that is connected to and extends from the bottom of the bottle. The fluid dispenser may have a fastener and a stabilizer. The protrusion has a diameter that is smaller than the diameter of the bottom wall of the bottle. The bottle is capable of standing upward on a horizontal surface without the use of a separate base or mount when the protrusion extends into an aperture in the horizontal surface such that the bottom wall of the bottle rests on the horizontal surface. Further, a method of installing a fluid dispenser.
    Type: Grant
    Filed: August 24, 2011
    Date of Patent: February 5, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Anthony McCullough, Ron Shuster, Lori Huffman
  • Patent number: 8361926
    Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: January 29, 2013
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Xinyuan Yang, Scott J. Smith