Patents Assigned to ExxonMobil Oil Corporation
  • Patent number: 8846204
    Abstract: This disclosure relates to a laminate film that includes an oriented, polymeric film and a polyolefinic substrate. The oriented, polymeric film includes about 60.0 to about 95.0 wt % of a first polymer and about 5.0 to about 40.0 wt % of a propylene-based elastomer. The polyolefinic substrate is laminated to the first surface of the first surface layer.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: September 30, 2014
    Assignee: ExxonMobil Oil Corporation
    Inventors: Pang-Chia Lu, George F. Cretekos
  • Patent number: 8557919
    Abstract: Provided are polymeric films that include a polyolefin and at least one cavitating agent including a poly(alkylene terephthalate) of formula (I); wherein n, representing the number of methylene segments in the repeating unit, is 3 or an integer greater than or equal to 5; p, representing the degree of polymerization, is an integer greater than 1. The polymeric film may be an opaque polymeric film. A preferred cavitating agent is poly(trimethylene terephthalate). Also provided are methods for making such polymeric films.
    Type: Grant
    Filed: October 27, 2009
    Date of Patent: October 15, 2013
  • Patent number: 8551587
    Abstract: Provided is a polypropylene film, and a method of making the film, the film comprising at least one core layer sandwiched between at least two skin layers, the layers comprising a core layer comprising polypropylene and within the range of from 20 wt % to 50 wt %, by weight of the materials in the core layer, of a propylene-?-olefin elastomer having within the range of from 5 wt % to 25 wt % ?-olefin derived units, by weight of the copolymer; and skin layers comprising one or more polymers having a melting point within the range of from 125° C. to 160° C., a Shore D Hardness within the range of from 55 to 70, and a Flexural Modulus of at least 600 MPa; wherein the film has a Haze value of less than 10%, the film being biaxially oriented but shrinkable substantially only in the MD.
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: October 8, 2013
    Assignee: ExxonMobil Oil Corporation
    Inventors: Pang-Cha Lu, Benoit Ambroise
  • Publication number: 20130212983
    Abstract: Multi-layer laminated structures are disclosed. Such structures include a multi-layer polymeric film having a Layer A that includes at least one polymer and a polymeric sealant layer adjacent to Layer A. The sealant layer has a surface roughness, Ra>5.0 and a Peak Count Value, Pc>50.0. The multi-layer laminated structures also include a substrate in surface contact with the multi-layer polymeric film, typically opposite the sealant layer. Such structures have a top seal and/or side seal of the polymeric sealant layer to itself has a seal strength of >5.00×102 grams/inch at 177° C. The multi-layer films may be transparent, contain a cavitating agent, or are pigmented to form an opaque film. Also, the multi-layer film may be metallized or coated with a barrier coating.
    Type: Application
    Filed: August 12, 2011
    Publication date: August 22, 2013
    Applicant: ExxonMobil Oil Corporation
    Inventors: Eric W. Bender, George F. Cretekos
  • Publication number: 20130180213
    Abstract: A metallized scanner-sensitive film having a shiny appearance but capable of being optically scanned, as well as a method of manufacture and method of using in packaging; the film comprising at least one metal-adhering skin layer having a first outside surface and an inside surface; a metal layer deposited onto the outside surface of the skin layer; the film having: an optical density within the range of from 0.50 to 1.60; an oxygen transmission rate (OTR) of less than 60 cm3/m2/24 hours; and a water vapor transmission rate (WVTR) of less than 0.60 g/m2/24 hours.
    Type: Application
    Filed: November 6, 2012
    Publication date: July 18, 2013
    Applicant: ExxonMobil Oil Corporation
    Inventors: Rajan Verghese, Joseph R. Patry
  • Patent number: 8479478
    Abstract: A sealable polymeric film structure comprising (a) a core layer including a thermoplastic polymer, the core layer having a machine side and a product side that is on a side of the film opposite from the machine side; and (b) a sealable skin layer positioned on the product side of the core layer, the sealable skin layer including a thermoplastic polymer, wherein an exterior surface of the sealable skin layer has a receding Cahn value of at least about 0.48; and wherein in some heat—sealable embodiments, the sealable skin layer sealed to itself has a MST of from about 175° F. to about 220° F., with a jaw pressure of 20 psi for 0.75 seconds and a minimum acceptable seal strength of 200 g/in at 175° F., on a Wrap-Ade™ Crimp Sealer Model J or K.
