Abstract: A process for the synthesis of a granular polymer, the process comprising (a) providing an active polymerization mixture that includes polymer, monomer, catalyst and optional solvent; (b) introducing a hydroxy-containing diaryl acetyl compound to the active polymerization mixture to thereby provide an inactive polymer mixture; (c) separating the polymer solution into a first stream and a second stream, where the first stream includes the polymer and the hydroxy-containing diaryl acetyl compound, and the second stream includes the monomer and the optional solvent; and (d) fabricating granules from the first stream.

Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

Abstract: A laminate film with moderate barrier properties can include: a machine direction oriented (MDO) blown polyethylene substrate laminated to a blown polyethylene sealant film, wherein the blown polyethylene sealant film comprises about 5 wt % to about 25 wt % of hydrocarbon resin. Preferably, a polymeric composition of the laminate film is about 90 wt % to about 100 wt % of polyethylene and hydrocarbon resin cumulatively.

Abstract: Linear alpha olefins (LAOS) may be formed by oligomerization of ethylene in the presence of a Ziegler-type catalyst. The presence of trace water during oligomerization can result in unwanted formation of insoluble higher oligomers or polymer. Methods for limiting the presence of water during ethylene oligomerization reactions may include separating residual ethylene and 1-butene from an LAO product stream to form a higher LAO-enriched stream comprising C6+ LAOs, separating 1-hexene as an overhead stream from the higher-LAO enriched stream using a first distillation column, obtaining separated solvent as a side stream from the first distillation column or as a side stream from a first of one or more downstream distillation columns, and returning the separated solvent to a reactor in a recycled solvent stream. The recycled solvent stream passes through one or more driers before returning to the reactor.

Abstract: An H2-rich fuel gas production plant comprising a syngas production unit can be advantageously integrated with an olefins production plant comprising a steam cracker in at least one of the following: (i) fuel gas supply and consumption; (ii) feed supply and consumption; and (iii) steam supply and consumption, to achieve considerable savings in capital and operational costs, enhanced energy efficiency, and reduced CO2 emissions, compared to operating the plants separately.

Abstract: The present disclosure provides a method for forming oxygenates from olefins which includes hydroformylation of aldehydes as a formyl source alternative to syngas. In at least one embodiment, a hydroformylation process is performed at low-temperature and at or near ambient pressure for the conversion of olefins into aldehydes, thus reducing the formation of by-products such as via double bond or skeletal isomerization of the feedstock; or via further conversion of the formed aldehydes and alcohols. In at least one embodiment, the use of gaseous olefinic products (e.g., ethylene) instead of strained olefins (e.g., norbornene) improves the control equilibria in transfer hydroformylation reactions.

Abstract: Disclosed is a polypropylene with an MFR of at least 20 g/10 min comprising a homopolypropylene and within a range from 2 wt % to 20 wt % of a propylene-?-olefin copolymer by weight of the polypropylene, where the homopolypropylene has a MFR within a range from 30 g/10 min to 200 g/10 min, where the propylene-?-olefin copolymer comprises within a range from 30 wt % to 50 wt % ?-olefin derived units by weight of the propylene-?-olefin copolymer, and has an IV within a range from 4 to 9 dL/g. The polypropylene may be obtained by combining a Ziegler-Natta catalyst having two transition metals with propylene in reactors in series to produce the homopolypropylene followed by a gas phase reactor to produce a propylene-?-olefin copolymer blended with the homopolypropylene.

Abstract: An H2-rich fuel gas stream can be advantageously produced by reforming a hydrocarbon/steam mixture in to produce a reformed stream, followed by cooling the reformed stream in a waste-heat recovery unit to produce a high-pressure steam stream, shifting the cooled reformed stream a first shifted stream, cooling the first shifted stream, shifting the cooled first shifted stream to produce a second shifted stream, cooling the second shifted stream, abating water from the cooled second shifted stream to obtain a crude gas mixture stream comprising H2 and CO2, and recovering a CO2 stream from the crude gas mixture stream. The H2-rich stream can be advantageously combusted to provide thermal energy needed for residential, office, and/or industrial applications including in the H2-rich fuel gas production process. The H2-rich fuel gas production process can be advantageously integrated with an olefins production plant comprising a steam cracker.

Abstract: A composition comprising the reaction product of a polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?vis) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C.; and within the range from 0.01 to 3 wt % of at least one organic peroxide, by weight of the polypropylene and organic peroxide. Such hyperbranched polypropylenes are useful in films, foamed articles, and thermoformed articles.

Abstract: A process for producing an olefin polymer employs a gas phase polymerization reactor having a product discharge system comprising first and second pairs of lock hoppers, wherein each pair comprises an upstream lock hopper connected by valve means to the reactor and a downstream lock hopper connected by valve means to the upstream lock hopper and by further valve means to a product recovery system, and wherein a first cross-tie is provided between the upstream lock hoppers of the first and second pairs of lock hoppers and a second cross-tie is provided between the downstream lock hoppers of the first and second pairs of lock hoppers. Operation of the second cross-tie during product removal cycles is controlled in accordance with reactor pressure.

Abstract: This invention relates bisindenyl metallocene catalyst compounds having long (at least 4 carbon atoms) linear alkyl groups substituted at the two position and substituted or unsubstituted aryl groups at the four position and process using such catalyst compounds, particularly in the solution process at higher temperatures.