    Type: Grant
    Filed: May 16, 2008
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Oil Corporation
    Inventors: Michael Dale Cleckner, Scott P. Wilkins
  • Publication number: 20130171386
    Abstract: Multi-layer films particularly suited for packaging applications, including a core layer, a tie layer made from at least 10 wt % of a first polymer and where the first polymer preferably is not present in the core layer are provided. Optionally, the multi-layer film may have a skin layer, a second tie layer and/or a second skin layer. Embodiments may have the advantage of improved seal strength, hermeticity, hot tack and reduced-temperature sealability.
    Type: Application
    Filed: February 22, 2013
    Publication date: July 4, 2013
    Applicant: ExxonMobil Oil Corporation
    Inventor: ExxonMobil Oil Corporation
  • Patent number: 8455064
    Abstract: The present invention relates to printed substrates for use in a variety of applications such as a label stock and flexible packaging structures. The substrates are printed with radiation curable printing ink, especially UV curable printing inks employed in UV inkjet printing processes. The substrates are coated with an ethylene-acrylic acid copolymer based coating capable of adhering and providing wet out properties with UV inkjet inks. Optionally, the coating contains an acrylic polymer. In a specific embodiment, the coating includes a major proportion of ethylene-acrylic acid and minor amounts of filler such as talc and silica. The coating can also include wax and/or pigment such as titanium dioxide. In a further embodiment, the carboxylate groups of the copolymer are neutralized with metal ions from Group Ia, IIa or IIb of the Periodic Table of the Elements, specifically, sodium.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: June 4, 2013
    Assignee: ExxonMobil Oil Corporation
    Inventors: Jeffrey James O'Brien, Dennis Emmett McGee
  • Publication number: 20130130047
    Abstract: This disclosure relates to a laminate film that includes an oriented, polymeric film and a polyolefinic substrate. The oriented, polymeric film includes about 60.0 to about 95.0 wt % of a first polymer and about 5.0 to about 40.0 wt % of a propylene-based elastomer. The polyolefinic substrate is laminated to the first surface of the first surface layer.
    Type: Application
    Filed: May 11, 2011
    Publication date: May 23, 2013
    Applicant: EXXONMOBIL OIL CORPORATION
    Inventors: Pang-Chia Lu, George F. Cretekos
  • Publication number: 20130115398
    Abstract: Provided is a polypropylene film, and a method of making the film, the film comprising at least one core layer sandwiched between at least two skin layers, the layers comprising a core layer comprising polypropylene and within the range of from 20 wt % to 50 wt %, by weight of the materials in the core layer, of a propylene-?-olefin elastomer having within the range of from 5 wt % to 25 wt % ?-olefin derived units, by weight of the copolymer; and skin layers comprising one or more polymers having a melting point within the range of from 125° C. to 160° C., a Shore D Hardness within the range of from 55 to 70, and a Flexural Modulus of at least 600 MPa; wherein the film has a Haze value of less than 10%, the film being biaxially oriented but shrinkable substantially only in the MD.
    Type: Application
    Filed: September 27, 2012
    Publication date: May 9, 2013
    Applicant: ExxonMobil Oil Corporation
    Inventor: ExxonMobil Oil Corporation
  • Patent number: 8404072
    Abstract: Disclosed herein is an improved, metallized polymer film and method for preparing the same. Such films comprise a) at least one treated polymeric skin layer comprising butylene, and b) a metal layer deposited onto at least one surface of this polymeric skin layer. The polymeric skin layer can comprise a propylene-butylene copolymer or an ethylene-propylene-butylene terpolymer, with this copolymer or terpolymer containing from about 4 wt % to about 12 wt % of butylene. The polymeric skin layer is preferably preconditioned by subjecting an outermost surface thereof to plasma treatment which facilitates the deposition thereon of a strongly adhering metal layer which is preferably aluminum. The resulting multi-layer films exhibit metal adhesion bond strength of at least about 100 grams/25 mm. These films will preferably also exhibit a Water Vapor Transmission Rate of from about 0.05 to about 0.2 g/m2/24 hour, and an Oxygen Transmission Rate of from about 5.0 to about 20 cm3/m2/24 hour.
    Type: Grant
    Filed: July 21, 2011
    Date of Patent: March 26, 2013
    Assignee: ExxonMobil Oil Corporation
    Inventors: Laurence D. Urbain, Christophe J. Maertens, George F. Cretekos
  • Patent number: 8383246
    Abstract: In one aspect is provided a film, a shrink sleeve film in a particular embodiment, comprising at least one core layer, one skin layer, and optionally one tie layer between the two, wherein the core comprises from 0 to 30 wt % polypropylene by weight of the core layer, and from 70 to 100 wt % of a random propylene-?-olefin copolymer having within the range of from 1 to 10 wt % ?-olefins, the ?-olefin selected from the group consisting of ethylene and C4 to C12 ?-olefins, and having an MWD within the range of from 1.2 to 4.5 and a melting point within the range of from 110 to 150° C.; wherein the film possesses a TD Tensile Strength of from 100 to 400 MPa and a MD Tensile Strength of from 20 to 60 MPa. In a particular embodiment, the at least one skin layer comprises a solvent sealable material.
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: February 26, 2013
    Assignee: ExxonMobil Oil Corporation
    Inventors: Lori A. Frauenhofer, Lindsay J. Mendes, Eric W. Bender
  • Patent number: 8377845
    Abstract: A composite film useful for image supporting media, including: a first layer containing a thermoplastic polymer and optionally containing a whitening agent; a second layer containing a thermoplastic polymer and a whitening agent; a third layer containing a thermoplastic polymer and a cavitating agent, wherein the third layer is a cavitated layer; optionally a fourth layer containing a thermoplastic polymer and optionally a whitening agent; and optionally a fifth layer containing a thermoplastic polymer and optionally a whitening agent; wherein the second layer is between the first layer and the third layer, the third layer is between the second layer and the optional fourth layer, and the optional fourth layer is between the third layer and the optional fifth layer. Embodiments may have the advantage(s) of improved outer surface characteristics, compressibility, thermal insulation, whiteness, and/or stiffness.
    Type: Grant
    Filed: July 7, 2006
    Date of Patent: February 19, 2013
    Assignee: Exxonmobil Oil Corporation
    Inventors: Jeffrey James O'Brien, Robert M. Sheppard, Pang-Chia Lu
  • Patent number: 8349429
    Abstract: Clear and opaque polymeric film structures for providing clear and opaque labels that are removable, respectively. The film structure includes a core layer and first skin layer, wherein the first skin layer contains a polymeric matrix of a material that allows a label, which has been produced from the film structure and applied onto a container or product, to be removed from the container or product by the solution employed in a process for re-using the container. The first skin layer is co-extruded along with the remainder of the layers of the film structure, or the first skin layer is deposited on the film structure as an emulsion or extrusion coating. The first skin layer can be contacted with a water-based adhesive to affix the label onto a particular product or product container. Labels produced from the film structure exhibit a desirable combination of excellent initial adhesion strength, moisture resistance and delaminatability, as well as excellent removability.