Abstract: Described herein are propylene-based polymer compositions that comprise a reactor blend of a first polymer component and a second polymer component. The first polymer component has an ethylene content of from greater than 12 to less than 19 wt % ethylene, and the second polymer component has an ethylene content of from greater than 4 to less than 10 wt % ethylene. Preferably, the ethylene content of the first and second polymer components satisfy the formula: ?1.7143R1+29.771?R2??1.9167R1+37.25. The propylene-based polymer compositions are particularly useful for forming meltspun nonwoven compositions that exhibit a desirable balance of retractive force and permanent set.

Abstract: Methods to produce heterogeneous polyethylene granules, the method including: contacting first olefin monomers and second olefin monomers with a catalyst system in a single reaction zone to produce heterogeneous polyethylene granules and recovering the heterogeneous polyethylene granules; wherein the catalyst system includes a product of a combination including: one or more catalysts having a Group 3 through Group 12 metal atom or lanthanide metal atom; at least one activator; and optionally, one or more support material compositions; and wherein the heterogeneous polyethylene granules include a product of a combination of: a first portion comprising a first polyethylene including the first olefin monomers and the second olefin monomers; a second portion including a second polyethylene including the first monomers and the second monomers; and wherein the first polyethylene has a higher second monomer weight percent than the second polyethylene, are provided.

Abstract: In an embodiment, a slit film tape composition includes a propylene-based elastomer comprising 1-16 wt % ethylene based on a total weight of the propylene-based elastomer, the propylene-based elastomer having a melt flow rate (MFR) of 1-50 g/10 min; a polypropylene comprising 10-100 mol % propylene based on a total weight of the polypropylene, the polypropylene having a MFR of 2-35 g/10 min; and a filler. In another embodiment, a slit film tape composition includes a propylene-based elastomer comprising from 5-30 wt % ethylene based on a total weight of the propylene-based elastomer, the propylene-based elastomer having a MFR of 35-60 g/10 min; a polypropylene comprising 10-100 mol % propylene based on a total weight of the polypropylene, the polypropylene having a MFR of 2-35 g/10 min; and a filler.

Abstract: Provided herein are polyethylene compositions suitable in the fabrication of PE-RT pipes for use in cold and hot water plumbing in accordance with ISO 22391-2, and processes for making the same.

Abstract: A high-pressure steam stream produced from the waste heat recovery system of a syngas producing unit may be superheated and then supplied to a steam turbine in a hydrocarbon production plant to produce an expanded steam stream and shaft power. A portion of the expanded stream can be fed into the reforming reactor in the syngas producing unit. The shaft power can be used to drive compressors and pumps in an olefins production plant. Considerable energy efficiency and capital investment savings can be realized by such steam integration compared to running the olefins production plant separately.

Abstract: In some embodiments, ethylene-propylene branched copolymers are synthesized with pyridyldiamido catalysts and a chain transfer agent, and their performance as viscosity modifiers in oil are detailed. In some embodiments, the present disclosure provides for ethylene-propylene branched copolymers having a shear thinning onset of less than about 0.01 rad/s and an HTHS value of less than about 3.3. In some embodiments, the ethylene-propylene branched copolymer is used as a viscosity modifier in a lubricating composition and a fuel composition.

Abstract: Provided herein are methods of polymerizing ?-olefin monomer with a catalyst and hydrogen in a slurry to produce low molecular weight polyolefins. Hydrogen is vented from the low molecular weight polyolefins and then the low molecular weight polyolefins are further polymerized in a gas phase to produce a polyolefin having a molecular weight distribution of between 4.0 and 30 and a flexural modulus between 1500 mPa and 2500 mPa.

Abstract: Chromium particulate emissions in flue gas can be reduced or minimized by incorporating a thin layer bed of a catalyst within the flue gas flow path of a furnace, boiler, or other furnace environment that includes Cr-containing surfaces. The thin layer bed of catalyst can correspond to, for example, a honeycomb monolith with catalyst supported on the monolith surface, so as to provide a high contact area while forcing all of the flue gas to pass through the catalyst bed. The honeycomb monolith structure and the depth of the bed can be selected to provide a reduced or minimized pressure drop across the catalyst bed, such as a pressure drop of 0.25 kPa (1.0 inches of water) or less. Exposing the Cr-containing flue gas to the thin layer catalyst bed can result in a treated flue gas with a lower content of Cr.

Abstract: A hydrocarbon conversion process comprises pyrolysing at a temperature ?700° C. a feedstock comprising hydrocarbon to produce a pyrolysis effluent comprising at least one C2 to C4 olefin and C5+ aliphatic and aromatic hydrocarbons. The pyrolysis effluent is contacted with an oleaginous quench stream to reduce the temperature of the pyrolysis effluent to ?400° C. At least first and second streams are separated from the cooled effluent. The first stream comprises at least one C2 to C4 olefin, and the second stream comprises a quench oil having an average boiling point at atmospheric pressure of at least 120° C. At least a portion of the second stream is catalytically hydroprocessed to produce a hydroprocessed stream, which is combined with at least a portion of any remainder of the second stream to form the quench stream.