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: January 8, 2013
    Assignee: Exxonmobil Oil Corporation
    Inventors: Jo Ann H. Squier, Robert E. Touhsaent
  • Patent number: 8202623
    Abstract: Novel coated substrates are disclosed wherein a substrate is coated with a coating composition that forms good hermetic seals at very low temperatures and exhibits good blocking and slip characteristics. Such coating composition is comprised of an aqueous dispersion of a substantially non-polar copolymer of ethylene and an alpha-olefin having less than 20 carbon atoms, and an additive selected from the group consisting of an anti-blocking and slip agent, a coalescent and wetting agent, and mixtures thereof.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: June 19, 2012
    Assignee: Exxonmobil Oil Corporation
    Inventors: Thierry Jean-Luc Dabadie, Bruno R. Gringoire, Pang-Chia Lu, Jean-Pierre Frognet, Brad M. Moncla, Matthew J. Kalinowski
  • Patent number: 8149251
    Abstract: A color reproduction system comprises a color imaging output device (e.g., monitor, printer, etc.) and its device characterization (e.g., ICC profile, device link, etc.). A method for assessing the capability and accuracy of a color reproduction system is presented. This method may be used to assess the fit between a color reproduction system and its intended use (e.g., proofing, production, etc.). In addition, it may be used to monitor the color accuracy of a color reproduction system over time, thus informing users of the need to recalibrate and/or recharacterize the system.
    Type: Grant
    Filed: October 1, 2007
    Date of Patent: April 3, 2012
    Assignee: Exxonmobil Oil Corporation
    Inventors: H. Scott Gregory, Jr., Robert J. Eller
  • Patent number: 8142604
    Abstract: A method useful for applying labels to a container, the labels having an activatable adhesive coating on a surface thereon, the adhesive is activated by contact with a low viscosity activator solution from an apparatus comprising at least a label pallet that receives a low viscosity activator solution by contact with a spinning roller, the spinning roller receives at least one stream of the low viscosity activator solution delivered or sprayed by a fluid manifold.
    Type: Grant
    Filed: October 21, 2008
    Date of Patent: March 27, 2012
    Assignee: ExxonMobil Oil Corporation
    Inventors: Richard A. Rehkugler, James A. Johnson, Jr., Daniel L. Hinman, Jo Ann H. Squier
  • Patent number: 8142893
    Abstract: Multi-layer polymeric films having at least one skin layer comprising at least one polyhydroxyether component or a combination of at least one polyhydroxyether component and at least polyester component are provided. The multi-layer films exhibit advantages such as high surface energy contributing to improved printability, barrier properties, and metallization. Additionally, the films exhibit improved adhesion between the skin layer and other layers of multi-layer film structures. In certain embodiments, the at least one skin layer incorporates from about 70 wt. % to about 100 wt. % of the at least one polyhydroxyether component or the combination of the at least one polyhydroxyether component and the at least one polyester component. The combination of the at least one polyhydroxyether component and the at least one polyester component incorporates from about 1 wt. % to about 99.0 wt. % of the at least one polyhydroxyether component and from about 1 wt. % to about 99 wt.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: March 27, 2012
  • Patent number: 8129032
    Abstract: Novel coated substrates are disclosed wherein a substrate is coated with a coating composition that forms good hermetic seals at very low temperatures and exhibits good blocking and slip characteristics. Such coating composition is comprised of an aqueous dispersion of a substantially non-polar copolymer of ethylene and an alpha-olefin having less than 20 carbon atoms, and an additive selected from the group consisting of an anti-blocking and slip agent, a coalescent and wetting agent, and mixtures thereof.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: March 6, 2012
    Assignee: ExxonMobil Oil Corporation
    Inventors: Thierry Jean-Luc Dabadie, Bruno R. Gringoire, Pang-Chia Lu, Jean-Pierre Frognet, Brad M. Moncla, Matthew J. Kalinowski
  • Patent number: 8124243
    Abstract: Thermoplastic films particularly suited for use in bags including at least a core layer comprising an ethylene copolymer, wherein the films are subjected to post-quench biaxial orientation are provided. Optionally, the films may have a first skin layer and/or a second skin layer located on each side of the core layer. Embodiments may have the desirable combination of improved puncture toughness and ultimate tensile strength, low manufacturing cost and desirable optical and tactile properties.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: February 28, 2012
    Assignee: Exxonmobil Oil Corporation
    Inventors: Sydney R. Wright, Donna S. Davis, Jay K. Keung, Pang-Chia Lu